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用一锅法合成了4种磺酸酯桥联杯芳烃化合物,用它们作萃取剂,以氯仿为溶剂,用原子吸收的方法测定了它们对水溶性的Ca2+、Pb2+及部分过渡金属10种金属盐的萃取作用.结果表明,此类杯芳烃对Cr3+、Cd2+和Co2+等几种有毒有害的离子有良好的选择性识别作用,其中化合物2a对Cr3+、化合物2b对Cd2+的苯取率分别达到了50.15%和46.48%.

参考文献

[1] YANG Fafu,ZHENG Linlu,JI Yanqing,et al.Syntheses and Cations' Extraction Properties of Poly(aza) Calixarenes and Bis-calixarene[J].Chinese J Appl Chem,2006,23(6):691-693(in Chinese).杨发福,郑林禄,季衍卿,等.多重氮杂杯[4]芳烃和双杯[4]芳烃的合成与阳离子萃取性能[J].应用化学,2006,23(6):691-693.
[2] DU Juan,CHEN Long,FENG Wen,et al.Synthesis of a Cabas-like Calix[4]crown Ether and Its Complexation Towards Cesium Ions[J].Chem Res Appl,2011,23(4):451-456(in Chinese).杜鹃,陈龙,冯文,等.提篮型杯[4]芳烃冠醚的合成及其对铯离子络合性能的研究[J].化学研究与应用,2011,23(4):451-456.
[3] WANG Hao,LI Zhe,LIU Yu.Synthesis and Cation Selectivity of Calix[4]arene with Lower edge Containing Heteroatoms[J].Sci China(Series B:Chem),2007,37(4):350-354(in Chinese).王浩,李喆,刘育.下缘含有杂原子杯[4]芳烃的合成及其阳离子选择性[J].中国科学(B辑:化学),2007,37(4):350-354.
[4] He L,An Y,Yuan L H,et al.Shape-persistent Macrocyclic Aromatic Tetrasulfonamides:Molecules with nanosized Cavities and Their Nanotubular Assemblies in Solid State[J].Proc Nat Acad Sci USA,2006,103(29):10850-10855.
[5] Geng M W,Zhang D C,Wu X X,et al.One-Pot Formation and Characterization of Macrocyclic Aromatic Tetrasulfonates[J].Org Lett,2009,11(4):923-926.
[6] ZHANG Dechun,WANG Wenge.Progress on the Synthesis of Heteroatom-bridged Calixarenes[J].Chem Mater,2011,39(12):22-23,110(in Chinese).张德春,王文革.含多种杂原子的桥联杯芳烃的合成研究进展[J].化工新型材料,2011,39(12):22-23,110.
[7] He L,An Yu,Yuan L H,et al.Macrocyclic Aromatic Tetrasulfonamides with a Stable Cone Conformation[J].Chem Commun,2005,30:3788-3790.
[8] YE Danian,AI Desheng,ZENG Rongshu.Quantitative Relationship of Metallic Radius,Cation Radius and Electric Configuration[J].Sci China(Series B:Chem),1999,29(4):303-310(in Chinese).叶大年,艾德生,曾荣树.金属半径和阳离子半径与电子构型的定量关系[J].中国科学(B辑),1999,29(4):303-310.
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