研究了不同La含量Ni-Cr-W-Mo耐热合金的1173 K恒温氧化行为.结果表明:La能明显提高合金的抗氧化能力.不同La含量合金的抗氧化性能从劣到优依次为:La含量为0%、0.048%、0.026%、0.087%.添加超过0.026%的合金由于析出La化合物,使La的固溶量未呈线性增加,而在0.048%处出现拐点.氧化中由于La化物不参与氧化,因此合金的抗氧化能力主要取决于La在合金中的实际固溶量,固溶的La形成LaCrO3是La提高合金抗氧化能力的主要原因.LaCrO3在氧化物晶界处的偏聚阻碍了Cr3+的扩散,并可作为MnCr2O4异制形核的核心,促进细小的MnCr2O4生成并弥散分布于Cr2O3之间,形成混合氧化膜,提高了氧化膜的粘附性,亦成为提高抗氧化能力的因素.
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