合成了3,5-二硝基水杨酸铕配合物(EuDNS)及其聚合物材料,通过元素分析和红外光谱等测试技术推测了配合物的结构,考察了配合物的用量和聚合物基质对聚合物材料荧光性能的影响.结果表明,配合物EuDNS可能存在的螯合杂环结构使其有较宽的紫外吸收,且与其荧光激发波长能较好的吻合,能发射很强的稀土Eu3+离子特征红光；当EuDNS质量分数为0.25％时,EuDNS/PMMA(甲基丙烯酸甲酯)聚合物材料仍有很强的荧光强度；3种不同聚合物基质中,最强发射峰强度顺序为:P(MMA-co-St)＞PMMA＞P(MMA-coAA),丙烯酸(AA)共聚单体会强烈猝灭材料发光；EuDNS对MMA/St自由基共聚有阻聚和缓聚作用,随苯乙烯(St)的比例提高,阻聚作用增大,且材料透明性降低；与EuDNS配合物相比,EuDNS/PMMA聚合物材料形成后表观荧光寿命延长了467.5μs.
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