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以F127为模板剂,采用自组装与后活化相结合制备了具有微孔-介孔结构的多级孔炭.N2吸附等温线分析表明后活化可在介孔炭孔壁上生成大量微孔.电化学阻抗谱测量表明多级孔炭电极对I3-还原反应的催化活性明显高于介孔炭电极,电荷迁跃电阻为0.3 Ω·cm2.多级孔炭电极催化活性高是由于它具有较高的比表面和特殊的多级孔结构,有效比表面积较高.以多级孔炭电极为对电极组装染料敏化太阳电池,电池的短路电流密度、开路电压和填充因子分别为0.624V、15.44 mA/cm2和0.67,相应的光电转换效率为6.48%,比介孔炭对电极电池的光电转换效率提高了11.5%.

参考文献

[1] O'Regan B,Gr(a)tzel M. A low cost high-efficiency solar cell based on dye-sensitized colloidal TiO2 films.Nature,1991,353(24):737-739.
[2] Gr(a)tzel M.Dye-sensitized solid-state heterojunction solar cells.MRS Bull.,2005,30(1):23-27.
[3] Nazeeruddin M K,De Angelis F,Fantacci S,et al.Combined experimental and DFT-TDDFT computational study of photoelectrochemical cell ruthenium sensitizers.J.Am.Chem.Soc.,2005,127(48):16835-16847.
[4] Gr(a)tzel M.Mesoscopic solar cells for electricity and hydrogen production from sunlight.Chem.Lett.,2005,34(1):8-9.
[5] Spath M,Sommeling P M,Van Roosmalen J A M,et al.Reproducible manufacturing of dye-sensitized solar cells on a semi-automated baseline.Progress in Photovoltaics,2003,11(3):207-220.
[6] Dai S,Wang K,Weng J,etal.Design DSC panel with efficiency more than 6%.Sol.Energy Mater.Sol.Cells,2005,85(4):447-455.
[7] Papageorgiou N,Maier W F,Gr(a)tzel M.An iodine/triiodide reduction electrocatalyst for aqueous and organic media.J.Electrochem.Soc.,1997,144(3):876-884.
[8] Fang X,Ma T,Guan G,et al.Effect of Pt film thickness of a counter electrode on the performance of dye-sensitized solar cell.J.Electroanal.Chem.,2004,570(2):257-263.
[9] Wang G,Lin R,Lin Y,et al.A novel high-performance counter electrode for dye-sensitized solar cells.Electrochim.Acta,2005,50(28):5546-5552.
[10] Suzuki K,Yamamoto M,Kumagai M,et al.Application of carbon nanotubes to counter eelctrode of dye-sensitized solar cells.Chem.Lett.,2003,32(1):28-29.
[11] Trancik J E,BartonS C,Hone J.Transparent and catalytic carbon nanotube films.Nano Lett.,2008,8(4):982-987.
[12] Han J,Kim H,Kim D,et al.Water-soluble polyelectrolyte-grafted multiwalled carbon nanotube thin films for efficient counter electrode of dye-sensitized solar cells.ACS Nano,2010,4(6):3503-3509.
[13] Kay A,Gr(a)tzel M.Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder.Sol.Energy Mater.Sol.Cells,1996,44(1):99-117.
[14] Imoto K,Takahashi K,Yamaguchi T,et al.High-performance carbon counter electrode for dye-sensitized solar cells.Sol.Energy Mater.Sol.Cells,2003,79(4):459-469.
[15] Huang Z,Liu X,Li K,et al.Application of carbon materials as counter electrodes of dye-sensitized solar cells.Electrochem.Commun.,2007,9(4):596-598.
[16] Wang Q Xing W,Zhuo S.Application of mesoporous carbon to counter electrode for dye-sensitized solar cells.J.Power Source,2009,194(1):568-573.
[17] Ramasamy E,Lee J.Large pore-size mesoporous carbon electrocatalyst for efficient dye-sensitized solar cells.Chem.Commun.,2010,46(12):2136-2138.
[18] Fang B,Fan S,Kim J,et al.Incorporating hierarchical nanostructured carbon counter electrode into metal-free organic dye-sensitized solar cells.Langmuir,2010,26(13):11238-11243.
[19] Hauch A,Georg A.Diffusion in the electrolyte and charge-transfer reaction at the platinum electrode in dye-sensitized solar cells.Electrochim.Acta,2001,46(22):3457-3466.
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