结合发电厂凝汽器不锈钢管内壁腐蚀部位分布规律和腐蚀外貌特征,分别对腐蚀部位沉积物、内壁蚀孔附近管材成分进行扫描电子显微镜观察和能谱分析,探讨了管材中MnS溶解与微生物对凝汽器不锈钢管腐蚀的电化学反应机理,发现二者在点蚀形成过程中具有协同作用,并在综合分析影响不锈钢腐蚀的各种因素的基础上,提出了不锈钢凝汽器在运行过程中应采取的防护措施.
参考文献
[1] | LIANG Lei,XIU Sigang,ZHU Yunpeng,et al.Study on the Corrosion of 304 Stainless Steel Tube for Condenser[J].Turbine Technol,2007,49(1):78-81 (in Chinese).梁磊,修思刚,朱云鹏,等.304不锈钢管凝气器腐蚀原因研究[J].汽轮机技术,2007,49(1):78-81. |
[2] | Ralph D E,Stevenson J M.The Role of Bacteria Inwall Clogging[J].Water Res,1995,29:365-369. |
[3] | Baker M A,Castle J E.The Initiation of Pitting Corrosion at MnS Inclusions[J].Corros Sci,1993,34(4):667-682. |
[4] | Williams D E,Newman R C,Song Q,et al.Passivity Breakdown and Pitting Corrosion of Binary Alloys[J].Nature,1991,350:216-219. |
[5] | Zheng S J,Wang Y J,Zhang B,et al.Identification of MnCr2O4 Nano-octahedron in Catalysing Pitting Corrosion of Austenitic Stainless Steels[J].Acta Mater,2010,58:5070-5085. |
[6] | YANG Ning,REN Sulian,SONG Weibo.Mucous Cells in the Alimentary Tract of Meretrix Meretrix[J].J Fish China,2005,29(4):461-466(in Chinese).杨宁,任素莲,宋微波.文蛤消化道粘液细胞研究[J].水产学报,2005,29(4):461-466. |
[7] | XIE Qun.Influence of Microbial Corrosion and Chlorine Biocide in Cooling Water of Stainless Steel Condenser Tube[J].East China Electr Power,2002,(9):30-32(in Chinese).解群.冷却水中微生物腐蚀及含氯杀生剂对凝汽器不锈钢管的影响[J].华东电力,2002,(9):30-32. |
[8] | LI Xing.Problems and Countermeasures in Using the Condenser of Stainless Steel Tube[J].Tianjin Electr Power Technol,2008,(4):18-19(in Chinese).李兴.不锈钢凝汽器管使用中的问题与对策[J].天津电力技术,2008,(4):18-19. |
[9] | WANG Fang,XU Xuping,ZHENG Xiaodan,et al.Influencing Factors of Manganese Oxidation of Manganese Bacterium[J].J Fujian Teachers Univ(Nat Sci),2010,26(2):111-114(in Chinese).王芳,许旭萍,郑晓丹,等.锰细菌氧化锰的影响因素研究[J].福建师范大学学报(自然科学版),2010,26(2):111-114. |
[10] | QIN Songyan,MA Fang,HUANG Peng.Ferrous-Manganese Oxidizing Bacteria from the Nature Water[J].Environ Sci,2008,29 (6):1649-1654 (in Chinese).秦松岩,马放,黄鹏.自然水体中铁-锰氧化细菌的研究[J].环境科学,2008,29(6):1649-1654. |
[11] | Wranglen G.Pitting and Sulphide Inclusions in Steel[J].Corros Sci,1974,14(5):331-349. |
[12] | Dieter D,Wemer S.Is Dissolved Mn2+ Being Oxidized by O2 in Absence of Mn-Bacteria or Surface Catalysts?[J].Geochim Cosmochim Acta,1984,48(7):1571-1573. |
[13] | HAO Ruixia,PENG Shenglin.Bacterial Oxidation and Accumulation of Manganese[J].Mar Geol Quat Geol,1998,18 (2):69-74(in Chinese).郝瑞霞,彭省临.细菌对锰的氧化和聚集作用[J].海洋地质与第四纪地质,1998,18(2):69-74. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%