以废弃椰壳为原料,经炭化和磺化制得新型固体磺酸催化剂,用于催化各种芳醛与间苯二酚的缩合反应,以较高收率(49%～95%)制得一系列杯[4]芳烃化合物,产物结构经IR、~1H NMR和MS测试技术表征得以确证.
A novel solid sulfonic acid was prepared from coconut shell via carbonization and sulfonation and used as a catalyst for the condensation of aldehydes and resorcinol, and calix[4]resorcinarenes were prepared rapidly in good yield(49%～95%). The structures of the target compounds were confirmed by IR, ~1H NMR and MS.
参考文献
| [1] | Shinkai S,Mori S,Koreishi H,Tsubaki T,Manabe O.J Am Chem Soc[J],1986,108(9):2 409 |
| [2] | Perret A,Lazar A N,Coleman A W.Chem Commun[J],2006,23:2 425 |
| [3] | YANG Fa-Fu(杨发福),ZHENG Lin-Lu(郑林禄),JI Yan-Qing(季衍卿),LIN Jian-Rong(林建荣),PENG Qi(彭奇).Chinese J Appl Chem(应用化学)[J],2006,23(6):691 |
| [4] | Timmerman P,Verboom W,Reinhoudt D N.Tetrahedron[J],1996,52(8):2 663 |
| [5] | GONG Lin-Bo(龚林波),GONG Shu-Ling(龚淑玲),DONG Hai-Qing(董海青),ZHANG Chun-Lei(张春雷),CHEN Yuan-Yin(陈远荫).Chinese J Appl Chem(应用化学)[J],2006,23(9):1 023 |
| [6] | Dubberley S R,Blake A J,Mountford P.Chem Commun[J],1997,17:1 603 |
| [7] | Tunstad L M,Tucker J A,Dalcanale E,Weiser J,Bryant J A,Sherman J C,Helgeson R C,Knobler C B,Cram D J.J Org Chem[J],1989,54:1 305 |
| [8] | Roberts B A,Gareth W V Cave,Colin L Raston,Janet L S.Green Chem[J],2001,3:280 |
| [9] | YIN Du-Lin(尹笃林),XU Qiong(徐琼),MAO Li-Qiu(毛丽秋),LAN Zhi-Li(兰支利),WANG Ji-Hui(王季惠),WANG Yi-Juan(王艺娟),ZHANG Feng(张锋).ZL 200 610 032 187.9[P],2006 |
| [10] | Wilson K,Lee A F,Macquarrie D J,Clark J H.Appl Catal A[J],2002,228:127 |
| [11] | YU Kun(于昆),LI Hong(李红).Chem World(化学世界)[J],2008,5:792 |
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