在存在超临界异丙醇介质的条件下,将钛酸异丙酯与活性炭反应生成具有光催化与吸附性能协同效应的TiO2/活性炭复合材料.产生协同效应,可使低浓度污染物快速地表面富集和吸附净化,加快了污染物的光催化降解速率,TiO2的光催化作用又促使被活性炭吸附的污染物向TiO2表面迁移,使活性炭吸附能力得以恢复,实现了吸附剂的原位再生.
参考文献
[1] | G.Wieslander,D.Norback,E.Bjornsson,C.Janson,G.Boman,Asthma and the indoor environment:the significance of emission of formaldehyde and volatile organic compounds from newly painted indoor surfaces,Int.Arch Occup.Environ.Health.,69,115(1997) |
[2] | F.Fujishima,K.Hashimoto,T.Watanabe,TiO2 photocatalysis fundamentals and applications,In:A Revolution in Cleaning Technology (Tokyo:BKC,1999) p.14-21 |
[3] | SHAO Zhongbao,CHEN Yanfang,LUAN Wanqiang,CHEN Xuebing,Preparation and photocatalytic characteristics of nanometer-sized TiO2 by the polyacrylamide gel method,Journal of Chinese Materials Research,19(2),213(2005)(邵忠宝,陈艳芳,栾万强,陈雪冰,纳米TiO2的制备及其光催化活性,材料研究学报,19(2),213(2005)) |
[4] | ZHANG Xia,ZHAO Yang,ZHANG Caibei,The synthesis of hydrophobic nano-TiO2 powder and its photocatalytic property,Journal of Chinese Materials Research,19(2),131(2005)(张霞,赵岩,张彩碚,表面疏水性纳米TiO2颗粒的制备及光催化性能,材料研究学报,19(2),131(2005)) |
[5] | M.Toyoda,H.Umemura,M.Inagaki,Sorption and decomposition of heavy oil on exfoliated graphite loaded with TiO2,New Carbon Materials,17(2),1(2002)(Toyoda M.,Umemura H.,Inagaki M.,新型炭材料,17(2),1(2002)) |
[6] | J.L.Ferry,W.H.Glaze,Photocatalytic reduction of nitro organics over illuminated titanium dioxide:role of the TiO2 surface,Langmuir,14(13),3551(1998) |
[7] | T.Torimoto,Y.Okawa,N.Takeda,H.Yoneyama,Effect of activated carbon content in TiO2-loaded activated carbon on photodegradation behaviors of dichloromethane,J.Photochem.Photobio.A:Chem.,103(2),153(1997) |
[8] | LI Xuanke,LIU Lang,SHEN Shide,LIU Jing,The Prepsration of binary carbonaceous-titania aerogel precursor by using sol-gel method,New Carbon Materials,15(2),65(2000)(李轩科,刘朗,沈士德,刘静,溶胶-凝胶法制备二元炭质-TiO2气凝胶前驱体,新型炭材料,15(2),65(2000)) |
[9] | HUANG Biao,GAO Shangyu,Progress in advanced carbon materials from wood charcoal,New Carbon Materials,19(2),151(2004)(黄彪,高尚愚,功能性木质炭素新材料的研究与开发,新型炭材料,19(2),151(2004) |
[10] | GU Zhengrong,CHEN Aiping,DAI Zhiming,GU Hongchen,Mechanism of mutual enhancing ability of purification between photocatalysis agent and active carbon on air purification sieve,Chemistry and Industry of Forest Products,20(1),5(2000)(古政荣,陈爱平,戴智铭,古宏晨,空气净化网上光催化剂和活性炭相互增强净化能力的作用机理,林产化学与工业,20(1),5(2000)) |
[11] | LI Suxin,HE Yaming,CUI Pengfei,Study on preparation and properties of TiO2 film supported on granular activated carbon,Journal of Beijing Institute of Light Industry,19(2),36(2000)(李素芹,何亚明,崔鹏飞,颗粒活性炭负载TiO2薄膜的制备与性能研究,北京轻工业学院学报,19(2),36(2000)) |
[12] | M.Doi,S.Saka,H.Miyafuji,D.A.I.Goring,Development of carbonized TiO2-woody composites for environmental cleaning,Materials Sci.Res.Int.,6(1),615(2000) |
[13] | LI Youji,LI Xiaodong,LI Junwen,YIN Jing,Preparation and characterization of TiO2-coated active carbon composites,Materials Science & Techenology,13(5),537(2005)(李佑稷,李效东,李君文,尹静,TiO2/活性炭复合体的制备及其表征,材料科学与工艺,13(5),537(2005)) |
[14] | V.G.Courtecuisse,K.Chhor,J.F.Bocquet,Pommier C.,Kinetics of the Titanium Isopropoxide.decomposition in supercritical isopropyl-alcohol,Ind.Eng.Chem.Res.,35(8),2539(1996) |
[15] | J.B.Tilmant,C.Pommier,K.Chhor,Synthesis of supported TiO2 membranes using supercritical alcohol,Materials Chem.Phys.,64(2),156(2000) |
[16] | Z.B.Zhang,C.C.Wang,R.Zakaria,J.Y.Ying,Role of particle size in nanocrystalline TiO2-based photocatalysts,J.Phys.Chem.B,102(52),10871(1998) |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%