采用化学共沉淀方法合成了柠檬酸化β-环糊精(CA-β-CD)修饰的水基磁流体.运用红外光谱(FTIR)、透射电子显微镜(TEM)、热重分析(TGA)、X射线衍射(XRD)和振动样品磁强计(VSM)对其结构、形貌、组成成分和磁性能进行了表征.结果显示,磁流体粒子分散性良好,粒径分布在(7±2)nm范围;磁流体具有超顺磁性,CA-β-CD修饰前后的饱和磁化值分别为62和43 A·m2/Kg.将磁流体用于染料中性红(NR)的吸附,考察了吸附时间、NR初始浓度及溶液pH值对吸附作用的影响.结果显示,磁流体在中性条件下对NR的吸附效果最佳,最大吸附量为244 mg/g,吸附效率最高可达99.8%.
参考文献
[1] | MA Tao,WU Jingzhi,YANG Lizhen.Preparation Technology and Properties of Nanosized Fe3O4 Magnetic Fluids[J].Mater Mech Eng,2006,30(2):58-60(in Chinese).马涛,吴静芝,杨丽珍.纳米磁性液体的制备和性能[J].机械工程材料,2006,30(2):58-60. |
[2] | Zahn M.Magnetic Fluid and Nanoparticle Applications to Nanotechnology[J].J Nanopart Res,2001,3(1):73-78. |
[3] | XIONG Longrong,WEN Yuhua,YI Cheng,et al.Synthesis and Stability of PEG-coated Fe3O4 Magnetis Fluid[J].Mater Rev,2007,21(zl):195-197 (in Chinese).熊隆荣,文玉华,易成,等.聚乙二醇-4000包覆Fe3O4磁流体的制备及稳定性研究[J].材料导报,2007,21(z1):195-197. |
[4] | HAN Huimin,LI Decai.Research Status and Development Direction Magnetic Liquid Preparation Technology[J].Mech Eng,2007,(2):25-27(in Chinese).韩会敏,李德才.磁流体制备技术的研究现状及发展方向[J].机械工程师,2007,(2):25-27. |
[5] | Elmore W.Ferromagnetic Colloid for Studying Magnedc Structures[J].Phys Rev,1938,54(4):309-310. |
[6] | Goya G.Handling the Particle Size and Distribution of Fe3O4 Nanoparticles Through Ball Milling[J].Solid State Commun,2004,130 (12):783-787. |
[7] | FU Xiaolan,BIAN Xuehai,ZHAO Yaping,et al.Preparation and Study of Nano-scale Fe3O4 and Its Magnetic Fiuids[J].J Donghua Univ(Nat Sci),2011,37 (3):341-345 (in Chinese).符晓兰,卞学海,赵亚萍,等.纳米Fe3 O4颗粒及其磁流体的制备与研究[J].东华大学学报(自然科学版),2011,37(3):341-345. |
[8] | YU Chengbing.Development in Preparation of Water-Based Magnetic Liquid with Chemical Coprecipitation Method[J].New Chem Mater,2006,34:19-22(in Chinese).俞成丙.化学共沉淀法制备水基磁流体的研究进展[J].化工新型材料,2006,34:19-22. |
[9] | GU Pingdao,LI Guoshun,HU Jun.Experimental Study on Treatment of Printing and Dyeing Wastewater by Magnetic Fluid[J].Environ Sci Technol,2013,2,3(Supp2):4-6(in Chinese).顾平道,李国顺,胡君.磁流体处理印染废水的实验研究[J].环境科技,2013,23(增刊2):4-6. |
[10] | DAI Richeng,ZHANG Tong,GUO Xi,et al.Summary of Printing-Dyeing Wastewater Treatment Technology[J].Water Wastewater Eng,2000,26(10):33-36(in Chinese).戴日成,张统,郭茜,等.印染废水水质特征及处理技术综述[J].给水排水,2000,26(10):33-36. |
[11] | LI Yinhuan,ZHANG Xiulan,SHAO Dongyuan,et al.Treatment of Dye Wastewater with Anion-Cation Modified Zeolite[J].J Xinyang Normal Univ(Nat Sci),2011,24(1):127-131 (in Chinese).栗印环,张秀兰,邵东圆,等.阴-阳离子改性沸石处理染料废水[J].信阳师范学院学报(自然科学版),2011,24(1):127-131. |
[12] | Banerjee S,Chen D.Fast Removal of Copper Ions by Gum Arabic Modified Magnetic Nano-Adsorbent[J].J Hazard Mater,2007,147(3):792-799. |
[13] | Iram M,Guo C,Guan Y,et al.Adsorption and Magnetic Removal of Neutral Red Dye from Aqueous Solution Using Fe3O4 Hollow Nanospheres[J].J Hazard Mater,2010,181(1/3):1039-1050. |
[14] | Banerjee S,Chen D.Magnetic Nanoparicles Grafted with Cyclodextrin for Hydrophobic Drug Delivery[J].Chem Mater,2007,19(25):6345-6349. |
[15] | Liao M,Chen D.Preparation and Characterization of a Novel Magnetic Nano-Adsorbent[J].J Mater Chem,2002,12 (12):3654-3659. |
[16] | Khaled E,Gaffar M,Safaa E.Novel Method for Preparation of β-Cyclodextrin/Grafted Chitosan and It's Application[J].Carbohydr Polym,2006,63(2):385-392. |
[17] | Xu X,Shen H,Xu J,et al.The Colloidal Stability and Core-Shell Structure of Magnetite Nanoparticles Coated with Alginate[J].Appl SurfSci,2006,253(4):2158-2164. |
[18] | Caruntu D,Caruntu G,Chen Y,et al.Synthesis of Variable-Sized Nanocrystals of Fe3O4 with High Surface Reactivity[J].Chem Mater,2004,16 (25):5527-5534. |
[19] | ZOU Weihua,BAI Hongjuan,LI Ke,et al.Adsorption Properties and Mechanism of Neutral Red on Natural Zeolite[J].J Zhengzhou Univ(Nat Sci),2011,43(4):71-76(in Chinese).邹卫华,白红娟,李苛,等.天然沸石对阳离子染料中性红的吸附及机理研究[J].郑州大学学报(理学版),2011,43(4):71-76. |
[20] | LEI Xiaoling,HUANG Fang,CHEN Hu,et al.Research on the Adsorption Effect of Activated Carbon on Typical Dyes[J].Ind Water Tteat,2013,33(5):57-60(in Chinese).雷晓玲,黄芳,陈壶,等.活性炭对典型染料的吸附性能研究[J].工业水处理,2013,33(5):57-60. |
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