合成了一种新型有机硅表面活性剂——聚醚改性二硅烷.首先以( CH3)3SiCl和(CH3)2HSiCl为原料,金属钠作还原偶合剂,二甲苯作溶剂,用Wurtz偶合法合成了含氢二硅烷,对其结构进行了红外光谱、紫外吸收光谱和气相色谱表征,并确定了合成最佳反应条件:n(( CH3)3SiCl)∶n((CH3)2HSiCl)=1.2∶1,反应物浓度为1.8 mol/L,助剂15-冠醚-5用量为总反应原料质量的2％,反应温度为80℃,反应时间为11h.再以合成的含氢二硅烷和甲基封端烯丙基聚醚(Mr=400)为原料,在Karstedt铂催化剂作用下进行硅氢加成反应,合成了聚醚改性二硅烷表面活性剂,确定的合成反应最佳温度为95℃,时间为4h;该表面活性剂的表面张力为22.49 mN/m,临界胶束浓度为0.9 g/L,在pH值为6.94和4.12的水溶液中,具有良好的水解稳定性.
参考文献
| [1] | GU Zhongyan,XU Xiaolong,HAN Lijuan.Study on the Function of Surfactant in the Application of Pesticides[J].Mod Agrochem,2003,2(4):21-23 (in Chinese).顾中言,许小龙,韩丽娟.表面活性剂在农药使用中的作用研究[J].现代农药,2003,2(4):21-23. |
| [2] | SHAO Zhenrun,GUO Yongwang.Situation and Strategies of Spraying Facilities and Pesticide Application Technology in China[J].Plant Prot,2006,32(2):5-8(in Chinese).邵振润,郭永旺.我国施药机械与施药技术现状及对策[J].植物保护,2006,32(2):5-8. |
| [3] | Randal M H.Silicone Surfactants-new Developments[J].Curr Opin Colloid Interface Sci,2002,(7):255-261. |
| [4] | Peter J G.Organosilicon Surfactants as Adjuvants for Agrochemicals[J].Pestic Sci,1993,38:103-122. |
| [5] | LI Xianghong.Trisiloxane Surfacetant[J].Silicone Mater,2004,18 (1):32-34 (in Chinese).李祥洪.三硅氧烷表面活性剂[J].有机硅材料,2004,18(1):32-34. |
| [6] | XU Xiaohua,JIAO Qingze,ZHANG Qiang.Synthesis of Amino Modified Polyether-silicone Surfactant for Agrochemical Additives and Its Applisd Properteries[J].Agrochemicals,2007,46(4):235-237(in Chinese).许晓华,矫庆泽,张强.氨基聚醚改性有机硅助剂的合成及性能[J].农药,2007,46(4):235-237. |
| [7] | YU Chunxin,XUE Zhanqiang,LI Xuefeng,et al.Application of Silicone Surfactants for Pesticide Adjuvants in the Word[J].J Chinese Agrochem,2007,(4):21-24(in Chinese).于春欣,薛占强,李学锋,等.农用有机硅表面活性剂在世界范围内的应用[J].中国农药,2007,(4):21-24. |
| [8] | HAN Fu.Synthesis and Properties of Novel Trisiloxane Surfactans[D].Wuhan:Wuhan University,2004(in Chinese).韩富.新型三硅氧烷表面活性剂的合成及表征[D].武汉:武汉大学,2004. |
| [9] | YIN Danna,ZHENG Cheng,ZHANG Liping,et al.Synthesis and Characterization of Polyether Modifisd Trisiloxanes[J].CIESC J,2010,61 (6):1565-1570(in Chinese).尹丹娜,郑成,张利萍,等.聚醚改性三硅氧烷表面活性剂的合成与表征[J].化工学报,2010,61(6):1565-1570. |
| [10] | Mark D L,PENG Wenqing,George A P,et al. Hydrolysis Resistant Organomodified Silyated Surfactants:US,20070249560A1[P].2007-10-25. |
| [11] | Mark D L,George A P,Suresh K R.Hydrolysis Resistant Organomodified Disiloxane Surfactants:US,7507775B2[P].2009-03-24. |
| [12] | Kumada M,Ishikawa M,Sajiro M.Preparation of Some Derivatives of Disilane,Trisilane and Tetrasilane[J].J Organomet Chem,1964,2:478-484. |
| [13] | Maki H,Saeki S,Ikeda I,et al.Faculty of Engineering,Syntheses and Properties of Suffactants Containing Organometals:Ⅳ[J].J Am Oil Chem,Soc,1969,46:635-638. |
| [14] | ZHAO Yancui.Synthesis and Application of Karstedt Catalyst Used for Hydrosilylation[D].Hangzhou:Zhejiang University,2006 (in Chinese).赵延翠.硅氢加成Karstedt催化剂的合成及应用[D].杭州:浙江大学,2006. |
| [15] | Boury B,Bryson N.Borate Catalyzed Thermolysis of Polymethylsilane[J].Chem Mater,1998,10:297-303. |
| [16] | Timokhin V I,Zaborovskii A B,Ferreri K,et al.Liquid-Phase Oxidation of Pentamethyldisilane with Oxygen[J].Russ J Gen Chem,2004,74(3):469. |
| [17] | Smith A L.Analysis of Silicones[M].New York:Wiley,1974:247. |
| [18] | Richard G J,Wataru A,Julian C. Silicon-Containing Polymers-The Science and Technology of Their Synthesis and Applications[M].Holland:Kluwer Academic Publishers,2000:379. |
| [19] | Burger C,Hertler W R,Kochs P,et al.Silicon in Polymer Synthesis[M].Beijing:World Pubhshing Corporation,1998:245. |
| [20] | CHEN Deben,LI Gaoquan,FU Hejian,et al.Studies on the Synthesis and Characterization of Polysilane Copolymers[J].J Sichuan Univ,1997,34 (5):673-677 (in Chinese).陈德本,李高全,傅鹤鉴,等.聚硅烷共聚物的合成及表征的研究[J].四川大学学报,1997,34(5):673-677. |
| [21] | XING Xin,LI Xiaodong,LIU Lin,et al.Synthesis and Characterization of Trimethylsilyl-Substtuted Polysilane[J].Acta Polym Sin,2007,(5):428-433(in Chinese).邢欣,李校东,刘琳,等.三甲基硅基取代聚硅烷的合成与性能研究[J].高分子学报,2007,(5):428-433. |
| [22] | Miller R D,Thompson D,Sooriyakumaran R,et al.The Synthesis of Soluble,Substituted Silane High Polymers by WurtzCoupling Techniques[J].J Polym Sci:Part A:Polym Chem,1991,29 (7):813-820. |
| [23] | XUE Lianbao,JIN Guantaihe.Theory and Application of Anionic Polymerization[M].Beijing:China Friendship Publishing Company,1990:19,85 (in Chinese).薛联宝,金关泰合.阴离子聚合的理论和应用[M].北京:中国友谊出版公司,1990:19,85. |
| [24] | LI Jinhui,CHEN Lai,PAN Jianfeng,et al.Effects of Additives on Wurtz Polymerization of Dimethyldicholorosilane[J].Silicone Mater,2005,19(2):5-8(in Chinese).李金辉,陈来,潘健峰,等.助剂对二甲基二氯硅烷Wurtz聚合反应的影响[J].有机硅材料,2005,19(2):5-8. |
| [25] | HU Huiping,HUANG Kelong,PAN Chunyue,et al.Studies on Syntheses and Characterizations of Polysilanes[J].Polym Mater Sci Eng,2001,17 (2):149-153(in Chinese).胡慧萍,黄可龙,潘春跃,等.聚硅烷的合成,表征及光敏性研究[J].高分子材料科学与工程,2001,17(2):149-153. |
| [26] | ZHOU Junchang,REN Yujuan,WANG Xurong.Synthesis of Alkyl Siloxane[C]//The Senventh Nantional Symposium on Printing and Dyeing Post-processing.Wuxi:Wuxi Keguang Silicone New Material Institute.2008:344-348 (in Chinese).周军昌,任玉娟,王绪荣.长链烷基硅油的制备[C]//第七届全国印染后整理学术研讨会.无锡:无锡科光有机硅材料研究所,2008:344-348. |
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