随着化石能源日益匮乏,生物质热裂解制备生物油广受关注.然而,生物油中含有大量酚、呋喃、醛、酮等含氧化合物,含氧量高达50％,导致其热值低、化学稳定性差等,因而阻碍了它的广泛应用,必须对其进行加氢脱氧精制降低含氧量.在生物油中众多含氧化合物中,酚羟基氧被认为是最难被脱除的.对酚类含氧化合物加氢脱氧催化剂及反应进行了简单综述,并提出了如何进一步提高催化剂性能的有效方法.
参考文献
| [1] | 徐向阳.能源供应安全视角下中印生物质能源利用的比较[J].自然资源学报,2010(10):1806-1812. |
| [2] | Huber G W;Iborra S;Corma A .[J].Chemical Reviews,2006,106:4044. |
| [3] | Furimsky E. .Catalytic hydrodeoxygenation [Review][J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2000(2):147-190. |
| [4] | Zakzeski, J.;Bruijnincx, P.C.A.;Jongerius, A.L.;Weckhuysen, B.M. .The catalytic valorization of lignin for the production of renewable chemicals[J].Chemical Reviews,2010(6):3552-3599. |
| [5] | 姚勇,邸敏艳.国内外清洁汽车汽油的现状及发展趋势[J].小型内燃机与摩托车,2008(03):93-96. |
| [6] | 王树荣,骆仲泱,谭洪,洪军,董良杰,方梦祥,岑可法.生物质热裂解生物油特性的分析研究[J].工程热物理学报,2004(06):1049-1052. |
| [7] | Crossley S;Faria J;Shen M;Resasco D E .[J].Science,2010,327:68. |
| [8] | Li Ch L;Xu Z R;Gates B C .[J].Industrial & Engineering Chemistry Process Design and Development,1985,24:92. |
| [9] | Vuori A;Helenius A;Bredenberg J B S .[J].Applied Catalysis,1989,52:41. |
| [10] | Ferrari M;Bosmans S;Maggi R;Delmon B Grange P .[J].Catalysis Today,2001,65:257. |
| [11] | Ferrari M.;Delmon B.;Grange P.;Maggi R. .Influences of the hydrogen sulfide partial pressure and of a nitrogen compound on the hydrodeoxygenation activity of a CoMo/carbon catalyst[J].Journal of Catalysis,2001(1):47-55. |
| [12] | Viljava T.-R. .Effect of H_2S on the stability of CoMo/Al_2O_3 catalysts during hydroxygenation[J].Catalysis Today,2000(1/2):83-92. |
| [13] | Senol O I;Ryymin E M;Viljava T R;Krause A O I .[J].Journal of Molecular Catalysis A:Chemical,2007,277:107. |
| [14] | Ryymin E M;Honkela M L;Viljava T R;Krause A O I .[J].Applied Catalysis A:General,2010,389:114. |
| [15] | Laurent E;Delmon B .[J].Applied Catalysis A:General,1994,109:77. |
| [16] | Laurent E;Delmon B .[J].Industrial and Engineering Chemistry Research,1993,32:2516. |
| [17] | Badawi, M.;Paul, J.F.;Cristol, S.;Payen, E.;Romero, Y.;Richard, F.;Brunet, S.;Lambert, D.;Portier, X.;Popov, A.;Kondratieva, E.;Goupil, J.M.;El Fallah, J.;Gilson, J.P.;Mariey, L.;Travert, A.;Maugé, F. .Effect of water on the stability of Mo and CoMo hydrodeoxygenation catalysts: A combined experimental and DFT study[J].Journal of Catalysis,2011(1):155-164. |
| [18] | Odebunmi E O;Ollis D F .[J].Journal of Catalysis,1983,80:56. |
| [19] | Odebunmi E O;Ollis D F .[J].Journal of Catalysis,1983,80:65. |
| [20] | Odebunmi E O;Ollis D F .[J].Journal of Catalysis,1983,80:76. |
| [21] | Wandas R;Surygata J;Sliwka E .[J].Fuel,1996,75:687. |
| [22] | Bredenberg J B;Huuska M;Toropainen P .[J].Journal of Catalysis,1989,120:401. |
| [23] | Gevert B S;Otterstedt J E;Massoth F E .[J].Applied Catalysis,1987,31:119. |
| [24] | Gevert S B;Eriksson M;Eriksson P;Massoth F E .[J].Applied Catalysis A:General,1994,117:151. |
| [25] | Centeno A.;Delmon B.;Laurent E. .INFLUENCE OF THE SUPPORT OF COMO SULFIDE CATALYSTS AND OF THE ADDITION OF POTASSIUM AND PLATINUM ON THE CATALYTIC PERFORMANCES FOR THE HYDRODEOXYGENATION OF CARBONYL, CARBOXYL, AND GUAIACOL-TYPE MOLECULES[J].Journal of Catalysis,1995(2):288-298. |
| [26] | de la Puente G;Gil A;Pis J J;Grange P .[J].Langmuir,1999,15:5800. |
| [27] | Yang Y Q;Tye C T;Smith K J .[J].Catalysis Communications,2008,9:1364. |
| [28] | Yang Y Q;Luo H A;Tong G Sh;Kevin J S Tye C T .[J].Chinese Journal of Chemical Engineering,2008,16:733. |
| [29] | Romero Y;Richard F;Brunet S .[J].Applied Catalysis B:Environmental,2010,98:213. |
| [30] | Bui V N;Laurenti D;Delichère P;Geantet C .[J].Applied Catalysis B:Environmental,2011,101:246. |
| [31] | Bui V N;Laurenti D;Afanasiev P;Geantet C .[J].Applied Catalysis B:Environmental,2011,101:239. |
| [32] | Gutierrez A;Kaila R K;Honkela M L;Slioor R Krause A O I .[J].Catalysis Today,2009,147:239. |
| [33] | Ruiz P E;Leiva K;Garcia R;Reyes P Fierro J L G Escalona N .[J].Applied Catalysis A:General,2010,384:78. |
| [34] | Zhao C;Kou Y;Lemonidou A A;Li X B Lercher J A .[J].Angewandte Chemie International Edition,2009,48:3987. |
| [35] | Zhao, C.;He, J.;Lemonidou, A.A.;Li, X.;Lercher, J.A. .Aqueous-phase hydrodeoxygenation of bio-derived phenols to cycloalkanes[J].Journal of Catalysis,2011(1):8-16. |
| [36] | Zhao, C;Kou, Y;LemonDEou, AA;Li, XB;Lercher, JA .Hydrodeoxygenation of bio-derived phenols to hydrocarbons using RANEY (R) Ni and Nafion/SiO2 catalysts[J].Chemical communications,2010(3):412-414. |
| [37] | Yan N;Yuan Y;Dykeman R;Kou Y A Dyson P J .[J].Angewandte Chemie International Edition,2010,49:5549. |
| [38] | Hong D Y;Miller S J;Agrawal P K;Jones C W .[J].Chemical Communications,2010,46:1038. |
| [39] | Lin Y C;Li C L;Wan H P;Lee H T Liu C F .[J].Energy and Fuels,2011,25:890. |
| [40] | González-Borja M A;Resasco D E .[J].Energy and Fuels,2011,25:4155. |
| [41] | Yang Y;Gilbert A;Xu C .[J].Applied Catalysis A:General,2009,360:242. |
| [42] | Whiffen V M L;Smith K J .[J].Energy and Fuels,2010,24:4728. |
| [43] | Gandarias I;Barrio V L;Requies J;Arias P L Cambra J F Güemez M B .[J].International Journal of Hydrogen Energy,2008,33:3485. |
| [44] | Echeandia S;Arias P L;Barrio V L;Pawelec B Fierro J L G .[J].Applied Catalysis B:Environmental,2010,101:1. |
| [45] | Sepúlveda C;Leiva K;García R;Radovic L R Ghampson I T DeSisto W J Fierro J L G Escalona N .[J].Catalysis Today,2011,172:232. |
| [46] | Wang W Y;Yang Y Q;Bao J G;Luo H A .[J].Catalysis Communications,2009,11:100. |
| [47] | Wang W Y;Yang Y Q;Luo H A;Liu W Y .[J].Reac Kinet Mechan Catal,2010,101:105. |
| [48] | 王威燕,杨运泉,罗和安,王锋,胡韬,刘文英.La-Ni-Mo-B非晶态催化剂的制备、加氢脱氧性能及失活研究[J].燃料化学学报,2011(05):367-372. |
| [49] | Wang W Y;Yang Y Q;Luo H A;Hu T Liu W Y .[J].Catalysis Communications,2011,12:436. |
| [50] | Wang W Y;Yang Y Q;Luo H A;Hu T Liu W Y .[J].React Kinet Mechan Catal,2011,102:207. |
| [51] | 王威燕,杨运泉,罗和安,彭会左,张小哲,胡韬.Ni-Co-W-B非晶态催化剂的制备及其加氢脱氧性能[J].催化学报,2011(10):1645-1650. |
| [52] | Wang W Y;Yang Y Q;Luo H A;Peng H Z Wang F .[J].Industrial and Engineering Chemistry Research,2011,50:10936. |
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