合成了顺丁烯二酸酐酯化β-环糊精与苯乙烯的共聚物及其金属配合物.利用红外、紫外、元素分析、差示扫描量热法及热失重分析法对其进行了结构表征和性能测试.这种含有β-环糊精的共聚物金属配合物作为脲酶抑制剂,对大豆脲酶催化尿素水解的抑制效果显著,其铜金属配合物为4 g/L时,抑制率达96.67%.
参考文献
[1] | TONG Linhui.Cyclodextrin Chemistry-Theory and Application[M].Beijing:Science Press,2001:10(in Chinese).童林荟.环糊精化学-基础与应用[M].北京:科学出版社,2001:10. |
[2] | WANG Yongjian,ZHANG Zhengpu,HE Binglin.Polymer Effects of Cyclodextrin Polymer[J].Prog Chem,2000,12(3):318-324(in Chinese).王永健,张政朴,何炳林.环糊精聚合物的高分子效应[J].化学进展,2000,12(3):318-324. |
[3] | SU Xiaodi,LIU Liuzhan,SHEN Hanxi.Studies on the Fluorimetric Molecular Recognition of Schiff Bases Containing Double Aromatic Guests with Water Solubleβ-Cyclodextrin Cross-linking Polymer[J].Chem J Chinese Univ,1997,18(8):1275-1280(in Chinese).苏小笛,刘六站,沈含熙.水溶性β-环糊精交联聚合物对双客体芳香吸附碱的荧光识别作用研究[J].高等学校化学学报,1997,18(8):1275-1280. |
[4] | LONG Yuande,HUANG Tianbao.Enantioselective Permeation of Amino Acids Through β-Cyclodextrin Polymer Membranes[J].Chem J Chinese Univ,1999,20(6):884-886(in Chinese).龙远德,黄天宝.β-环糊精聚合物膜拆分氨基酸对映体[J].高等学校化学学报,1999,20(6):884-886. |
[5] | TANG Kuowen,CHEN Guobin.β-Cyclodextrin Polymer as Stationary Phase in Gas Chromatographic Capillary Columns[J].Chinese.J Appl Chem,2000,17(6):677-679(in Chinese).唐阔文,陈国斌.用β-环糊精聚合物作毛细管气相色谱固定相[J].应用化学,2000,17(6):677-679. |
[6] | HUANG Wensheng,SONG Fajun,JIN Wenwen,et al.Effects of Metallic Complex ofβ-Cyclodextrin Derivative on Activities of Urease[J].J South-Central Uniu Nat(Nat Sci Ed),2000,19(3):76-80(in Chinese).黄文胜,宋发军,金文闻,等.β-环糊精衍生物的金属配合物对脲酶活性的影响[J].中南民族学院学报(自然科学版),2000,19(3):76-80. |
[7] | WANG Tianyuan,SONG Yajun,TENG Pengqi.The Urease of the Inhibitor of Urease[J].Chem Eng,2004,107(8):22-23(in Chinese).王天元,宋雅君,腾鹏起.土壤脲酶及脲酶抑制剂[J].化学工程师,2004,107(8):22-23. |
[8] | Bremner J M,Chai H S.Evaluation of N-Butyl Phosphorothioic Triamide for Retardation of Urea Hydrolysis in Soil[J].Commun Soil Sci Plant Anal,1986,17 (3):337-351. |
[9] | Chai H S,Bremner J M.Evaluation of Some Phosphoroamides as Soil Urease Inhibitors[J].Biol Fert Soils,1987,3(4):189-194. |
[10] | Tarun E T,Rubinov D B,Metelitza D I.Inhibition of Urease by Cyclic β-Triketines and Fluoride Ions[J].BiochemMicrobiol,2004,40(4):337-344. |
[11] | PENG Ren,QIU Yexian.Screening of Urease Inhibitors from Plants[J].J Jiangxi Norm Univ(Nat Sci Ed),2005,29(1):73-76 (in Chinese).彭仁,邱业先.植物性脲酶抑制剂的筛选[J].江西师范大学学报(自然科学版),2005,29(1):73-76. |
[12] | YAN Haiyan,WU Jing.A Extraction Method of Urease Inhibitors:CN,101759481.A[P],2010-06-30(in Chinese).严海燕,吴菁.一种脲酶抑制剂的提取方法:中国,101759481.A[P],2010-06-30. |
[13] | Wang C Y,Ye J Y.Synthesis,Crystal Structures,and Urease Inhibitory Activity of Cooper(Ⅱ) Complexes with Schiff Bases[J].Russ J Coord Chem,2011,37 (3):235-241. |
[14] | ZOU Jing,YU Dezhong,YANG Xianjin,et al.The Extraction of Urease from Glycine Max and Its Application to the Determination of Urea-Nitrogen in Controlled Release Fertilizers[J].J Anal Sci,2004,20 (4):178-180 (in Chinese).邹菁,喻德忠,杨先进,等.黄豆脲酶的提取及其在缓释肥料中尿素态氮测定中的应用[J].分析科学学报,2004,20(4):178-180. |
[15] | The National Chemical Standardization Technical Committee Chemical Reagent Branch.GB/T 601-2002,China Standard Book Number[S].Beijing:Standards Press of China,2002:121-147 (in Chinese).全国化学标准化技术委员会化学试剂分会.GB/T 601-2002中国标准书号[S].北京:中国标准出版社,2002:121-147. |
[16] | Jiang Y,Du L X,Lu F P,et al.Synthesis and Properties of Functionalized β-Cyclodextrin Copolymer and Its Metal Complexes[J].Polym Bull,2006,57:481-489. |
[17] | The National Feed Industry Standardization Technical Committee.GB/T 8622-2006 China Standard Book Number[S].Beijing:Standards Press of China,2006:1-6(in Chinese).全国饲料工业标准化技术委员会.GB/T8622-2006中国标准书号[S].北京:中国标准出版社,2006:1-6. |
[18] | WANG Juan,HE Wenxiang,SUN Tieheng.Soil Urease Activity Affected by Copper[J].J Northwest Sci-Tech Univ Agric (Nat Sci Ed),2007,35(11):135-140(in Chinese).王娟,何文祥,孙铁珩.铜对土壤脲酶活性特性的影响[J].西北农林科技大学学报(自然科学版),2007,35(11):135-140. |
[19] | Manunza B,Deiana S,Pintore M,et al.The Binding Mechanism of Urea,Hydroxamic Acid and N-(N-Butyl)-phosphoric Triamide to the Urease Active Site:A Comparative Molecular Dynamics Study[J].Soil Biol Biochem,1999,31 (5):789-796. |
[20] | QI Desheng,YU Yanhu,ZHAN Zhichun,et al.Inhibitory Effect of Acetohydroxamic Acid on Urease Activity[J].Cereal Feed Ind,2003,(9):33-34 (in Chinese).齐德生,于炎湖,詹志春,等.脲酶抑制剂对脲酶活性的抑制试验[J].粮食与饲料工业,2003,(9):33-34. |
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