铌酸钾钠基无铅压电陶瓷的现状、机遇与挑战

无机材料学报, 2014, 29(1): 13-22. doi: 10.3724/SP.J.1077.2014.10002

铌酸钾钠基无铅压电陶瓷的现状、机遇与挑战

1.清华大学材料学院,新型陶瓷与精细工艺国家重点实验室,北京100084

2.清华大学材料学院,新型陶瓷与精细工艺国家重点实验室,北京100084;景德镇陶瓷学院材料科学与工程学院,江西省先进陶瓷材料重点实验室,景德镇333403

3.北京科技大学材料科学与工程学院,北京,100083

4.清华大学材料学院,新型陶瓷与精细工艺国家重点实验室,北京100084

基金项目: National Natural Science Foundation of China(51332002,51302144) 国家自然科学基金青年及重点项目(51332002,51302144) 江西省教育厅科技落地计划(KJLD13076) Ground Plan of Science and Technolagy in Jiangxi Province department of Education(KJLD13076)

关键词：无铅压电陶瓷 , 铌酸钾钠 , 钙钛矿 , 铁电体

(K, Na)NbO3-based Lead-free Piezoceramics: Status, Prospects and Challenges

Keywords： lead-free piezoceramics , (K,Na)NbO3 , perovskite , ferroelectrics

近十年来,铌酸钾钠(KNN)基无铅压电陶瓷一直是国内外的研究热点.基于笔者的研究工作,本文从晶体结构、性能优化、制备工艺三个方面总结了KNN陶瓷的发展现状,并进而尝试分析了该体系在未来发展中面临的机遇与挑战.

参考文献

[1]	Jaffe B,Cook W R,Jaffe H.Piezoelectric Ceramics.Academic Press:New York,1971.
[2]	Xiao D G.Environmentally conscious ferroelectries research.J.Korean Phys.Soc.,1998,32(S):S1798-S1800.
[3]	Ge W,Cao H,Li J,et al.Influence of dc-bias on phase stability in Mn-doped Na0.5Bi0.5TiO3-5.6at％BaTiO3 single crystals.Appl.Phys.Lett.,2009,95(16):162903-1-3.
[4]	Wang K,Li J F.Domain engineering of lead-free Li-modified (K,Na)NbO3 polycrystals with highly enhanced piezoelectricity.Adv.Funct.Mater.,2010,20(12):1924-1929.
[5]	Wang K,Yao F Z,Jo W,et al.Temperature-insensitive (K,Na) NbO3-based lead-free piezo actuator ceramics.Adv.Funct.Mater.,2013,23:4079-4086.
[6]	Wang K,Li J F.Analysis of crystallographic evolution in (Na,K) NbO3-based lead-free piezoceramics by X-ray diffraction,Appl.Phys.Lett.,2007,91(26):262902-1-3.
[7]	Dai Y J,Zhang X W,Zhou G Y.Phase transitional behavior in K0.5Na0.5NbO3-LiTaO3ceramics.Appl.Phys.Lett.,2007,90(26):262903-1-3.
[8]	Lu N,Yu R,Cheng Z Y,et al.Ferroelectric polarization and domain walls in orthorhombic (K1-xNax)NbO3 lead-free ferroelectric cerarrics.Appl.Phys.Lett.,2010,96(22):221905-1-3.
[9]	Xiao D Q,Wu J G,Wu L,et al.Investigation on the composition design and properties study ofperovskite lead-free piezoelectric ceramics.J.Mater.Sci.,2009,44(19):5408-5419.
[10]	Wang L Y,Ren W,Shi P,et al.Enhanced ferroelectric properties in Mn-doped K0.5Na0.5NbO3 thin films derived from chemical solution deposition.Appl.Phys.Lett.,2010,97(7):072902-1-3.
[11]	Fu F,Shen B,Zhai J W,et al.Influence ofMn2+ on the electrical properties of textured KNN thick films.Ceram.Int.,2012,38:S287-S290.
[12]	Gao Y,Zhang J L,Qing Y,et al.Remarkably strong piezoelectricity of lead-free (K0.45Na0.55)0.98Li0.02-(Nb0.77Ta0.18Sb0.05)O3 ceramic.J.Am.Ceram.Soc.,2011,94(9):2968-2973.
[13]	Cheng H L,Du H L,Zhou W C,et al.Effects of LaFeO3 additions on the dielectric and ferroelectric properties of (K0.5Na0.5)NbO3 ceramics.Journal of Inorganic Materials,2012,27(11):1228-1232.
[14]	Chu R G,Hao J G,Xu Z J,et al.Preparation and characterrization of (K0.5Na0.5)0.94-2xLi0.06SrxNb0.98Sb0.02O3 lead-free piezoelectric ceramics.Journal of Inorganic Materials,2010,25(11):1164-1168.
[15]	Zuo R,Fu J.Rhombohedral-tetragonal phase coexistence and piezoelectric properties of (NaK)(NbSb)O3-LiTaO3-BaZrO3 lead-free ceramics.J.Am.Ceram.Soc.,2011,94(5):1467-1470.
[16]	JIANG X P,HU X P,JIANG F L,et al.Li-modified sodium potassium tantalum niobate lead-free piezoelectric ceramics.Journal of Inorganic Materials,2007,22(3):465-468.
[17]	LI YM,XIAO Z G,SHEN Z Y,etal.Effect of BaZrO3 depend on the structure and electric properties of (K0.49Na051)0.98Li0.02-(Nb0.77Ta0.18Sb0.05)O3 lead-free piezoceramics.Journal of Inorganic Materials,2013,28(6):629-634.
[18]	Fu J,Zuo R Z,Wang X H,et al.Polymorphic phase transition and enhanced piezoelectric properties of LiTaO3-modified (Na0.52K0.48)-(Nb0.93Sb0.07)O3 lead-free ceramics.J.Phys.D:Appl.Phys.,2009,42(1):012006-1-4.
[19]	Liu N,Wang K,Li J F,et al.Hydrothermal synthesis and spark plasma sintering of (K,Na)NbO3 lead-free piezoceramics.J.Am.Ceram.Soc.,2009,92(8):1884-1887.
[20]	Zuo R Z,Xu Z K,Li L T.Dielectric and piezoelectric properties of Fe2O3-doped (Na0.5K0.5)0.96Li0.04Nb0.86Ta0.1Sb0.04O3 lead-free ceramics.J.Phys.Chem.Solids.,2008,69(7):1728-1732.
[21]	Zhu K J,Su L K,Ji H L,et al.Hydrothermal solvothermal synthesis of (K,Na) NbO3 lead-free piezoelectric ceramics and its properties.Journal of Inorganic Materials,2010,25(11):1159-1163.
[22]	Smolenskii G A,Isupov V A,Agranovskaya A I,et al.New ferroelectrics of complex composition.Soviet Physics-Solid State,1961,2(11):2651-2654.
[23]	Takenaka T,Maruyama K,Sakata K.(Bi1/2Na1/2)TiO3-BaTiO3 system for lead-free piezoelectric ceramics.Jpn.J.Appl.Phys.,1991,30(9B):2236-2239.
[24]	Egerton L,Dillon D M.Piezoelectric and dielectric properties of ceramics in the system potassium sodium niobate.J.Am.Ceram.Soc.,1959,42(9):438-442.
[25]	Maeder M D,Damjanovic D,Setter N.Lead free piezoelectric materials.J.Electroceram.,2004,13(1/2/3):385-392.
[26]	Tennery V J,Hang K W.Thermal and X-Ray diffraction studies of NaNbO3-KNbO3 system.J.Appl.Phys.,1968,39(10):4749-4753.
[27]	Megaw H D.Crystal structure of double oxides of the perovskite type.P.Phys.Soc.Lond,1946,58(326):133-152.
[28]	Dai Y J,Zhang X W,Chen K P.Morphotropic phase boundary and electrical properties of K1-xNaxNbO3 lead-free ceramics.Appl.Phys.Lett.,2009,94(4):042905-1-3.
[29]	Damjanovic D.Contributions to the piezoelectric effect in ferroelectric single crystals and ceramics.J.Am.Ceram.Soc.,2005,88(10):2663-2676.
[30]	Haun M J,Furman E,Jang S J,et al.Thermodynamic theory of the lead zirconate-titanate solid-solution system,5.Theoretical Calculations.Ferroelectrics,1989,99:63-86.
[31]	Haun M J,Zhuang Z Q,Furman E,etal.Thermodynamic theory of the lead zirconate-titanate solid-solution system,3.Curie constant And 6th-order polarization interaction dielectric stiffness coefficients.Ferroelectrics,1989,99:45-54.
[32]	Damjanovic D,Demartin M.Contribution of the irreversible displacement of domain walls to the piezoelectric effect in barium titanate and lead zirconate titanate ceramics.Journal of Physics-CondensedMatter,1997,9(23):4943-4953.
[33]	Wu L,Zhang J L,Wang C L,et al.Influence of compositional ratio K/Na on physical properties in (KxNa1-x)NbO3 ceramics.J.Appl.Phys.,2008,103(8):084116-1-5.
[34]	Li J F,Wang K,Zhang B P,et al.Ferroelectric and piezoelectric properties of fine-grained Na0.5K0.5NbO3 lead-free piezoelectric ceramics prepared by spark plasma sintering.J.Am.Ceram.Soc.,2006,89(2):706-709.
[35]	Zhang B P,Li J F,Wang K,et al.Compositionaldependence of piezoelectric properties in NaxK1-xNbO3 lead-free ceramicsprepared by spark plasma sintering.J Am.Ceram.Soc.,2006,89(5):1605-1609.
[36]	Saito Y,Takao H,Tani T,et al.Lead-free piezoceramics.Nature,2004,432(4):84-87.
[37]	Lin D,Kwok K W,Chan H L W.Microstructure,phase transition,and electrical properties of (K0.5Na0.5)1-xLix (Nb1-yTay)O3 lead-free piezoelectric ceramics.J.Appl.Phys.,2007,102(3):034102-1-7.
[38]	Wu J G,Xiaob D Q,Wang Y Y,et al.Effects of K/Na ratio on the phase structure and electrical properties of (KxNa0.96-xLi0.04)(Nb0.91Ta0.05Sb0.04)O3 lead-free ceramics.Appl.Phys.Lett.,2007,91(25):252907-1-3.
[39]	Akdo(g)an E K,Kerman K,Abazari M,et al.Origin of high piezoelectric activity in ferroelectric (K0.44Na0.52Li0.04)(Nb0.84Ta0.1Sb0.06)O3 ceramics.Appl.Phys.Lett.,2008,92(11):112908-1-3.
[40]	Zhou J J,Wang K,Li F.et al.High and frequency-insensitive converse piezoelectric coefficient obtained in AgSbO3-modified (Li,K,Na)(Nb,Ta)O3 lead-free piezoceramics.J.Am.Ceram.Soc.,2013,96(2):519-523.
[41]	Li J F,Zhen Y H,Zhang B P,et al.Normal sintering of(K,Na)NbO3-based lead-free piezoelectric ceramics.Ceram.Int.,2008,34(4):783-786.
[42]	Zhou J J,Li J F,Zhang X W.Orthorhombic to tetragonal phase transition due to stress release in (Li,Ta)-doped(K,Na)NbO3 lead-free piezoceramics.J.Eur.Ceram.Soc.,2012,32(2):267-270.
[43]	Guo Y P,Kakimoto K,Ohsato H.Phase transitional behavior and piezoelectric properties of (Na0.5K0.5)NbO3-LiNbO3 ceramics.Appl.Phys.Lett.,2004,85(18):4121-4123.
[44]	Wada S,Yako K,Kakemoto H,et al.Enhanced piezoelectric properties of barium titanate single crystals with different engineered-domain sizes.J.Appl.Phys.,2005,98(1):014109-1-7.
[45]	Sluka T,Tagantsev A K,Damjanovic D,et al.Enhanced electromechanical response of ferroelectrics due to charged domain walls.Nature Commun.,2012,3:748-1-7.
[46]	Zhen Y H,Li J F.Abnormalgrain growth and new core-shell structure in (K,Na)NbO3-based lead-free piezoelectric ceramics.J.Am.Ceram.Soc.,2007,90(11):3496-3502.
[47]	Li E,Kakemoto H,Wada S,et al.Influence of CuO on the structure and piezoelectric properties of the alkaline niobate-based lead-free ceramics.J.Am.Ceram.Soc.,2007,90(6):1787-1791.
[48]	Zuo R Z,R(o)del J,Chen R Z,et al.Sintering and electrical properties of lead-free Na0.5K0.5NbO3 piezoelectric ceramics.J.Am.Ceram.Soc.,2006,89(6):2010-2015.
[49]	Bernard J,Bencan A,Rojac T,et al.Low-temperature sintering of K0.5Na0.5NbO3 ceramics.J.Am.Ceram.Soc.,2008,91(7):2409-2411.
[50]	Matsubara M,Kikuta K,Hirano S.Piezoelectric properties of (K0.5Na0.5)(Nb1-xTax)O3-K5.4CuTa10O29 ceramics.J.Appl.Phys.,2005,97(11):114105.
[51]	Park H Y,Ahn C W,Song H C,et al.Microstructure and piezoelectric properties of 0.95(Na0.5K0.5)NbO3-0.05BaTiO3 ceramics.Appl.Phys.Lett.,2006,89(6):062906-1-3.
[52]	Li Y M,Shen Z Y,Li R R,et al.Effect of BBS-based frit on the low temperature sintering and electrical properties of KNN lead-free piezoceramics.International Journal of Applied Ceramic Technology,2013,10(5):866-872.
[53]	Wang K,Li J F.Low-temperature sintering of Li-modified (K,Na)NbO3 lead-free ceramics:sintering behavior,microstructure,and electrical properties.J.Am.Ceram.Soc.,2010,93(4):1101-1107.
[54]	Yao F Z,Wang K,Li J F.Comprehensive investigation of elastic and electrical properties of Li/Ta-modified (K,Na)NbO3 lead-free piezoceramics.J.Appl.Phys.,2013,113(17):174105-1-7.
[55]	Shen Z Y,Wang K,Li J F.Combined effects of Li content and sintering temperature on polymorphic phase boundary and electrical properties of Li/Ta co-doped (Na,K)NbO3 lead-free piezoceramics.Appl.Phys.A,2009,97(4):911-917.
[56]	Wang K,Li J F,Zhou J J.High normalized strain obtained in Li-modified (K,Na)NbO3 lead-free piezoceramics.Appl.Phys.Express,2011,4(6):061501-1-3.
[57]	Zhou J J,Li J F,Wang K,et al.Phase structure and electrical properties of (Li,Ta)-doped (K,Na)NbO3 lead-free piezoceramics in the vicinity ofNa/K=50/50.J.Mater.Sci.,2011,46(15):5111-5116.
[58]	Cheng L Q,Zhou J J,Wang K,et al.Influence of ball milling on sintering behavior and electrical properties of (Li,Na,K)NbO3 lead-free piezoceramics.J.Mater.Sci.,2012,47(19):6908-6914.
[59]	Wang K,Li J F.(K,Na) NbO3-based lead-free piezoceramics:phase transition,sintering and property enhancement.Journal of Advanced Ceramics,2012,1(1):24-37.
[60]	Malic B,Bemard J,Bencan A,et al.Influence of zirconia addition on the microstructure of K0.5Na0.5NbO3 ceramics.J.Eur Ceram.Soc.,2008,28(6):1191-1196.
[61]	Zhu F,Skidmore T A,Bell A J,et al.Diffuse dielectric behaviour in Na05K0.5NbO3-LiTaO3-BiScO3 lead-free ceramics,Mater.Chem.Phys.,2011,129(1/2):411-417.
[62]	Patterson E A,Caun D P.Piezoelectric properties and unipolar fatigue behavior of KNN-based Pb-free piezoceramics.IEEE Trans.Ultrason.Ferroelectr Freq.Control,2011,58(9):1835-1841.
[63]	Du H L,Liu D J,Tang F S,et al.Microstructure,piezoelectric,and ferroelectric properties of Bi2O3-added (K0.5Na0.5)NbO3 lead-free ceramics.J.Am.Ceram.Soc.,2007,90(9):2824-2829.
[64]	Sun X Y,Chen J,Yu R B,et al.BiScO3 doped (Na0.5K0.5)NbO3 lead-Free piezoelectric ceramics.J.Am.Ceram.Soc.,2009,92(1):130-132.
[65]	Chang Y F,Yang Z P,Wei L L.Microstructure,density,and dielectric properties of lead-free (K0.44Na0.52Li0.04)(Nb0.96-xTaxSb0.04)O3 piezoelectric ceramics.J.Am.Ceram.Soc.,2007,90(5):1656-1658.
[66]	Wang Y,Damjanovic D,Klein N,et al.Compositional inhomogeneity in Li-and Ta-modified (K,Na)NbO3 ceramics.J.Am.Ceram.Soc.,2007,90(11):3485-3489.
[67]	Yang Z P,Chang Y F,Wei L L.Phase transitional behavior and electrical properties of lead-free (K0.44Na0.52Li0.04)(Nb0.96-xTaxSb0.04)O3 piezoelectric ceramics.Appl.Phys.Lett.,2007,90(4):042911-1-3.
[68]	Wang R P,Bando H,Itoh M.Universality in phase diagram of (K,Na)NbO3-MTiO3 solid solutions.Appl.Phys.Lett.,2009,95(9):092905-1-3.
[69]	Zuo R Z,Fu J,Lv D Y.Phase transformation and tunable piezoelectric properties of lead-free (Na0.52K0.48-xLix)(Nb1-x-ySbyTax)O3 system.J.Am.Ceram.Soc.,2009,92(1):283-285.
[70]	Shen Z Y,Zhen Y H,Wang K,et al.Influence of sintering temperature on grain growth and phase structure of compositionally optimized high-performance Li/Ta-Modified (Na,K)NbO3 ceramics.J.Am.Ceram.Soc.,2009,92(8):1748-1752.
[71]	Jaeger R E,Egerton L.Hot pressing of potassium-sodium niobates.J.Am.Ceram.Soc.,1962,45(5):209-213.
[72]	Wang R P,Xie R J,Sekiya T,et al.Fabrication and characterization of potassium-sodium niobate piezoelectric ceramics by spark-plasma-sintering method.Mater.Res.Bull.,2004,39(11):1709-1715.
[73]	Wang K,Zhang B P,Li J F,et al.Lead-free Na0.5K0.5NbO3 piezoelectric ceramics fabricated by spark plasma sintering:Annealing effect on electrical properties.J.Electroceram.,2008,21(1-4):251-254.
[74]	Shen Z Y,Li J F,Wang K,et al.Electrical and mechanical properties of fine-grained Li/Ta-modified (Na,K)NbO3-based piezoceramics prepared by spark plasma sintering.J.Am.Ceram.Soc.,2010,93(5):1378-1383.
[75]	Zhen Y,Li J F,Wang K,et al.Spark plasma sintering of Li/Ta-modified (K,Na)NbO3 lead-free piezoelectric ceramics:Post-annealing temperature effect on phase structure,electrical properties and grain growth behavior,Mater.Sci.Eng.B-Adv.Funct.Solid-State Mater.,2011,176(14):1110-1114.
[76]	Shen Z Y,Li J F,Chen R,et al.Microscale 1-3-Type (Na,K)NbO3-based Pb-free piezocomposites for high-frequency ultrasonic transducer applications.J.Am.Ceram.Soc.,2011,94(5):1346-1349.
[77]	Chang Y F,Poterala S F,Yang Z P,et al.< 001 > textured (K0.5Na0.5)Nb0.97Sb0.03)O3 piezoelectric ceramics with high electromechanical coupling over a broad temperature range.Appl.Phys.Lett.,2009,95(23):232905-1-3.
[78]	Chang Y F,Poterala S F,Yang Z P,et al.Microstructure development and piezoelectric properties of highly textured CuO-doped KNN by templated grain growth.J.Mater.Res.,2010,25(4):687-694.
[79]	Chang Y,Poterala S,Yang Z,et al.Enhanced electromechanical properties and temperature stability of textured (K0.5Na0.5)NbO3-based piezoelectric ceramics.J.Am.Ceram.Soc.,2011,94(8):2494-2498.
[80]	Yao J J,Li J F,Viehland D,et al.Aging associated domain evolution in the orthorhombic phase of< 001 > textured (K05Na0.5)Nb0.97Sb0.03O3 ceramics.Appl.Phys.Lett.,2012,100:132902-1-3.
[81]	Li Y L,Hui C,Wu M J,et al.Textured (K0.5Na0.5)NbO3 ceramics prepared by screen-printing multilayer grain growth technique.Ceram.Int.,2012,38:S283-S286.
[82]	Lv D Y,Zuo R Z.Evolution of crystallographic grain orientation and anisotropic properties of (K0.5Na0.5)NbO3 ceramics using BaTiO3 templates by reactive templated grain growth.J.Alloys Compd.,2013,560:62-66.
[83]	Kawada S,Kimura M,Higuchi Y,et al.(K,Na)NbO3-based multilayer piezoelectric ceramics with nickel inner electrodes.Appl.Phys.Express,2009,2(11):111401-1-3.
[84]	Kobayashi K,Doshida Y,Mizuno Y,et al.A route forwards to narrow the performance gap between PZT and lead-free piezoelectric ceramic with low oxygen partial pressure processed (Na0.5K0.5)NbO3.J.Am.Ceram.Soc.,2012,95(9):2928-2933.
[85]	Zhang S J,Xia R,Shrout T R,et al.Piezoelectric properties in perovskite 0.948(K0.5Na0.5)NbO3-0.052LiSbO3 lead-free ceramics.J.Appl.Phys.,2006,100(10):104-108.
[86]	Hollenstein E,Damjanovic D,Setter N.Temperature stability of the piezoelectric properties of Li-modified KNN ceramics.J.Eur.Ceram.Soc.,2007,27(13/14/15):4093-4097.
[87]	Morozov M I,Kungl H,Hoffmann M J.Effects of poling over the orthorhombic-tetragonal phase transition temperature in compositionally homogeneous (K,Na)NbO3-based ceramics.Appl.Phys.Lett.,2011,98(13):132908-1-3.
[88]	Zhang S J,Xia R,Shrout T R.Modified (K0.5Na0.5)NbO3 based lead-free piezoelectrics with broad temperature usage range.Appl.Phys.Lett.,2007,91(13):132913-1-3.
[89]	Wu J G,Xiao D Q,Wang Y Y,et al.Improved temperature stability of CaTiO3-modified[(K0.5Na0.5)0.96Li0.04](Nb0.91Sb0.05Ta0.04)O3 leadfree piezoelectric ceramics.J.Appl.Phys.,2008,104(2):024102-1-4.
[90]	Zhao J B,Du H L,Qu S B,et al.Improvement in the piezoelectric temperature stability of (K0.5Na0.5)NbO3 ceramics.Chinese Sci.Bull.,2011,56(22):2389-2393.
[91]	Ge H,Hou Y T,Rao X,et al.The investigation of depoling mechanism of densified KNbO3 piezoelectric ceramic.Appl.Phys.Lett.,2011,99(3):032905-1-3.
[92]	Chang Y F,Yang Z P,Hou Y T,et al.Effects of Li content on the phase structure and electrical properties of lead-free (K0.46-x/2Na0.54-x/2Lix)(Nb0.76Ta0.20Sb0.04)O3 ceramics.Appl.Phys.Lett.,2007,90(23):232905-1-3.
[93]	Zhao P,Zhang B P,Li J F.High piezoelectric d33 coefficient in Li-modified lead-free (Na,K)NbO3 ceramics sintered at optimal temperature.Appl.Phys.Lett.,2007,90(24):242909-1-3.
[94]	Du H L,Zhou W C,Luo F,et al.An approach to further improve piezoelectric properties of (K0.5Na0.5)NbO3-based lead-free ceramics.Appl.Phys.Lett.,2007,91(20):202907-1-3.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网