原位合成法制备石墨烯/CdS量子点复合材料,并考察其作为锂离子电池负极材料的电化学性能.交流阻抗揭示电解质在石墨烯/CdS量子点复合材料表面形成稳定的SEI膜,首次放电比容量达1264.7mAh/g,循环20次后可逆容量为888.9mAh/g.结果显示CdS量子点提高了石墨烯结构的稳定和层间传导性,从而导致复合材料的电化学性能明显优于单独的石墨烯材料.
参考文献
[1] | Wu Y P,Rahm E,Holze R.Effects of heteroatoms on electrochemical performance of electrode materials for lithium ion batteries.Electrochim.Acta,2002,47(21):3491-3507. |
[2] | Lian P C,Zhu X F,Liang S Z,et al.Large reversible capacity of high quality graphene sheets as an anode material for lithium-ion batteries.Electrochim.Acta,2010,55(12):3909-3914. |
[3] | Guo P,Song H H,Chen X H.Electrochemical performance of graphene nanosheets as anode material for lithium-ion batteries.Electrochem.Commun,2009,11(6):1320-1324. |
[4] | Wang C Y,Li D,Too C O,et al.Electrochemical properties of graphene paper electrode used in lithium batteries.Chem.Mater.,2009,21(13):2604-2606. |
[5] | Wang G X,Shen X P,Yao J,et al.Graphene nanosheets for enhanced lithium storage in lithium ion batteries.Carbon,2009,47(8):2049-2053. |
[6] | Pan D Y,Wang S,Zhao B,et al.Li storage properties of disordered graphene nanosheets.Chem.Mater.,2009,21(14):3136-3142. |
[7] | Yoo E,Kim J,Hosono E,et al.Large reversible Li storage of graphene nanosheet families for use in rechargeable lithium ion batteries.Nano Lett.,2008,8(8):2277-2282. |
[8] | Liang M H,Zhi L J.Graphene-based electrode materials for rechargeable lithium batteries.J.Mater.Chem.,2009,19(20):5871-5878. |
[9] | Wang G X,Wang B,Wang X L,et al.Sn/graphene nanocomposite with 3D architecture for enhanced reversible lithium storage in lithium ion batteries.J.Mater.Chem.,2009,19(44):8378-8384. |
[10] | Lee J K,Smith K B,Hayner C M,et al.Silicon nanoparticles-graphene paper composites for Li ion battery anodes.Chem.Commun,2010,46(12):2025-2027. |
[11] | Chou S L,Wang J Z,Choucair M,et al.Enhanced reversible lithium storage in a nanosize silicon/graphene composite.Electrochem.Commun.,2010,12(2):303-306. |
[12] | Chen S Q,Chen P,Wu M H,et al.Graphene supported Sn-Sb@carbon core-shell particles as a superior anode for lithium ion batteries.Electrochen.Commun.,2010,12(10):1302-1306. |
[13] | Yao J,Shen X P,Wang B,et al.In situ chemical synthesis of SnO2-graphene nanocomposite as an anode materials for lithiumion batteries.Electrochem.Commun.,2009,11(10):1849-1852. |
[14] | Peak S M,Yoo E J,Honma I.Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure.Nano lett.,2009,9(1):72-75. |
[15] | Yang S B,Cui G L,Pang S P,et al.Fabrication of cobalt and cobalt oxide/graphene composites:towards high-performance anode materials for lithium ion batteries.Chemsuschem,2010,3(2):236-239. |
[16] | Nose K,Fujita H,Omata T,et al.Chemical role of amines in the colloidal synthesis of CdSe quantum dots and their luminescence properties.J.Lumin.,2007,126(1):21-26. |
[17] | Beta P,Kim C H,Seok S I.High-yield synthesis of quantumconfined CdS nanorods using a new dimeric cadmium(Ⅱ) complex of S-benzyldithiocarbazate as single-source molecular precursor.Solid State Sci.,2010,12(4):532-535. |
[18] | Unni C,Philip D,Gopchandran K G Studies on optical absorption and photoluminescence of thioglycerol-stabilized CdS quantum dots.Spectrochim.Acta A,2008,71(4):1402-1407. |
[19] | Cao AN,Liu Z,Chu S S,et al.A facile one-step method to produce graphene-CdS quantum dot nanocomposites as promising optoelectronic materials.Adv.Mater.,2010,22(1):103-106. |
[20] | 郑洪河.锂离子电池电解质.北京:化学工业出版社,2006:69-103. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%