合成了具有较高荧光量子产率(0.69)和良好光稳定性的可聚合荧光染料单体,该荧光染料的光稳定性高于商品化的染料罗丹明B.通过氧化还原引发剂引发乳液聚合制备了超细荧光聚合物纳米微球,将染料分子共价连接在聚合物链上.使用非离子表面活性剂Triton X-100作为乳化剂、甲基丙烯酸甲酯(MMA)作为单体和助乳化荆,制备的超细纳米微球平均粒径为22nm,而不加MMA时制备出的纳米微球平均粒径在150nm左右.由于微球表面带有苄氯基团,为进一步的微球功能化提供了途径.
参考文献
[1] | Barner L.Synthesis of Microspheres as Versatile Functional Scaffolds for Materials Science Applications[J].Adv Mater,2009,21(29):2547-2553. |
[2] | Song H,He R,Wang K,et al.Anti-HIF-1 Alpha Antibody-conjugated Pluronic Triblock Copolymers Encapsulated with Paclitaxel for Tumor Targeting Therapy[J].Biomaterials,2010,31(8):2302-2312. |
[3] | Goddard J M,Hotchkiss J H.Polymer Surface Modification for the Attachment of Bioactive Compounds[J].Prog Polym Sci,2007,32(7):698-725. |
[4] | Zhang P,Liu W G.ZnO QD@PMAA-co-PDMAEMA Nonviral Vector for Plasmid DNA Delivery and Bioimaging[J].Biomaterials,2010,31(11):3087-3094. |
[5] | ZHAO Chunshan.Study on Preparation of Polymerized Fluorescent Microsphere and Fluorescent Gel[D].Changchun:Jilin University,2009(in Chinese).赵春山.聚合物荧光微球及荧光凝胶的制备研究[D].长春:吉林大学,2009. |
[6] | Kawaguchi H.Functional Polymer Microspheres[J].Prog Polym Sci,2000,25(8):1171-1210. |
[7] | MA Guanghui,SU Zhiguo.Polymer Microsphere Materials[M].Beijing:Chemical Industry Press,2005:20(in Chinese).马光辉,苏志国.高分子微球材料[M].北京:化学工业出版社,2005:20. |
[8] | Kong X F,Wu Q,Hu W C,et al.Monodisperse Ultrafine Polystyrene Nanoparticles Prepared by a Semicontinuous Microemulsion Polymerization[J].J Polym Sci Part A:Polym Chem,2008,46(13):4522-4528. |
[9] | Yoshino K,Yokoyama A,Yokozawa T.Synthesis of a Variety of Star-shaped Polybenzamides via Chain-growth Condensation Polymerization with Tetrafunctional Porphyrin Initiator[J].J Polym Sci Part A:Polym Chem,2011,49(4):986-994. |
[10] | Zhao C S,Liu X L,Yang M,et al.The Preparation of Copolymerized Fluorescent Microspheres of Styrene Using Detergentfree Emulsion Polymerization[J].Dyes Pigm,2009,82(2):134-141. |
[11] | Govindaiah P,Jung Y J,Lee J M,et al.Monodisperse and Fluorescent Poly(styrene-co-methacrylic acid-co-2-naphthyl methacrylate)/Fe3O4 Composite Particles[J].J Colloid lnterface Sci,2010,343(2):484-490. |
[12] | Wang B S,Fan J L,Sun S G,et al.1-(Carbamoylmethyl)-3H-indolium Squaraine Dyes:Synthesis,Spectra,Photo-stability and Association with BSA[J].Dyes Pigm,2010,85(1/2):43-50. |
[13] | Chen X Y,Peng X J,Cui A J,et al.Photostabilities of Novel Heptamethine 3H-Indolenine Cyanine Dyes with Different N-Substituents[J].J Photochem Photobiol A:Chem,2006,181(1):79-85. |
[14] | Daisuke O,Yutaka S,Noriko K,et al.Anthrapyridone Coloring Matter,Salt Thereof,Ink Composition and Colored Body:US2011195238[P],2011-08-11. |
[15] | Norilo K,Hiroyuki M.Anthrapyridone Compound or Salt Thereof,Magenta Ink Composition,and Colored Material:WO2010084741[P],2010-07-29. |
[16] | Hiroyuki M,Noriko K,Seiji E.Anthrapyridone Pigment or Salt Thereof,and Ink Composition Containing the Same:JP,2010059217[P],2010-03-18. |
[17] | HE Yuanjun,TIAN He.Synthesis of Novel Copolymeric Laser Dyes and Dichromophoric Copolymer[J].Acta Polym Sin,2000,(3):379-381(in Chinese).何元君,田禾.新型可聚合激光染料及双发色团共聚物的合成[J].高分子学报,2000,(3):379-381. |
[18] | PAN Zuren.Polymer Chemistry[M].Beijing:Chemical Industry Press,2007:108(in Chinese).潘祖仁.高分子化学[M].北京:化学工业出版社,2007:108. |
[19] | Zhang Z L,Long Y,Pan J B,et al.Preparation of Fluorescence-encoded Microspheres in a Core-shell Structure for Suspension Arrays[J].J Mater Chem,2010,20(6):1179-1185. |
[20] | YIN Yi,NIU Aopan,LI Guangtian,et al.Synthesis of Anthrapyridone Solvent Dyes and Their Solubility[J].Dyestuffs Color,2003,40(4):191-192(in Chinese).尹益,钮敖盘,李光天,等.蒽吡啶酮类溶剂染料的合成和溶解性能的研究[J].染料与染色,2003,40(4):191-192. |
[21] | Martinez V M,Arbeloa F L,Prieto J B,et al.Characterization of Rhodamine 6G Aggregates Intercalated in Solid Thin Films of Laponite Clay.2-Fluorescence Spectroscopy[J].J Phys Chem B,2005,109(15):7443-7450. |
[22] | Moadhen A,Elhouichet H,Nosova L,et al.Rhodamine B Absorbed by Anodic Porous Alumina:Stokes and Anti-Stokes Luminescence Study[J].J Lumin,2007,126(2):789-794. |
[23] | Antonietti M,Bremser W,Muschenborn D,et al.Synthesis and Size Control of Polystyrene Lattices via Polymerization in Microemulsion[J].Macromolecules,1991,24(25):6636-6643. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%