欢迎登录材料期刊网

材料期刊网

高级检索

以3(4)-硝基邻苯二腈和苯酚为原料,经过两步反应合成了α(β)-四苯氧基酞菁锌,通过红外光谱、紫外光谱、核磁共振谱、质谱和元素分析表征了其结构,比较研究其光谱性质.并以旋涂发光层的方法制备了电致发光器件,研究其电致发光性质.固态酞菁材料的光致发光波长红移到866~930nm范围内的近红外波段,β-位取代酞菁发光波长红移的程度比α-位取代酞菁大.2种器件电致发光波长和酞菁固体材料的光致发光波长较接近,分别在880和885nm处.

参考文献

[1] Tessler N,Medvedev V,Kazes M,et al.Efficient Near-infrared Polymer Nanocrystal Lightemitting Diodes[J].Science,2002,295:1506-1508.
[2] Slooff L H,Polman A,Cacialli F,et al.Near-infrared Electroluminescence of Polymer Lightemitting Diodes Doped with a Lissamine-sensitized Nd3+ Complex[J].Appl Phys Lett,2001,78:2122-2124.
[3] Kang T S,Harrison B S,Foley T J,et al.Near-Infrared Electroluminescence from Lanthanide Tetraphenyl Porphyrin:Polystyrene Blends[J].Adv Mater,2003,15:1093-1097.
[4] Sun R G,Wang Y Z,Zheng Q B,et al.Epstein,1.54 μm Infrared Photoluminescence and Electroluminescence from an Enbium Organic Compound[J].Appl Phys Lett,2000,87:7589-7591.
[5] McKeown N B.Phthalocyanine Materials:Synthesis,Structure and Function[M].New York:Cambridge University Press Cambridge,1998:193.
[6] Leznoff C C,Lever A B P.Phthalocyanines:Properties and Applications.Cambridge VCHs[M].VCH Publishers(LSK) Lid;Cambridge.1989.1993.1996;1-4.
[7] Maya E M,Garcia-Frutos E M,Vazquez P,et al.Novel Push-pull Phthalocyanines as Targets for Second-order Nonlinear Applications[J].J Phys Chem A,2003,107:2110-2117.
[8] Collins R A,Mohammed K A.Gas Senstitivity of Some Metal Phthalocyanines[J].J Phys D,1988,21:154-161.
[9] Baldo M A,OBrien D F,You Y,et al.High Efficient Phosphorescent Emission from Organic Electroluminescent Devices[J].Nature,1998,395:151-154.
[10] Peumans P,Uchida S,Forrest S R.Efficient Bulk Heterojunction Photovottaic Cells Using Small-molecular-weight Organic Thin Films[J].Nature,2003,425:158-162.
[11] Suzette A P,Anne R,Winslow S C.Porphyrin and Phthalocyanine Antiscrapie Compounds[J].Science,2000,287:1503-1506.
[12] Fujii A,Ohmori Y,Yoshino K.An Organic Infrared Electroluminescent Diode Utilizing a Phthalocyanine Film[J].IEEE Trans Electron Dev,1997,44:1204-1207.
[13] Cheng C H,Fan Z Q,Yu S K,et al.1.1 μm Near-infrared Electrophosphorescence from Organic Light-emitting Diodes Based on Copper Phthalocyanine[J].Appl Phys Lett,2006,88:213505-1-3.
[14] Somerauer M C,Rager M,Hanack M.Separation of 2(3),9(10),16(17),23(24)-Tetrasubstituted Phthalocyanines with Newly Developed HPLC Phases[J].J Am Chem Soc,1996,118:10085-10093.
[15] Rager C,Schmid G,Hanack M.Influence of Substituents,Reaction Conditions and Central Metals on the Isomer Distributions of 1(4)-Tetrasubstituted Phthalocyanines[J].Chem Eur J,1999,5:280-288.
[16] Sastre A,Gouloumis A,Vázquez P,et al.Phthalocyanine-Azacrown-Fullerene Multicomponent System:Synthesis,Photoinduced Processes and Electrochemistry[J].Org Lett,1999,1(11):1807-1810.
[17] Baldassare D B.Spectroscopy of the Excited State[M].New York:Plenum Press,1972:340.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%