合成了低聚度烷氧磺酸锂盐(LiSA(EO)n)和对称星形醚(STEO)增塑剂,并制备了聚环氧乙烷(PEO)基聚合物电解质.研究了 PEO16+LiSA(EO)n体系的锂离子迁移数和电导率与锂盐结构的关系,实验结果表明,LiSA(EO)n代替LiClO4作为锂盐时,其电导率得到提高,而且聚合物电解质的锂离子迁移数随着烷氧磺酸锂盐阴离子体积的增大而增加,并且其中PEO16+LiSA(EO)2体系的锂离子迁移数达到0.35.STEO可明显地提高PEO16-LiSEO-STEO体系的电导率,PEO16-LiSAEO-20%STEO室温电导率可达到0.5×10-4S/cm.通过DSC实验结果表明,STEO的加入,可有效降低聚合物电解质体系的熔融温度和结晶度,PEO16-LiSAEO-20%STEO电化学稳定窗口在4.4 V以上,可满足锂电池的应用要求.
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