欢迎登录材料期刊网

材料期刊网

高级检索

采用双氨基硅烷偶联剂KH-792对盐酸改性凹凸棒土(HATT)进行改性,使用FTIR、TGA、DSC、XRD和BET等对目标产物(KHATT)进行了表征.研究了KHATT对模拟水样中Cr(Ⅵ)的吸附性能,系统考察了模拟水样中Cr(Ⅵ)的初始浓度、pH值、吸附时间及KHATF用量等因素对Cr(Ⅳ)去除率的影响.结果表明,在KHATT用量为3 g/L、吸附时间为40 min、pH值为5.5的条件下,KHATT对Cr(Ⅵ)的去除率最高,达85.15%;且KHATT经再生后第4次的吸附量仍可达到第1次吸附量的90%以上.对吸附的过程和机理进行了初步探讨.

参考文献

[1] WANG Jiusi,HE Zhaozhao,GUO Lixin,et al. Preparation of Composite Flocculant (Polyfertic Silicate Sulfate and Chitosan) and Its Application in Wastewater Treatment[J].Chinese J Appl Chem,2011,28(1):27-32(in Chinese).王九思,何兆照,郭立新,等.聚硅酸硫酸铁/壳聚糖复合絮凝剂的制备及其在废水处理中的应用[J].应用化学,2011,28(1):27-32.
[2] LIU Wan,LI Zeqin.Progress on Research of Treating Cr Containing Wastewater[J].Guangdong Trace Elem Sci,2007,14(9):5-8(in Chinese).刘婉,李泽琴.水中铬污染治理的研究进展[J].广东微量元素科学,2007,14(9):5-8.
[3] CHEN Tianhu.A Discussion on the Adsorption Mechanism of Palygorskite Clay to Pollutants in Wastewater[J].Geol J China Univ.2000.6(2):265-269(in Chinese).陈天虎.凹凸棒石粘土吸附废水中污染物机理探讨[J].高校地质学报,2000,6(2):265-269.
[4] YU Zhixin,LU Ziyang,ZHAO Xiaohong,et al.Attapulgite Modification and Its Application in Environmental Water Treatment[J].Bull Chinese Ceram Soc,2010,29(6):1367-1372(in Chinese).于志新,逯子扬,赵晓红,等.凹凸棒土改性及其在环境水处理中的应用研究[J].硅酸盐通报,2010,29(6):1367-1372.
[5] MENG Qingsen,SHI Zongli,WANG Shunhua.Attapulgite Surface Modification and Its Applicationin the Wastewater Treatment[J].BullChinese Ceram Soc,2008,25(7):996-999(in Chinese).孟庆森,石宗利,王顺花.凹凸棒土表面改性及其在废水处理中的应用[J].硅酸盐通报,2008,25(7):996-999.
[6] Cai Y,Xuea J,Polya D A.A Fourier Transform Infrared Spectroscopic Study of Mg-rich,Mg-poor and Acid Leached Palygorskites[J].Spectrochim Acta Part A,2007,66:282-288.
[7] Barrios M S,Gonzales L V F,Rodriguez M A V,et al.Acid Activation of A Palygorskite with HCI Development of PhysicChemical,Textural and Surface Properties[J].Appl Clay Sci,1995,10:247-258.
[8] GAO Hua,LI Cun,WU Zhenyu,et al.Study on Preparation of Acid Modified Attapulgite/manganese Oxide Composites[J].Non-Met Mines,2010,33(2):35-38(in Chinese).高华,李村,吴振玉,等.酸改性Att/氧化锰复合材料的制备研究[J].非金属矿,2010,33(2):35-38.
[9] Wang L H,Sheng J.Graft Polymerization and Characterization of Butyl Acrylate onto Silane-Modified Attapulgite[J].JMacromol Sci:Pure Appl Chem,2003,40A:1135-1146.
[10] PENG Shuchuan,XIE Jingjing,QING Chengsong,et al. Photocatalysis Oxidation Process of Acid Fuchsine Dyestuff Wastewater by Titania Coated Palygorskite[J].J Chinese Ceram Soc,2006,34(10):1208-1212(in Chinese).彭书传,谢晶晶,庆承松,等.负载TiO2凹凸棒石光催化氧化法处理酸性品红染料废水[J].硅酸盐学报,2006,34(10):1208-1212.
[11] Juang R S,Shao H J.A Simplified Equilibrium Model for Sorption of Heavy Metal Ions from Aqueous Solutions on Chitosan[J].Water Res,2002,36:2999-3008.
[12] Bicak N,Sherrington D C,Senkal B F.Graft Copolymer of Acrymamide onto Cellulose as Mercury Selective Sorbent[J].React Funct Polym,1999,41:69-76.
[13] Guibal E,Milot C,Tobin J M.Metal-Anion Sorption by Chitosan Beads:Equilibrium and Kinetic Studies[J].Ind Eng Chem Res,1998,37:1454-1463.
[14] Yavuz H,Denizli A,Gungunes H,et al.Biosorption of Mercury on Magnetically Modified Yeast Cells[J].Sep Purif Technol,2006,52:253-260.
[15] Chen H,Wang A Q.Kinetic and Isothermal Studies of Lead Ion Adsorption onto Palygorskite Clay[J].J Colloid Interface Sci,2007,307:309-316.
[16] YANG Hui,NING Haili,PEI Liang.Properties Study on Ammonia Nitrogen Adsorption of Attapulgite[J].Chinese J Environ Eng,2011,5(2):343-346(in Chinese).杨慧,宁海丽,裴亮.凹凸棒土的氨氮吸附性能研究[J].环境工程学报,2011,5(2):343-346.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%