锂/硫电池是以金属锂为负极、单质硫为正极而构筑的二次电池体系.锂/硫电池具有高的理论能量密度(2600 Wh/kg),成为最具发展潜力的高能化学电源体系.但这种基于溶解-沉积反应的锂/硫电池体系仍面临一些无法避免的问题,包括金属锂负极的显著结构变化、硫正极材料存在的活性物质利用率低和循环性能差等缺点,制约了锂/硫电池的发展.本文结合近年来关于锂/硫电池的突破进展,简要阐述了锂/硫电池的研究现状、问题及面临的挑战.
参考文献
| [1] | Gao X P,Yang H X.Multi-electron reaction materials for high energy density batteries.Energy Environ.Sci.,2010,3(2):174-189. |
| [2] | Herbert D,Ulam J.Electric dry cells and storage batteries.US Pat.,3043896 (1962). |
| [3] | Yamin H,Gorenshtein A,Penciner J.,et al.Lithium sulfur battery:oxidation/reduction mechanisms of polysulfides in THF solutions.J.Electrochem.Soc.,1988,135(5):1045-1048. |
| [4] | Akridge J R,Mikhaylik Y V,White N.Li/S fundamental chemistry and application to high-performance rechargeable batteries.Solid State Ionics,2004,175(1-4):243-245. |
| [5] | Ji X L,Nazar L F.Advances in Li-S batteries.J.Mater.Chem.,2010,20(44):9821-9826. |
| [6] | Wang J L,Yang J,Xie J Y,et al.A novel conductive polymersulfur composite cathode material for rechargeable lithium batteries.Adv.Mater.,2002,14(13/14):963-965. |
| [7] | Ji X L,Lee K T,Nazar L E A highly ordered nanostructured carbonsulphur cathode for lithium-sulphur batteries.Nat.Mater,2009,8(6):500-506. |
| [8] | Zhang B,Qin X,Li G R,et al.Enhancement of long stability of sulfur cathode by encapsulating sulfur into micro-pores of carbon spheres.Energy Environ.Sci.,2010,3(10):1531-1537. |
| [9] | Li N W,Zheng M B,Hong H L,et al.High-rate lithium-sulfur batteries promoted by reduced graphene oxide coating.Chem.Commun.,2012,48(34):4106-4108. |
| [10] | Chen J J,Zhang Q,Shi Y N,et al.A hierarchical architecture S/MWCNT nanomicrosphere with large pores for lithium sulfur batteries.Phys.Chem.Chem.Phys.,2012,14(16):5376-5382. |
| [11] | Lee K T,Black R,Yim T,et al.Surface-initiated growth of thin oxide coatings for Li-sulfur battery cathodes.Adv.Energy Mater.,2012,2(12):1490-1496. |
| [12] | Yin L C,Wang J L,Lin F J,et al.Polyacrylonitrile/graphene composite as a precursor to a sulfur-based cathode material for high-rate rechargeable Li-S batteries.Energy Environ.Sci.,2012,5(5):6966-6972. |
| [13] | Li G C,Li G R,Ye S H,et al.A polyaniline-coated sulfur/carbon composite with an enhanced high-rate capability as a cathode material for lithium/sulfur batteries.Adv.Energy Mater-,2012,2(10):1238-1245. |
| [14] | Li G C,Hu J J,Li G R,et al.Sulfur/activated-conductive carbon black composites as cathode materials for lithium/sulfur battery.J.Power Sources,2013,240:598-605. |
| [15] | He G,Ji X L,L Nazar L.High "C" rate Li-S cathodes:sulfur imbibed bimodal porous carbons.Energy Environ.Sci.,2011,4(8):2878-2883. |
| [16] | Wu F,Chen J Z,Chert R J,et al.Sulfur/polythiophene with a core/shell structure:synthesis and electrochemical properties of the cathode for rechargeable lithium batteries.J.Phys.Chem.C,2011,115(13):6057-6063. |
| [17] | Seh Z W,Li W Y,Cha J J,et al.Sulphur-TiO2 yolk-shell nanoarchitecture with internal void space for long-cycle lithium-sulphur batteries.Nat.Commun.,2013,4:1331-1336. |
| [18] | Ding B,Shen L F,Xu J Y,et al.Encapsulating sulfur into mesoporous TiO2 host as a high performance cathode for lithiumsulfur battery.Electrochim.Acta,2013,107:78-84. |
| [19] | Lai C,Li G C,Ye S H,et al.Research process in sulfur-carbon composites as cathode with high capacity.Progress in Chemistry,2011,23(2/3):527-532. |
| [20] | Patel M U M,Demir-Cakan R,Morcrette M,et al.Li-S battery analyzed by UV/Vis in operando mode.Chem.Sus.Chem.,2013,6(7):1177-1181. |
| [21] | Zhang S S.Does the sulfur cathode require good mixing for a liquid electrolyte lithium/sulfur cell? Electrochem.Commun.,2013,31:10-12. |
| [22] | Fu Y Z,Su Y S,Manthiram A.Highly reversible lithium/dissolved polysulfide batteries with carbon nanotube electrodes.Angew.Chem.Int.Ed.,13,52(27):6930-6935. |
| [23] | Yang Y,Zheng G Y,Cui Y.A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage.Energy Environ.Sci.,2013,6(5):1552-1558. |
| [24] | Yang Y,McDowell M T,Jackson A,et al.New nanostructured Li2S/silicon rechargeable battery with high specific energy.Nano Lett.,2010,10(4):1486-1491. |
| [25] | He M,Yuan L X,Zhang W X,et al.Enhanced cyclability for sulfur cathode achieved by a water-soluble binder.J.Phys.Chem.C,2011,115(31):15703-15709. |
| [26] | Wang J L,Yao Z D,Monroe C W,et al.Carbonyl-β-cyclodextrin as a novel binder for sulfur composite cathodes in rechargeable lithium batteries.Adv.Funct.Mater,2013,23(9):1194-1201. |
| [27] | Ai X P,Cao Y L,Yang H X.Simple analysis and possible solutions of the unusual interfacial reactions in Li-S batteries.J.Electrochem.,2012,18(3):224-228. |
| [28] | Lai C,Gao X P,Zhang B,et al.Synthesis and electrochemical performance of sulfur/highly porous carbon composites.J.Phys.Chem.C,2009,113(11):4712-4716. |
| [29] | Barchasz C,Lepretre J,Patoux S,et al.Revisiting TEGDME/DIOX binary electrolytes for lithium/sulfur batteries:Importance of solvation ability and additives.J.Electrochem.Soc.,2013,160(3):A430-A436. |
| [30] | Shin E S,Kim K,Oh S H,et al.Polysulfide dissolution control:the common ion effect.Chem.Commun.,2013,49(20):2004-2006. |
| [31] | Suo L M,Hu Y S,Li H,et al.A new class of solvent-in-salt electrolyte for high-energy rechargeable metallic lithium batteries.Nat.Commun.,2013,4:1481-1489. |
| [32] | Aurbach D,Pollak E,Elazari R,et al.On the surface chemical aspects of very high energy density,rechargeable Li-sulfur batteries.J.Electrochem.Soc.,2009,156(8):A694-A702. |
| [33] | Liang X,Wen Z Y,Liu Y,et al.Improved cycling performances of lithium sulfur batteries with LiNO3-modified electrolyte.J.Power Sources,2011,196(22):9839-9843. |
| [34] | Xiong S Z,Xie K,Diao Y,et al.Properties of surface film on lithium anode with LiNO3 as lithium salt in electrolyte solution for lithium-sulfur batteries.Electrochim.Acta,2012,83:78-86. |
| [35] | Zhang S S.Role of LiNO3 in rechargeahle lithium/sulfur battery.Electrochim.Acta,2012,70:344-348. |
| [36] | Zheng J M,Gu M,Chen H H,et al.Ionic liquid-enhanced solid state electrolyte interface (SEI) for lithium-sulfur batteries.J.Mater Chem.A,2013,1(29):8464-8470. |
| [37] | Song J H,Yeon J T,Jang J Y,et al.Effect of fluoroethylene carbonate on electrochemical performances of lithium electrodes and lithium-sulfur batteries.J.Electrochem.Soc.,2013,160(6):A873-A881. |
| [38] | Xiong S Z,Xie K,Diao Y,et al.On the role of polysulfides for a stable solid electrolyte interphase on the lithium anode cycled in lithium-sulfur batteries.J.Power Sources,2013,236:181-187. |
| [39] | Lee Y M,Choi N S,Park J H,et al.Electrochemical performance of lithium/sulfur batteries with protected Li anodes.J.Power Sources,2003,119-121:964-972. |
| [40] | Zheng M S,Chen J J,Dong Q F.The enhanced electrochemical performance of lithium/sulfur battery with protected lithium anode.Adv.Mater Res.,2012,476-478:676-680. |
| [41] | Wu M F,Wen Z Y,Liu Y,et al.Electrochemical behaviors of a Li3N modified Li metal electrode in secondary lithium batteries.J.Power Sources,201 l,196(19):8091-8097. |
| [42] | Yu Z B,Wang W K,Wang A B,et al.Study on the performance of soft-package Li/S battery.Battery Bimonthly,2007,37(4):247-249. |
| [43] | Wang L,He X M,Li J J,et al.Charge/discharge characteristics of sulfurized polyacrylonitrile composite with different sulfur content in carbonate based electrolyte for lithium batteries.Electrochim.Acta,2012,72:114-119. |
| [44] | Xia L,Li S L,Ai X P,et al.Safety enhancing methods for Li-ion batteries.Progress in Chemistry,2011,23(2/3):328-335. |
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