用水热法合成了过渡金属联吡啶配阳离子硅钨杂多酸:[M(2,2'-bpy)2]2SiW12O40(M=Mn(1)和M=Co(2)),采用红外光谱、元素分析、热重和单晶X射线衍射对其进行了表征.结果表明,化合物1和2是异质同构体,具有二维格子框架结构.初步研究了2种化合物的电催化H2O析出O2性能,发现化合物1对电催化H2O析出O2有一定的催化作用.
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