利用激光刻图机对Ba_(0.5) Sr_(0.5) Co_(0.8)Fe_(0.2) O_(3-δ) (BSCFO)透氧膜表面进行刻蚀,以提高膜表面的比表面积,改善膜的氧表面交换能力,从而达到提高透氧量的目的.研究结果表明,激光刻蚀在膜表面形成宽150μm,深25μm的条纹,可以显著提高膜表面的比表面积.XRD图谱显示,激光刻蚀不会引起BSCFO相结构的变化.透氧量测试表明,激光刻蚀可以增大透氧量,十字交叉双面刻蚀效果更加显著.十字交叉双面刻蚀后,其透氧量比未用激光处理的样品提高了大约34%.
The surfaces of Ba_(0.3)Sr_(0.5) Co<0,8> Fe_(0.2) O_(3-δ) (BSCFO) membranes were decorated by laser ablation treatment in order to increase the specific surface of the membrane surface, and laser ablation treatment could improve the ability of oxygen surface exchange and enhance the oxygen permeation flux of the membranes. The arc shape stripes with width about 150μm and depth about 25μm increase the specific surface of the membrane surface significantly, which were made by laser ablation treatment. XRD pattems showed that the BSCFO phase structure was kept after laser ablation treatment. The oxygen permeation fluxes through the membranes after laser ablation treatment were enhanced. and laser ablation treatment with cross stripes pattem on both sides of the membranes had a signification impact on the oxygen permeation flux. The oxygen permeation flux through the membrane with cross stripes pattem on both sides was 34% higher than that through membranes without laser ablation treatment.
参考文献
[1] | Vente Jaap F,Haije Wim G,Rak Zbigniew S.Performance of functional perovskite membranes for oxygen production.Journal of Membrane Science,2006,276 (1/2):178-184. |
[2] | Tu H Y,Takeda Y.Imanishi N,et al.Lnm_(0.4) Sr_(0.6) Co_(0.8) Fe_(0.2) O_(3-δ) (Ln = La.Pr,Nd.Sm,Gd) for the electrode in solid oxide fuel cells.Solid State Ionics.1999,117 (3/4):277-281. |
[3] | Hu Jie,Xing Tianlai,Jia Qingchao.et al.Methane partial oxidation to syngas in YBa_2Cu_3O_(7-x) membrane reactor.Applied Catalysis A:General,2006,306:29-33. |
[4] | Fan Chuan-Gang,Huang Xiang-Xian,Liu Wei,et al.Preparation and oxygen permeation for SrCo_(0.8)Fe_(0.2) O_(3-δ) tubular asymmetric membrane.Journal of Inorganic Materials,2008,23(6):1221-1224. |
[5] | Lee T H,Yang Y L,Jacobson A J,et al.Oxygen permeation in SrCo_(0.8)Fe_(0.2) O_(3-δ) membranes with porous electrodes.Solid State Ionics,1997,100(1/2):77-85. |
[6] | Shao Zongping,Yang Weishen,Cong You,et al.Performance of a mixed-conducting ceramic membrane reactor with high oxygen permeability for methane conversion.Journal of Membrane.Science,2000,172(1/2):177-188. |
[7] | Kim S,Yang Y L,Christoffersen R,et al.Determination of oxygen permeation kinetics in a ceramic membrane based on the composition SrFeCo_(0.5) O_(3.25-δ).Solid State Ionics,1998,109(3/4):187-196. |
[8] | Teraoka Y,Zhang H M,Furukawa S,et al.Oxygen permeation through perovskite-type oxides.Chemistry Letters,1985,14 (11):1743-1746. |
[9] | Bouwmeester H J M,Kruidhof H,Burggraaf A J.Importance of the surface exchange kinetics as rate limiting step in oxygen permeation through mixed-conducting oxides.Solid State Ionics,1994,72 (2):185-194. |
[10] | Sunarsoa J,Baumann S,Serra J.M,et al.Mixed ionic-electronic conducting (MIEC) ceramic-based membranes for oxygen separation.Journal of Membrane Science,2008,320(1/2):13-41. |
[11] | Wang Yingfang,Hao Hsoshan,Jia Jianfeng,et al.Improving the oxygen permeability of Ba_(0.5) Sr_(0.5) Co_(0.8)Fe_(0.2) O_(3-δ) membranes by a surface coating layer of GdBaCo_2O_(5+δ).Journal of European Ceramic Society,2008,28(19):3125-3130. |
[12] | Qi X,Akin F T,Lin Y S.Ceramic-glass composite high temperature seals for dense ionic-conducting ceramic membranes.Journal of Membrane Science,2001,193(2):185-193. |
[13] | Meriche F,Neiss Clauss E,Kremer R,et al.Micro structuring of LiNbO_3 by using nanosecond pulsed laser ablation.Applications of Sulface Science,2007,254(4):1327-1331. |
[14] | der Linde D Von,Sokolowski-Tinten K.The physical mechanisms of short-pulse laser ablation.Applications of Surface Science,2000,154-155:1-10. |
[15] | Kusaba H,Shibata Y,Sasaki K,et al.Surface effect on oxygen permeation through dense membrane of mixed-conductive LSCF perovskite-type oxide.Solid State Ionics,2006,177(26-32):2249-2253. |
[16] | Shao Zongping,Xiong Gnoxing,Dang Hui,et al.Synthesis,oxygen permeation studyandmembraneperformance of a Ba_(0.5)Sr_(0.5) Co_(0.8)Fe_(0.2) O_(3-δ) oxygen permeable dense ceramic reactor for partial oxidation of methane to syngas.Separation and Purifwation Technology,2001,25 (1/2/3):97-116. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%