以邻氯溴苯为起始原料,选用K4[Fe(CN)6]为氰基化试剂,Pd/C催化反应制得邻氯苯甲腈.考察了温度、碱、催化剂的用量和原料比等对反应的影响,确定了较佳反应条件.邻氯溴苯转化率达98.5％,产物邻氯苯甲腈得率95.1％.
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