以辛烯基琥珀酸淀粉钠和油酸甲酯分别为替代乳化剂和溶剂,采用浓缩乳化法制备了高度稳定的2.5%高效氯氟氰菊酯水乳剂,通过测定乳液油滴粒径分布,结合乳液外观研究了乳化方法、预处理液中辛烯基琥珀酸淀粉钠质量分数、转速和剪切时间等工艺条件对乳液稳定性的影响.研究结果表明,辛烯基琥珀酸淀粉钠对油酸甲酯具有较好乳化效果,以其为乳化剂可制备高度稳定的2.5%高效氯氟氰菊酯水乳剂,油滴平均粒径在1.2 μm左右,且加速试验[即(54±2)℃密封14 d]和常温储存6个月后平均粒径仅增长了0.1~0.3μm,外观无变化;采用浓缩乳化法且预处理液中辛烯基琥珀酸淀粉钠质量分数在15%~25%时乳液稳定性较好,提高转速可降低油滴平均粒径,但对乳液均一性无显著影响,延长剪切时间对油滴平均粒径影响不大,但有利于提高乳液均一性;辛烯基琥珀酸淀粉钠为乳化剂制备的高效氯氟氰菊酯水乳剂稳定性优于常规水乳剂.
参考文献
[1] | LIU Zhanshan,LI Xujun,CAI Xiangheng. Research Status and Development Trends of Water-based Formulations of Pesticide in China[J].Pestic Sci Admin,2008,29 (7):42-45 (in Chinese).刘占山,李旭君,蔡湘衡.我国水基性农药剂型研究现状及其发展动向[J].农药科学与管理,2008,29(7):42-45. |
[2] | HUA Naizhen.Problems and Solutions of Unsafe Additive in Pesticide Formulation[J].Mod Agrochem,2009,8(4):3-7(in Chinese).华乃震.农药剂型中非安全添加物的问题和对策[J].现代农药,2009,8(4):3-7. |
[3] | WANG Zhengwu,LI Ganzuo,ZHANG Xiao,et al.The Development of Study on Degradation of Surfactants[J].China Surfactant Deterg Cosmet,2001,6(5):32-36(in Chinese).王正武,李干佐,张笑,等.表面活性剂降解研究进展[J].日用化学工业,2001,6(5):32-36. |
[4] | LEI Ming,LIAO Baihan.Progress of Application and Ecotoxicity of Surfactants[J].J Safe Environ,2004,4 (7):27-30 (in Chinese).雷鸣,廖柏寒.表面活性剂的生态毒理学及其应用研究进展[J].安全与环境学报,2004,4(7):27-30. |
[5] | MA Lili,WU Houbin,LIU Fengmao.The Development Hazards and Management of Pesticide Adjuvants[J].Pesticide,2008,47(9):637-640(in Chinese).马立利,吴厚斌,刘丰茂.农药助剂及其危害与管理[J].农药,2008,47(9):637-640. |
[6] | HUANG Qiang,LUO Xingfa,LI Lin.Emulsification and Rheology Properties of Starch Sodium Octenylsucc Inate[J].J South China Univ Technol,2005,33(11):42-45(in Chinese).黄强,罗兴发,李琳.辛烯基琥珀酸淀粉钠的乳化性和流变性[J].华南理工大学学报,2005,33(11):42-45. |
[7] | LING Guanting.Handbook of Food Additives[M].Beijing:Chemical Industry Press,2000:883-884 (in Chinese).凌关庭.食品添加剂手册[M].北京:化学工业出版社,2000:883-884. |
[8] | XU Hanhong.Plant Chemical Protection[M].Beijing:China Agricultural Press,2007:82-87 (in Chinese).徐汉虹.植物化学保护学[M].北京:中国农业出版社,2007:82-87. |
[9] | LIN Bo,LI Dongqin.Determination of 26% Phoxim and Lambda-cyhalothrin EC by HPLC[J].Technol Dev Chem Ind,2005,34(3):33-40(in Chinese).凌波,李东芹.高效液相色谱法检测26%辛·高效氯氟氰菊酯乳油用量[J].化工技术与开发,2005,34(3):33-40. |
[10] | LU Bin,WU Wei.Optimization of Preparation of Dexamethasone Acetate-Loaded Poly(D,L-lactide) Microspheres by Central Composite Design[J].Acta Pharm Sin,1999,34 (5):387-391 (in Chinese).陆彬,吴伟.中心多点等距设计法优化醋酸地塞米松聚丙交酯微球的制备工艺[J].药学学报,1999,34(5):387-391. |
[11] | GUO Wuli.Liquid Formulation[M].Beijing:Chemical Industry Press,2003:90(in Chinese).郭武棣.液体制剂[M].北京:化学工业出版社,2003:90. |
[12] | Varona S,Martin A,Jose M.Formulation of a Natural Biocide Based on Lavandin Essential Oil by Emulsification Using Modified Starches[J].Chem Eng Proc,2009,48:1121-1128. |
[13] | Chanamai R,McClements D J.Dependence of Creaming and Rheology of Monodisperse Oil-in-water Emulsions on Droplet Size and Concentration[J].Colloid Interface Sci A,2000,172:79-86. |
[14] | ZHANG Hongguang,DONG Shouping,JIANG Xuemei.Mechanism of Deformation and Breakup of Single Drop in a Shear or an Extensional Flow[J].Sci Technol Eng,2006,6(24):3896-3899(in Chinese).张红光,董守平,姜雪梅.剪切或拉伸流场中油滴的变形和破裂准则[J].科学技术与工程,2006,6(24):3896-3899. |
[15] | Sajjadi S.Formation of Fine Emulsions by Emulsification at High Viscosity or Low Interfacial Tension; A Comparative Study[J].Colloid Interface Sci A,2007,299:73-78. |
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