以偏硼酸锂和草酸亚铁为原料,采用固相反应,合成了用于动力锂离子电池新型正极材料LiFeBO<,3>,并用乙丙共聚物(EPM)对该材料进行包覆保护处理;采用XRD、SEM和元素分析等测试技术对样品进行表征.实验表明.LiFeBO<,3>具有较高的放电重量比容量,而且包覆EPM后的硼酸铁锂具有更好的电化学性能,5%EPM包覆的硼酸锂首次放电容量达190 mA·h/g,0.5 C下充放电循环50次后容量衰减只有4.2%.
参考文献
[1] | Padhi A K,Nanjundaswamy K S,Goodenough J B.Phospho-olivines as Positive Elect Rode Materials for Rechargeable Lithium Batteries[J].J Electrochem Soc,1997,144(4):1188-1194. |
[2] | Prosini P P,Zane D,Pasquali M.Improved Electrochemical Performance of a LiFePO<,4> Based Composite Cathode[J].Electrochim Acta,2001,46(23):3517-3523. |
[3] | Andersson A S,Thomas J O.The Source of First Cycle Capacity Loss in LiFePO<,4>[J].J Power Source,2001,97/98:498-502. |
[4] | Takahashi M,Tobishima S,Takei K,et al.Characterization of LiFePO<,4> as the Cathode Material of Rechargeable Lithium Batteries[J].J Power Source,2001,97/98:508-511. |
[5] | Prosini P P,Lisi M,Scaccia S,et al.Synthesis and Characterization of Amorphous Hydrated FePO<,4> and Its Electrode Performance in Lithium Batteries[J].J Electrochem Soc,2002,149(3):A297-A301. |
[6] | Yang S,Zavalij P Y,Whittingham M S.Hydro-thermal Synthesis of Lithium Iron Phosphate Cathodes[J].Electrochem Commun,2001,3(9):505-508. |
[7] | Yamada A,Chung S C,Hinokuma K.Optimized LiFePO<,4> for Lithium Battery Cathodes[J].J Electrochem SOc,2001,148(3):A224-A229. |
[8] | Yamada A,Kudo Y,Liu K Y.React Ion Mechanism of the Livine Type Li<,x>(Mn<,0.6>Fe<,0.4>)PO<,4>[J].J Electrochem Soc,2001,148(7):A747 -A754. |
[9] | Yamada A,Chung S C.Crystal Chemistry of the Olivine Type Li(Mn<,y>Fe<,1-y>)PO<,4> and (Mn<,y>Fe<,1-y>)PO<,4> as Possible 4 V Cathode Materials for Lithium Batteries[J].J Electrochem Soc,2001,148(8):A960-A967. |
[10] | Yamada A,Kudo Y,Liu K Y.Phase Diagram of Li (Mn<,y>Fe<,1-y>)PO<,4> (0 ≤ y ≤ 1)[J].J Electrochem Soc,2001,148(10):A1153-A1158. |
[11] | Huang H,Yin S C,Nazar L F.Approaching Theoretical Capacity of LiFePO<,4> at Room Temperature at High Rates[J].J Electrochem Solid State Lett,2001,4(10):A170-A172. |
[12] | Reed J,Ceder G.Role of Electranic Structure in the Susceptibility of Metastable Transition-metal Oxide Structures to Trans-formation[J].Chem Rev,2004,104(10):4513-4533. |
[13] | Islam M S,Driscoll D J,Fisher C A J,et al.Atomic-scale Investigation of Defects,Dopants,and Lithium Transport in the LiFePO<,4> Olivine-type Battery Mater[J].Chem Mater,2005,17(20):5085-5092. |
[14] | Delaeourt C,Poizot P,Levasseur S,et al.Size Effects on Carbon-free LiFePO<,4> Powders[J].Electrochem Solid State Lett,2006,9:A352-A355. |
[15] | Wang L,Zhou F,Meng Y S.First -principles Study of Surface Properties of LiFePO<,4>:Surface Energy,Structure,Wulff Shape,and Surface Redox Potential[J].Phys Rev,2007,76(16):1-11 |
[16] | Ong S P,Wang L,Kang B,et al.Li-Fe-P-O<,2> Phase Diagram from First Principles Calculations[J].Chem Mater,2008,20(5):1798-1807. |
[17] | Atsuo Yamada,Nobuyuki Iwane,Yu Harada,et al.Lithium Iron Borates as High-Capacity Battery Electrodes[J].Adv Mater,2010,22(32):3583-3587. |
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