利用直流磁控溅射法制备纳米金颗粒表面改性TiO2纳米管,并通过XRD,FESEM对其结构进行表征.在紫外光下测试其光电效应,结果发现在定电位和动电位下,纳米金改性后的TiO2纳米管产生的光电流都要比未改性的TiO2纳米管大.在定电位下(1.0V),Au/TiO2纳米管产生的光电流为0.4mA,是TiO2纳米管的1.8倍.在动电位下(-1.5~1.5V),当电位达1.5V时,Au/TiO2纳米管产生的光电流为0.75mA,是TiO2纳米管的3.75倍.
Au nanoparticles surface-modified titania nanotubes were produced by direct-current (DC) magnetic sputtering technology. The morphology of the nanotubes was characterized by X-ray diffractometry (XRD) and field emission scanning electron microscope (FESEM). Opto-electronic properties were tested under UV light. Comparing with original titania nanotubes, Au/TiO2 nanotubes can generate the photocurrent with great improvements in constant potential and dynamic potential. At constant potential (1.0V) test under UV light, the photovoltaic current generated by Au/TiO2 is 0.4mA, 1. 8-fold of original nanotubes'. While at dynamic photocurrent ( -1.5V to 1.5V) test, the photocurrent has reached 0. 75mA, which is 3. 75-fold of that for original nanobubes under the scan voltage of 1. 5V.
参考文献
[1] | Hueso L,Mathura N.Nanotechnology,dreams of a hollow future.Nature,2004,427(6972):301-304. |
[2] | Fujishima A,Honda K.Photocell using covalently-bound dyes on semiconductor surfaces.Nature,1977,268(5617):226-268. |
[3] | Linsebigler A L,Lu G,Yates J T.Photocatalysis on TiO2 surfaces; principles,mechanisms,and selected results.Chem.Rev.,1995,95 (3):735. |
[4] | Bolton J R.Solar photo production of hydrogen:a review.Solar Energy,1996,57:37-50. |
[5] | Aroutiounian V M,Arakelyan V M,Shahnazaryan G E.Metal oxide photoelectrodes for hydrogen generation using solar radiationdriven water splitting.Solar Energy,2005,78(5):581-592. |
[6] | Cratzel M.Review:dye-sensitized solar cells.J.Photochem.Photo-biol.C:Photochem.Rev.,2003,4(2):145-153. |
[7] | Ashokkumar M.An overview on semiconductor particulate systems for photoproduction of hydrogen.Int.J.Hydrogen Energy,1998,23 (6):427-438. |
[8] | Cratzel M.Photoelectrochemical cell.Nature,2001,414:338-344. |
[9] | Cratzel M.Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells.J.Photochem.Phltobiol.A:Chem.,2004,163(1/2/3):3-14. |
[10] | Davis M E.Ordered porous materials for emerging applications.Nature,2002,417(6891):813-821. |
[11] | Inagaki S,Guan S,Ohsuna T,et al.An ordered mesoporous organosilica hybrid material with a crystal-like wall structure.Nature,2002,416(6878):304-307. |
[12] | Zhu K,Neale N R.Miedaner A.Enhanced charge-collection efficiencies and light scattering in dye-sensitized solar cells using oriented TiO2 nanotubes arrays.Nano Lett.,2007,7(1):69-74. |
[13] | Khan M A,Jung H T,Yang O B.Synthesis and characterization of ultrahigh crystalline TiO2 nanotubes.J.Phys.Chem.B,2006,110 (13):6626-6630. |
[14] | Nishijima K,Fukahori T,Murakami N,et al.Development of a titania nanotube (TNT) loaded site-selectively with Pt nanoparticles and their photocatalytic activities.Applied Catalysis A:General,2008,337(1):105-109. |
[15] | Kang Q,Yang L X,Cai Q Y.An electro-catalytic biosensor fabricated with Pt-Au nanoparticle-decorated titania nanotube array.Bioelectro.Chemistry,2008,74(1):62-65. |
[16] | Hou X G,Liu A D.Modification of photocatalytic TiO2 thin films by electron beam irradiation.Radiation Physics and Chemistry,2008,77 (3):345-351. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%