具有聚阴离子型结构的Li3V2(PO4)3正极材料凭借比容量高、结构稳定性好、工作电压高以及成本低的综合性优势受到了广泛的关注,被众多专家学者视为下一代锂离子动力电池正极材料的理想之选.本文对Li3V2(PO4)3材料的结构、电化学性质、制备方法、存在的问题和解决的方案进行了综述,同时对Li3V2(PO4)3正极材料的发展趋势进行了展望.
参考文献
[1] | Burba C M,Frech R.Vibrational spectroscopic studies of monoclinic and rhombohedral Li3V2(PO4)3.Solid Stated Ionics,2007,177(15):3445-3454. |
[2] | Fu P,Zhao Y M,Dong Y Z,et al.Synthesis of Li3V2(PO4)3 with high performance by optimized solid-state synthesis routine.J.Power Sources,2006,162(1):651-657. |
[3] | Masquelier C,Wurm C,Rodriguez-Carvajal J,et al.A powder neutron diffraction investigation of the two rhombohedral NASICON analogues:γ-Na3Fe2(PO4)3 and Li3Fe2(PO4)3.Chem.Mater.,2000,12(2):525-532. |
[4] | Patoux S,Wurm C,Morcrette M,et al.A comparative structural and electrochemical study of monoclinic Li3Fe2(PO4)3 and Li3V2(PO4)3.J.Power Sources,2003,119-121(1):278-284. |
[5] | Saidi M Y,Barker J,Huang H,et al.Performance characteristics of lithium vanadium phosphate as a cathode materials for lithium-ion batteries.J.Power Sources,2003,119-121(1):266-272. |
[6] | Barker J,Saidi M Y,Swoyer J L.A carbothermal reduction method for preparation of electroactive materials for lithium ion applications.J.Electrochem.Soc.,2003,150(6):A684-A688. |
[7] | Rui X H,Ding N,Liu J,et al.Analysis of the chemical diffusion coefficient of lithium ions in Li3Fe2(PO4)3 cathode material.Electrochim.Acta,2010,55(7):2384-2390. |
[8] | 武俊萍.锂离子电池正极材料Li3V2(PO4)3的合成及性能研究.哈尔滨:哈尔滨工业大学硕士论文,2007. |
[9] | Fu P,Zhao Y M,Dong Y Z,et al.Low temperature solid-state synthesis routine and mechanism for Li3V2(PO4)3 using LiF as lithium precursor.Electrochim.Acta,2006,52(3):1003-1008. |
[10] | Barker J,Saidi M Y,Swoyer J L.Lithium iron (Ⅱ) phospho-olivines prepared by a novel carbothermal reduction method.Electrochem.Solid-State Lett.,2003,6(3):A53-A55. |
[11] | Li Y Z,Liu X,Yan J.Study on synthesis routes and their influences on chemical and electrochemical performances of Li3V2(PO4)3/carbon.Electrochim.Acta,2007,53(2):474-479. |
[12] | Jiang T,Wang C Z,Chen G,et al.Effects of synthetic route on the structural,physical and electrochemical properties of Li3V2(PO4)3cathode materials.Solid Stated lonics,2009,180(9/10):708-714. |
[13] | Chen Z Y,Dai C S,Wu G,et al.High performance Li3V2(PO4)3/C composite cathode material for lithium ion batteries studied in pilot scale test.Electrochim.Acta,2010,55(28):8595-8599. |
[14] | Rui X H,Li C,Chen C H.Synthesis and characterization of carbon-coated Li3V2(PO4)3 cathode materials with different carbon sources.Electrochim.Acta,2009,54(12):3374-3380. |
[15] | Qiao Y Q,Wang X L,Zhou Y,et al.Electrochemical performance of carbon-coated Li3V2(PO4)3 cathode materials derived from polystyrene-based carbon-thermal reduction synthesis.Electrochim.Acta,2010,56(1):510-516. |
[16] | Qiao Y Q,Wang X L,Xiang J Y,Z,et al.Electrochemical performance of Li3V2(PO4)3/C cathode materials using stearic acid as a carbon source.Electrochim.Acta,2011,56(5):2269-2275. |
[17] | Rui X H,Yesibolati N,Chen C H.Li3V2(PO4)3/C composite as an intercalation-type anode material for lithium-ion batteries.J.Power Sources,2011,196(4):2279-2282. |
[18] | Qiao Y Q,Tu J P,Xiang J Y,et al.Effects of synthetic route on structure and electrochemical performance of Li3V2(PO4)3/C cathode materials.Electrochim.Acta,2011,56(11):4139-4145. |
[19] | Huang J S,Yang L,Liu K Y.One-pot syntheses of Li3V2(PO4)3/C cathode material for lithium ion batteries via ascorbic acid reduction approach.Mater.Chen Phys.,2011,128(3):470-474. |
[20] | Zhong S K,Yin Z L,Wang Z X.Synthesis and characterization of novel cathode material Li3V2(PO4)3 by carbon thermal reduction method. Trans. Nonferrous Met. Soc. China, 2006, 16(2):s708-s710. |
[21] | YING Jie-Rong,GAO Jian,JLANG Chang-Yin,et al.Preparation and characterization of Li3V2(PO4)3 cathod Material for Lithium ion Batteries.Journal of Inorganic Materials,2006,21(5):1097-1102. |
[22] | 刘素琴,唐联兴,黄可龙,等.新型锂离子电池正极材料Li3V2(PO4)3的合成及其性能.中国有色金属学报,2005,15(8):1294-1299. |
[23] | 刘素琴,唐联兴,黄可龙.碳热还原法合成正极材料Li3V2(PO4)3及其性能.电源技术,2006,30(6):473-476. |
[24] | Zheng J C,Li X H,Wang Z X.et al.Li3V2(PO4)3 cathode material synthesized by chemical reduction and lithiation method.J.Power Sources,2009,189(1):476-479. |
[25] | 肖政伟.以不同原材料制备锂离子电池复合正极材料LiFePO4/C的研究.长沙:中南大学博士论文,2008. |
[26] | Fu L J,Liu H,Li C,et al.Electrode materials for lithium secondary batteries prepared by Sol-Gel methods.Prog.Mater.Sci.,2005,50(7):881-928. |
[27] | Hsu K E,Tsay S Z,Hwang B J.Synthesis and characterization of nano-sized LiFePO4 cathode materials prepared by a citric acid-based Sol-Gel route.J.Mater Chem.,2004,14(17):2690-2695. |
[28] | Yang J,Xu J J.Nonaqueous Sol-Gel synthesis of high-performance LiFePO4.Electrochem.Solid-State Lett.,2004,7(12):A515-A518. |
[29] | Tang A P,Wang X Y,Liu Z M.Electrochemical behavior of Li3V2(PO4)3/C composite cathode material for lithium-ion batteries.Mater.Lett.,2008,62(10/11):1646-1648. |
[30] | Fu P,Zhao Y M,An X N,et al.Structure and electrochemical properties of nanocarbon-coated Li3V2(PO4)3 prepared by Sol-Gel method.Electrochim.Acta,2007,52(16):528 1-5285. |
[31] | Zhao Q,Li Y H,Zhong S K,et al.Syntheis and electrochemical performance of Li3V2(PO4)3 by optimized Sol-Gel synthesis routine.Trans.Nonferrous Met.Soc.China,2010,20(8):1545-1549. |
[32] | Rui X H,Li C,Liu J,et al.The Li3V2(PO4)3/C composites with high-rate capability prepared by a maltose-based Sol-Gel route.Electrochim.Acta,2010,55(22):6761-6767. |
[33] | Jiang T,Pan W C,Wang J,etal.Carbon coated Li3V2(PO4)3cathode material prepared by PVA assisted Sol-Gel method.Electrochim.Acta,2010,55(12):3864-3869. |
[34] | Li Y Z,Zhou Z,Gao X P,et al.A promising Sol-Gel route based on citric acid to synthesize Li3V2(PO4)3/carbon composite material for lithium ion batteries.Electrochim.Acta,2007,52(15):4922-4926. |
[35] | Chen Q Q,Wang J M,Tang Z,et al.Electrochemical performance of the carbon coated Li3V2(PO4)3 cathode material synthesized by Sol-Gel method.Electrochim.Acta,2007,52(16):5251-5257. |
[36] | Ren M M,Zhou Z,Gao X P,et al.Core-shell Li3V2(PO4)3@C composites as cathode materials for lithium-ion batteries.J.Phys.Chem.C,2008,112(14):5689-5693. |
[37] | 牟群英,李贤军.微波加热技术的应用与研究进展.物理,2004,33(6):438-442. |
[38] | 任慢慢,李宇展,周震,等.微波法合成正极材料Li3V2(PO4)3.电池,2006,36(1):13-14. |
[39] | Yang G,Liu H D,Ji H M,et al.Temperature-controlled microwave solid-state synthesis of Li3V2(PO4)3 as cathode materials for lithium battery.J.Power Sources,2010,195(16):5374-5378. |
[40] | Liu H W,Cheng C X,Huang X T,et al.Hydrothermal synthesis and rate capacity studies of Li3V2(PO4)3 nanorods as cathode material for lithium ion batteries.Electrochim.Acta,2010,55(28):8461-8465. |
[41] | 马铖杰,梁怡婧,刘松博.水热法合成聚苯胺掺杂的锂离子电池正极材料磷酸钒锂.河南化工,2011,28(6):3-5. |
[42] | Padhi A K,Nanjiundaswamy K S,Masquelier C.Mapping of transition metal redox energies in phosphates with NASICON structure by lithium intercalation.J.Electrochem.Soc.,1997,144(8):2581-2586. |
[43] | Wang J W,Liu J,Yang G L,et al.Electrochemical performance of Li3V2(PO4)3/C cathode material using a novel carbon source.Electrochim.Acta,2009,54(28):6451-6454. |
[44] | Barker J,Gover R K B,Burns P,et al.The effect of Al substitution on the electrochemical insertion properties of the lithium vanadium phosphate,Li3V2(PO4)3.J.Electrochem.Soc.,2007,154(4):A307-A313. |
[45] | Ren M M,Zhou Z Li Y Z,et al.Preparation and electrochemicalstudies of Fe-doped Li3V2(PO4)3 cathode materials for lithium-ionbatteries.J.Power Sources,2006,162(22):1357-1 362. |
[46] | Chen Y H,Zhao Y M,An X N,et al.Preparation andelectrochemical performance studies on Cr-doped Li3V2(PO4)3 ascathode materials for lithium-ion batteries.Electrochim.Acta,2009,54(24):5844-5850. |
[47] | Zhou S K,Liu L T,Jiang J Q,et al.Preparation andelectrochemical properties of Y-doped Li3V2(PO4)3 cathodematerials for lithium batteries.J.Rare Earth,2009,27(1):134-137. |
[48] | Liu S Q,Li S C,Huang K L,et al.Kinetic study onLiz8(V0.9Ge0.1)(PO4)3 by EIS measurement-J.Alloys Compd.,2006,450(1/2):499-504. |
[49] | Kuang Q,Zhao Y M,An X N,et al.Synthesis and electrochemicalproperties of Co-doped Li3V2(PO4)3 cathode mat~ials forlithium-ion batteries.Electrochim.Acta,2010,55(5):1575-1581. |
[50] | Bini M,Ferrari S,Capsoni D,et al.Mn influence on theelectrochemical behaviour of Li3V2(PO4)3 cathode material.Electrochim.Acta,2010,56(6):2648-2655. |
[51] | Dong Y Z,Zhao Y M,Duan H.The effect of doping Mg~ on thestructure and electrochemical properties of Li3V2(PO4)3 cathodematerials for lithium-ion batteries.J.Power Sources,2011,660(1):14-21. |
[52] | 刘素琴,李世彩,黄可龙,等(LIU Su-Qin,et al.).Ti4+“离子掺杂对晶体结构与性能的影响.物理化学学报(Acta Phys.Chim.Sin.),2007,23(4):537-542. |
[53] | Zhang L,Wang X L,Xiang J Y,et al.Synthesis andelectrochemical performances of Li3V2(PO4)3/(Ag+C) compositecathode.J.Power Sources,2010,195(15):5057-506 1. |
[54] | Jiang T,Wei Y J,Pan W C,et al.Preparation and electrochemicalstudies of Li3V2(PO4)3/Cu composite cathode material for lithiumion batteries.J.Alloys Compd.,2009,488(1):L26-L29. |
[55] | Zheng J C,Li X H,Wang Z X,et al.Novel synthesis ofLiFePO4-Li3V2(PO4)3 composite cathode material by aqueousprecipitation and lithiation.J.Power Sources,2010,195(1):2935-2938. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%