采用化学气相沉积法(CVD)制备单质B和BCx分别对SiC涂层进行改性, 在二维碳纤维增强碳化硅(2D C/SiC) 复合材料表面制备SiC/B/SiC和SiC/BCx/SiC两种多层自愈合涂层, 并利用扫描电镜对多层涂层表面和断面进行显微分析. 700℃静态空气条件下氧化结果表明: CVD-B和CVD-BCx改性层氧化后生成的B2O3玻璃相可以较好地封填涂层微裂纹, 氧化动力学受氧通过微裂纹和B2O3玻璃层的扩散共同控制; SiC/BCx/SiC-C/SiC复合材料氧化过程中氧化失重率更小, 氧化10h后的强度保持率更高.
Modification of SiC coating was carried out with B and BCx prepared by chemical vapor deposition(CVD), SiC/B/SiC and SiC/BC x/SiC multi-layer self-healing coatings were prepared on a two-dimensional C/SiC composite. The surface and cross section morphologies of the multi-layer coatings were analyzed by SEM. Oxidation were carried out in static air at 700℃. The results show that the B2O3 glass produced by oxidation of B or BCx can seal the cracks existed in the coating well, the kinetics of oxidation is controlled by
diffusion of oxygen through the micro-cracks and B2O3 glass layer; SiC/BC x/SiC-C/SiC composites have lower weight loss during the oxidation
and higher strength retention after oxidized for 10h.
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