用熔融挤出的方法制备了甘油塑化热塑性淀粉(TPS)/聚乙烯醇(PVA)/蒙脱土(MMT)纳米复合材料,添加蒙脱土和聚乙烯醇用以提高热塑性淀粉材料的力学性能.在相对湿度50%的条件下,复合材料的XRD衍射谱图和透射电子显微镜测试表明,MMT以剥离状态均匀分布在TPS/PVA基体中;力学测试表明,当MMT的质量分数从0%增至5%时,复合材料的力学性能明显提高.当蒙脱土的质量分数为3%时,复合材料最大抗张强度达到13.24 MPa,杨氏模量达到61.46 MPa.这说明蒙脱土在复合材料中可以起到物理交联点的作用,提高了复合材料的力学性能.
参考文献
[1] | Piyapom K,Duangdao A,Duanghathai P,et al.Preparation of Cassava Starch/montmorillonite Composite Film[J].Carbohydr Polym,2007,67(2):155-163. |
[2] | Huang M F,Yu J G,Ma X F.Studies on the Properties of Montmorillonite-reinforcod Thermoplastic Starch Composites[J].Polymer,2004,45:7017-7023. |
[3] | Viviana P C,Liliana B M,Minhtan T T,et al.Physical and Mechanical Properties of Thermoplastic Starch/montmorillonite Nanocomposite Films[J].Carbohydr Polym,2008,73(1):55-63. |
[4] | Katherine M D,My D D,Eustathios P,et al.Key Interactions in Biodegradable Thermoplastic Starch/poly (vinyl alcohol) /montmorillonite Micro-and Nanocomposites[J].Compos Sci Technol,2008,68(6):1453-1462. |
[5] | Frédéric C,Eric P,Patrice D.Starch-based Nano-biocomposites:Plasticizer Impact on the Montmorillonite Exfoliation Proceas[J].Carbohydr Polym,2010,79(4):941-947. |
[6] | Katherine D,Long Y,Dong Y W.Preparation and Characterization of Melt-extruded Thermoplastic Starch/clay Nanocomposites[J].Carbohydr Polym,2010,80(1):145-153. |
[7] | SHEN Xiaofeng,QIAN Zhongzhong,ZHANG Weian,et al.Thermal Properties and Dynamic Mechanical Behavior of Poly (ethylene-co-vinyl acetate)/Montmorillonite Nanocomposites Prepared by Melt-blending[J].Chinese J Appl Chem,2004,21(10):1042-1045 (in Chinese).沈效峰,钱中中,张伟安,等.熔融法制备EVA/OMMT纳粹复合材料及其热性能和动态力学性能[J].应用化学,2004,21(10):1042-1045. |
[8] | Hadi A,Bahak G,Ali A E.Physicochemical Properties of Stareh-CMC-nanoclay Biodegradable Films[J].Int J Biol Macromol,2010,46(1):1-5. |
[9] | Huang Mingfu,Yu Jiugao,Ma Xiao,et al.High Performance Biodegradable Thermoplastic Starch-EMMT Nanoplastics[J].Polymer,2005,46:3157-3162. |
[10] | Suprakas S R,Masami O.Polymer/layered Silicate Nanocomposites:A Review from Preparation to Processing[J].Prog Polym Sci,2003,(28):1539-1641. |
[11] | Park H M,Li X C,Jin C Z,et al.Preparation and Properties of Biodegradable Thermoplastic Starch/clay Hybrids[J].Macromol Mater Eng,2002,287:553-558. |
[12] | MA Xiaofei,YU Jiugao.Thermoplastic Starch Plasticized by the Mixture of Urea and Formamide[J].Acre Polym Sin,2004,(4):483-489(in Chinese).马骁飞,于九皋.尿素和甲酰胺塑化热塑性淀粉[J].高分子学报,2004,(4):483-489. |
[13] | Yu Yuanhsiang,Lin Chingyi,Yeh Juiming,et al.Preparation and Properties of Poly (vinyl alcohol) -clay Nanocomposite Materials[J].Polymer,2003,44:3553-3560. |
[14] | QIAO Xiuying,ZHOU Wei,SUN Kang,et al.The Effect of Mintmorillonite on the Structures and Properties of Montmorillonite/Starch Composites[J].Polym Mater Sci Eng,2005,21(3):201-203 (in Chinese).乔秀颖,周维,孙康,等.蒙脱土填充相对蒙脱土/淀粉复合材料结构和性能的影响[J].高分子材料科学与工程,2005,21(3):201-203. |
[15] | Pandey J K,Reddy K R,Kumar A P.An Overview on the Degradability of Polymer Nanocomposites[J].Polym Degrad Stab,2005,88:234-250. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%