纳米多孔碳具有很多优良的性能,如优异的生物相容性、高导电性、高比表面积等,可应用于电极材料、吸附、分离、催化剂载体等领域.碳化物衍生碳法(Carbide-derived carbons,CDC)在制备纳米多孔碳方面具有比表面积大范围可调、孔结构和石墨化程度精确可控、成本低、保持原有碳化物形态等优点,逐步引起了材料研究者的重视.本文从CDC工艺原理出发,重点概述了CDC工艺的最新研究进展,并介绍了其在超电容电极材料、吸附等领域中的应用情况,最后针对CDC工艺的不足,对其未来发展进行了展望.
参考文献
| [1] | Yürüm Y,Taralp A,Veziroglu T N.Storage of hydrogen in nanostructured carbon materials.International Journal of Hydrogen Energy,2009,34(9):3784-3798. |
| [2] | TANG Shui-Hua,SUN Gong-Quan,QI Jing,et al.New carbon materials as catalyst supports in direct alcohol fuel cells.Chinese Journal of Catalysis,2010,31(1):12-17. |
| [3] | Zhao Y F,Wang W,Xiong D B,et al.Titanium carbide derived nanoporous carbon for supercapacitor applications.International Journal of Hydrogen Energy,2012,37(24):19395-19400. |
| [4] | ZHAO Jiang-Hong,LIU Zhen-Yu.Effect of carbon support on CuO/AC(F) catalyst-sorbents used for catalytic dry oxidation of phenol.New Carbon Materials,2005,20(2):115-121. |
| [5] | Cheng G,Long D H,Liu X J,et al.Fabrication of hierarchical porous carbide-derived carbons by chlorination of mesoporous titanium carbides.New Carbon Materials,2009,24(3):243-250. |
| [6] | Sun G W,Song W H,Liu X J,et al.New concept of in situ carbide-derived carbor/xerogel nanocomposite materials for eleetrochemical capacitor.Materials Letters,2011,65(9):1392-1395. |
| [7] | Wang H L,Gao Q M.Synthesis,characterization and energy-related applications of carbide-derived carbons obtained by the chlorination of boron carbide.Carbon,2009,47(3):820-828. |
| [8] | Presser V,Heon M,Gogotsi Y.Carbide-derived carbons-from porous networks to nanotubes and graphene.Advanced Functional Materials,2011,21(5):810-833. |
| [9] | Urbonaite S,Juárez-Galán Jv M,Leis J,et al.Porosity development along the synthesis of carbons from metal carbides.Microporous and Mesoporous Materials,2008,113(1/2/3):14-21. |
| [10] | Urbonaite S,Wachtmeister S,Mirguet C,et al.EELS studies of carbide derived carbons.Carbon,2007,45(10):2047-2053. |
| [11] | Hoffman E N,Yushin G,El-Raghy T,et al.Micro and mesoporosity of carbon derived from ternary and binary metal carbides.Microporous and Mesoporous Materials,2008,112(1/2/3):526-532. |
| [12] | Zhang B F,Wang S,Li W,et al.Mechanical behavior of C/SiC composites under simulated space environments.Materials Science and Engineering A,2012,534:408-412. |
| [13] | Yu H J,Zhou X G,Zhang W,et al.Properties of carbon nano-tubes-C(f)/SiC composite by precursor infiltration and pyrolysis process.Materials andDesign,2011,32(6):3516-3520. |
| [14] | Ma Q S,Chen Z H.Electrical resistivity of silicon oxycarbide ceramics fabricated via polysiloxane pyrolysis.Rare Metal Materials and Engineering,2007,36(Suppl.1):619-621. |
| [15] | Liu H T,Cheng H F,Wang J,et al.Effects of the SiC powder contents on the mechanical properties of the 2D-SiC(f)/SiC composites fabricated via precursor infiltration pyrolysis process.Rare Metal Materials and Engineering,2009,38(Suppl.2):454-457. |
| [16] | Yeon S H.Reddington P,Gogotsi Y,et al.Cabide-derived-carbons with hierarchical porosity from a preceramic polymer.Carbon,2010,48(1):201-210. |
| [17] | Vakifahmetoglu C,Presser V,Yeon S H,et al.Enhanced hydrogen and methane gas storage of silicon oxycarbide derived carbon.Microporous and Mesoporous Materials,2011,144(1/2/3):105-112. |
| [18] | Batisse N,Guérin K,Dubois M,et al.Fluorination of silicon carbide thin films using pure F2 gas or XeF2.Thin Solid Films,2010,518(23):6746-6751. |
| [19] | Batisse N,Guérin K,Dubois M,et al.The synthesis of microporous carbon by the fluorination of titanium carbide.Carbon,2011,49(9):2998-3009. |
| [20] | Cambaz Z G,Yushin G N,Gogotsi Y,et al.Formation of carbidederived carbon on b-silicon carbide whiskers.Journal of the American Ceramic Society,2006,89(2):509-514. |
| [21] | Kormann M,Ghanem H,Gerhard H,et al.Processing of carbidederived carbon (CDC) using biomorphic porous titanium carbide ceramics.Journal of the European Ceramic Society,2008,28(6):1297-1303. |
| [22] | Portet C,Kazachkin D,Osswald S,et al.Impact of synthesis conditions on surface chemistry and structure of carbide-derived carbons.Thermochim Acta,2010,497(1/2):137-142. |
| [23] | Kormann M,Popovska N.Processing of carbide-derived carbons with enhanced porosity by activation with carbon dioxide.Microporous and Mesoporous Materials,2010,130(1/2/3):167-173. |
| [24] | Yeon S H,Osswald S,Gogotsi Y,et al.Enhanced methane storage of chemically and physically activated carbide-derived carbon.Journal of Power Sources,2009,191(2):560-567. |
| [25] | Gogotsi Y,Portet C,Osswald S,et al.Importance of pore size in high-pressure hydrogen storage by porous carbons.International Journal of Hydrogen Energy,2009,34(15):6314-6319. |
| [26] | Schmirler M,Glenk F,Etzold B J M.In-situ thermal activation of carbide-derived carbon.Carbon,2011,49(11):3679-3686. |
| [27] | Krawiec P,Kockrick E,Borchardt L,et al.Ordered mesoporous carbide derived carbons:novel materials for catalysis and adsorption.Journal of Physical and Chemistry C,2009,113(18):7755-7761. |
| [28] | Kockrick E,Schrage C,Borchardt L,et al.Ordered mesoporous carbide derived carbons for high pressure gas storage.Carbon,2010,48(6):1707-1717. |
| [29] | Oschatz M,Kockrick E,Rose M,et al.A cubic odered,mesoporous carbide-derived carbon for gas and energy storage applications.Carbon,2010,48(14):3987-3992. |
| [30] | Seredych M,Portet C,Gogotsi Y,et al.Nitrogen modified carbidederived carbons as adsorbents of hydrogen sulfide.Journal of ColloidandInterface Science,2009,330(1):60-66. |
| [31] | Jeong J H,Bae H T,Lim D S.The effect of iron catalysts on the microstructure and tribological properties of carbide-derived carbon.Carbon,2010,48(12):3628-3634. |
| [32] | K(a)(a)rik M,Arulepp M,Karelson M,et al.The effect of graphitization catalyst on the structure and porosity of SiC derived carbons.Carbon,2008,46(12):1579-1587. |
| [33] | Chmiola J,Yushin G,Dash R,et al.Effect of pore size and surface area of carbide derived carbons on specific capacitance.Journal of Power Sources,2006,158(1):765-772. |
| [34] | Dash R,Chmiola J,Yushin G,et al.Titanium carbide derived nanoporous carbon for energy-related applications.Carbon,2006,44(12):2489-2497. |
| [35] | Bhatia S K,Nguyen T X.Potential of silicon carbide-derived carbon for carbon capture.Industrial and Engineering Chemistry Research,2011,50(17):10380-10383. |
| [36] | Schlangea A,Rodolfo dos Santosa A,Hasseb B,et al.Titanium carbide-derived carbon as a novel support for platinum catalysts in direct methanol fuel cell application.Journal of Power Sources,2012,199:22-28. |
| [37] | McNallan M,Ersoy D,Zhu R,et al.Nano-structured carbidederived carbon films and their tribology.Tsinghua Science and Technology,2005,10(6):699-703. |
| [38] | Yushin G,Hoffrnana E N,Barsoum M W,et al.Mesoporous carbidederived carbon with porosity tuned for efficient adsorption of eytokines.Biomaterials,2006,27(34):5755-5762. |
| [39] | Yachamaneni S,Yushin G,Yeon S H,et al.Mesoporous carbidederived carbon for cytokine removal from blood plasma.Biomaterials,2010,31(18):4789-4794. |
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