提出了一种测定管道钢阴极充氢或阴极保护过程中氢吸收的新方法.将阴极预充氢试样在稀NaOH溶液中恒电位阳极极化,测量了试样中吸收氢的脱附(氧化)电流随时间的变化曲线.利用该曲线分析吸收氢的量,并建立其与预充氢电流密度、充氢时间及充氢溶液pH间的关系,探索用于评价X70管道钢对阴极充氢敏感性的指标.结果表明,在双对数坐标中试样中的氢浓度分别是预充氢电流密度和时间的单增函数.降低充氢溶液pH可大大提高X70钢的氢吸收量.
参考文献
[1] | Sergei A.Shipilov,Iain Le May,Structural integrity of aging buried pipelines having cathodic protection,Engineering Failure Analysis,13,1159(2006) |
[2] | Jarmila Woodtli,Rolf Kieselbach,Damage due to hydrogen embrittlement and stress corrosion cracking,Engineering Failure Analysis,7,427(2000) |
[3] | B.Gu,J.Luo,X.Mao,Hydrogen-facilitated anodic dissolution-type stress corrosion cracking of pipeline steels in near-neutral pH solution,Corrosion,55(1),96(1999) |
[4] | Kumkum Banerjee,U.K.Chatterjee,Hydrogen permeation and hydrogen content under cathodic charging in HSLA 80 and HSLA 100 steels,Scripta Mater.,44,213(2001) |
[5] | E.Lunarska,Y.Ososkov,Y.Jagodzinsky,Correlation between critical hydrogen concentration and hydrogen damage of pipeline steel,International Journal of Hydrogen Energy,22(2-3),279(1997) |
[6] | J.Mech,Mechanics and thermodynamics on the stress and hydrogen interaction in crack tip stress corrosion:experiment and theory,Phys.Solids,46(6),1125(1998) |
[7] | M.J.Danielson,Use of the Devanathan-Stachurski cell to measure hydrogen permeation in aluminum alloys,Corrosion Science,44,829(2002) |
[8] | P.Manolatos,M.Jerome,C.Duret-thual,J.Le Coze.The electrochemical permeation of hydrogen in steels without palladium coating.Part Ⅰ:interpretation difficulties,Corrosion Science,37(11),1773(1995) |
[9] | Y.F.Cheng,L.Yang,F.King,Analysis of hydrogen permeation through pipeline steel in near-neutral pH SCC environments,Proceedings of International Pipeline Conference,American Society of Mechanical Engineers,Calgary,Canada,2000,vol.2,1479 |
[10] | Maocheng Yan,Yongji Weng.Study on hydrogen absorption of pipeline steel under cathodic charging,Corrosion Science,48(2),432(2006) |
[11] | D.X.He,W.Chen,J.L.Luo,Effect of cathodic potential on hydrogen content in a pipeline steel exposed to NS4 nearneutral pH soil solution,Corrosion,60(8),778(2004) |
[12] | Y.M.Zeng,X.Pang,J.L.Luo,P.R.Norton,Abnormal photocurrent of hydrogen-containing passive films on X70 microalloyed steel,Journal of the Electrochemical Society,152(6),B187(2005) |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%