采用传统的固相烧结法制备了Yn(Ba08Bi0.2)1-nFe0.9Sn0.1O3负温度系数热敏陶瓷.借助X射线衍射分析仪、扫描电镜、阻温测试仪和交流阻抗分析仪对这类热敏陶瓷的物相、显微结构、阻温特性和阻抗特征进行了表征分析.所得L(Ba0.8Bi0.2)1-nFe0.9Sn0.1O3热敏陶瓷为伪立方钙钛矿结构,粒度约1.0 μm,随Y含量增加晶格常数a变小;其室温电阻率、热敏常数和活化能分别介于2.17～9.17 MΩ·cm、6757～7171 K和0.583～0.618 eV范围内,且均随Y含量增加趋于增大.阻抗分析表明,在n=0.02、0.04时,陶瓷体电阻由晶界、晶壳和晶粒电阻构成,其中晶粒电阻贡献最大;而在n=0.06、0.08时,陶瓷体电阻由晶界、畴壁和电畴三个部分构成,其中电畴区域电阻贡献最大;在限定的测量温度范围内,晶界、晶壳、晶粒、畴壁和畴电阻均表现出负温度系数热敏行为.
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