在弱酸性介质中,采用阴离子交换法合成了类球形的谷氨酸( Glu)/镁铝层状双氢氧化物(MgAlLDH)复合物,研究了介质pH值对所得Glu/LDH纳米复合物性质和形貌的影响.结果表明,与碱性介质中阴离子交换法得到的不规则六角形粒子相比,该法制备的纳米粒子呈类球形,且粒径较小,最佳pH值为5.0,探讨了可能的反应机理.
参考文献
| [1] | REN Lingling,HE Jing,DUAN Xue.The Relationship between Memory Effect and Composition of Layered Double Oxide in Penicillin G Acvlase[J].Chinese J Appl Chem,2001,18(11):853-856(in Chinese).任玲玲,何静,段雪.酶作用下双金属复合氧化物记忆效应与其组成的关系[J].应用化学,2001,18(11):853-856. |
| [2] | Li S P,Xu J J,Chen H Y. New Layered Double Hydroxides Containing Intercalated Au Particles:Synthesis and Characterization[J].Mater Lett,2005,59 (16):2090-2093. |
| [3] | XING Ying,LI Dianqing,REN Lingling,et al.Assembly and Structural Characteristics of Supramolecular Salicylate-pillared Hvdrotalcites[J].Acta Chim Sin,2003,61 (2):267-272(in Chinese).邢颖,李殿卿,任玲玲,等.超分子结构水杨酸根插层水滑石的组装及结构与性能研究[J].化学学报,2003,61(2):267-272. |
| [4] | ZHANG Weifeng,LI Dianqing,SUN Meng,et al.Supramolecular Assembly of Methyl Orangepillared Hydrotalcite and Its Light and Thermal Stability[J].Chem J Chinese Univ,2004,25 (10):1799-1803 (in Chinese).张伟峰,李殿卿,孙勐,等.超分子结构甲基橙插层水滑石的组装及其光热稳定性研究[J].高等学校化学学报,2004,25(10):1799-1803. |
| [5] | CAO Genting,ZHANG Feng,LI Dan,et al.Synthesis,Characterization and Release of Supramolecular Materials of Glutamic Acid Intercalated Zn/Al Layered Double Hydroxides[J].J Chinese Ceram Soc,2007,35(11):1546-1550(in Chinese).曹根庭,张峰,李丹,等.谷氨酸柱撑Zn/Al水滑石超分子材料的合成表征及缓释[J].硅酸盐学报,2007,35(11):1546-1550. |
| [6] | Li S P,Xu J J,Zhao G,et al.Influence of Molar Ratio of Zn/Al/Tyr on the Formation of Tyr/Zn-Al-LDH Nanohybrids[J].Chinese J Chem,2005,23(10):1343-1347. |
| [7] | Choy J H,Kwak S Y,Jeong Y J,et al.Inorganic Layered Double Hydroxides as Nonviral Vectors[J].Angew Chem Int Ed,2000,39(2):4041-4045. |
| [8] | Choy J H,Kwak S Y,Park J S,et al.Intercalative Nanohybrids of Nucleoside Monophosphates and DNA in Layered Metal Hydroxide[J].J Am Chem Soc,1999,121(6):1399-1400. |
| [9] | CEN Fangfang,SHA Zhaolin,LU Tianhong.Influence of Exchange Time on Structure and Thermal Stability of Glutamic Acid/ZnAl Layered Double Hydroxides via Ion Exchange Method[J].Chinese J Appl Chem,2010,27 (5):553-557 (in Chinese).岑芳芳,沙兆林,陆天虹.交换时间对离子交换法合成谷氨酸/锌铝层状双氢氧化物的结构和热稳定性的影响[J].应用化学,2010,27(5):553-557. |
| [10] | Aisawa S,Takahashi S,Ogasawara W,et al. Direct Intercalation of Amino Acids into Layered Double Hydroxides by Coprecipitation[J].J Solid State Chem,2001,162(1):52-62. |
| [11] | WU Zheng,WEI Min,ZHANG Fazhi,et al.Controllable Study of Interlayer Distance of Tartaric Acid Intercalated LDHs[J].J Beijing Univ Chem Technol,2004,31(4):74-77(in Chinese).吴正,卫敏,张法智,等.酒石酸插层水滑石层间距的可控性研究[J].北京化工大学学报,2004,31(4):74-77. |
| [12] | Reinholdt M X,Kirkpatrick R J K.Experimental Investigations of Amino Acid-Layered Double Hydroxide Complexes:Glutamate-Hydrotalcite[J].J Chem Mater,2006,18(10):2567-2576. |
| [13] | Steven P,Cristina T D,Coveney P V.Molecular Dynamics Simulation of Cationic and Anionic Clays Containing Amino Acids[J].Langmuir,2002,18(7):2933-2939. |
| [14] | Vaysse C L,Guerious-Demourgues G,Delmas C.Thermal Evolution of Carbonate Pillared Layered Hydroxides with (Ni,L)(L =Fe,Co) Based Slabs:Grafting or Nongafting of Carbonate Anions[J].Inorg Chem,2002,41 (25):6905-6913. |
| [15] | Li S P.The Dynamic Process in the Formation of Tyr/LDH Nanohybrids[J].Colloids SurfA,2006,290(1):56-61. |
| [16] | REN Lingling,HE Jing,Evans D G,et al.Intercalation and Assembly of Supramolecular Materials of Glutamic Acid Pillared Layered Double Hydroxides[J].Chem J Chinese Univ,2003,24(1):169-173(in Chinese).任玲玲,何静,Evans D G,等.谷氨酸柱撑水滑石超分子结构层柱材料的插层组装[J].高等学校化学学报,2003,24(1):169-173. |
| [17] | Parello M L,Rojas R,Giacomelli C E.Dissolution Kinetics and Mechanism of Mg-Al Layered Double Hydroxides:A Simple Approach to Describe Drug Release in Acid Media[J].J Colloid Interface Sci,2010,351 (1):134-139. |
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