以马来酸酐(MAH)、聚丙烯蜡(PPW)为主要原料,采用原位固相接枝改性法制得PP/CaCO3-MAH-PPW复合材料,并与添加相容剂聚丙烯接枝马来酸酐(PP-g-MAH)所制得的PP/PP-g-MAH/CaCO3复合材料进行比较.结果表明,CaCO3良好的分散性及其与PP基体适宜的界面粘接是复合材料具有较好韧性的关键因素.与PP/PP-g-MAH/CaCO3复合材料相比,PP/CaCO3-MAH-PPW复合材料表现出更佳的冲击、弯曲和加工性能,当m(PP)∶m(CaCO3)=100∶20时,材料缺口冲击强度达到最大值,是基体树脂的1.19倍.
参考文献
[1] | Krawczak P.Compounding and Processing of Polymer Nanocomposites:From Scientific Challenges to Industrial Stakes[J].Exp Polym Lett,2007,1(4):188. |
[2] | Jordan J,Jacob K I,Tannenbaum R,et al.Experimental Trends in Polymer Nanocomposites:A Review[J].Mater Sci Engine A,2005,393(1/2):1-11. |
[3] | Pérez E,Bernal C,Piacquadio M.Multifractal Analysis of Tensile Toughness and Filler Dispersion for Polypropylene-CaCO3 Composites[J].Appl Surf Sci,2012,258 (22):8940-8945. |
[4] | Yang K,Yang Q,Li G X,et al.Morphology and Mechanical Properties of Polypropylene/Calcium Carbonate Nanocomposites[J].Mater Lett,2006,60(6):805-809. |
[5] | Zhu P,Chen J,Wu C F.Crystallization Behavior and Mechanical Properties of Polypropylene/Modified Carbon Black Composites[J].Polym Compos,2009,30(4):391-398. |
[6] | Lin Y,Chen H B,Chan C M,et al.Nucleating Effect of Calcium Stearate Coated CaCO3 Nanoparticles on Polypropylene[J].J Colloid Interfaace Sci,2011,354(2):570-576. |
[7] | Zhu P,Chen J,Wu C F.Crystallization Behavior and Mechanical Properties of Polypropylene/Modified Carbon Black Composites[J].Polym Compos,2009,30 (4):391-398. |
[8] | Fuad M Y A,Hanim H,Zarina R,et al.Polypropylene/Calcium Carbonate Nanocomposites-Effects of Processing Techniques and Maleated Polypropylene Compatibiliser[J].Exp Polym Lett,2010,4 (10):611-620. |
[9] | Wang Y H,Shen H,Li G,et al.Effect of Inteffacial Interaction on the Crystallization and Mechanical Properties of PP/Nano-CaCO3 Composites Modified by Compatibilizers[J].J Appl Polym Sci,2009,113 (3):1584-1592. |
[10] | WANG Yuhai,ZHANG Zitao,SHEN Hao.Investigation on Interfacial Interaction in Nano-CaCO3/Compatibilizer/Polypropylene Composites[J].Acta Polym Sin,2010,(12):1444-1450 (in Chinese).王玉海,章自涛,沈浩.纳米CaCO3/相容剂/PP中的界面相互作用研究[J].高分子学报,2010,(12):1444-1450. |
[11] | JIN Jianping,ZHANG Hengjing,JIANG Hui.Effect of Compatibilizer on the Properties and Morphology of PP/PP-g-MAH/CaCO3 Composites[J].Plast Sci Technol,2011,39(8):55-58(in Chinese).金建平,张恒靖,蒋辉.增容剂对PP/PP-g-MAH/CaCO3复合材料性能与形态的影响[J].塑料科技,2011,39(8):55-58. |
[12] | JIA Runli,MING Yan,WAN Shun.Reactive Compatibilization and Its Application in Polymer Modification[J].Polym Bull,2003,(3):71-79 (in Chinese).贾润礼,明艳,万顺.几种反应型相容剂及其在聚合物共混改性中的应用[J].高分子通报,2003,(3):71-79. |
[13] | SHENG Yu,ZHU Deqin,WANG Jianfeng.A Preparation Method to Inorganic Powder with "Core-Shell" Structure Through Surface Modification:CN,200710144038.6[P],2007-12-18(in Chinese).生瑜,朱德钦,王剑峰.一种经表面改性制备具有"核-壳"结构的无机粉体的方法:中国,200710144038.6[P],2007-12-18. |
[14] | SHENG Yu,ZHU Deqin,WANG Jianfeng,et al.Calcium Carbonate Surface Coating Modification and Its Effect on the Mechanical Properties of Filled Polypropylene[J].Acta Polym Sin,2008,(8):813-817 (in Chinese).生瑜,朱德钦,王剑峰,等.CaCO3表面包覆改性及其对填充PP力学性能的影响[J].高分子学报,2008,(8):813-817. |
[15] | GB/T 1040-2006.Plastics-Determination of Tensile Properties[S].Beijing:China Standards Press,2006 (in Chinese).GB/T 1040-2006.塑料拉伸性能的测定[S].北京:中国标准出版社,2006. |
[16] | GB/T9341-2000.Plastics-Determination of Flexural Properties[S].Beijing:China Standards Press,2000(in Chinese).GB/T9341-2000.塑料弯曲性能实验方法[S].北京:中国标准出版社,2000. |
[17] | GB/T1043-2008.Plastics-Determination of Charpy Impact Properties[S].Beijing:China Standards Press,2008(in Chinese).GB/T1043-2008.塑料简支梁冲击性能的测定[S].北京:中国标准出版社,2008. |
[18] | GB/T3682-2000.Determination of the Melt Mass-Flow Rate (MFR) and the Melt Volume-Flow Rate (MVR) of Thermoplastics[S].Beijing:China Standards Press,2000 (in Chinese).GB/T3682-2000.热塑性塑料熔体质量流动速率和熔体体质流动速率的测定[S].北京:中国标准出版社,2000. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%