制备了聚苯乙烯负载型氯化铁催化剂(PS-FeCl3),并通过红外光谱、X射线衍射、扫描电子显微镜等技术手段进行了表征.在PS-FeCl3催化下,以苯乙酮、芳醛和芳胺为原料,采用一锅法Mannich反应合成了一系列β-氨基酮衍生物.制备的催化剂性能稳定,使用4次仍保持较高活性.
参考文献
| [1] | Ting A,Schaus S E.Organocatalytic Asymmetric Mannich Reactions:New Methodology,Catalyst Design,and Synthetic Applications[J].Eur J Org Chem,2007:5797-5815. |
| [2] | XU Xiujuan,CHEN Guangxu.Mannich Reaction of Aromatic Amines[J].Acta Chim Sin,1982,40 (5):63-468 (in Chinese).徐秀娟,陈光旭.芳香胺参加的Mannich反应[J].化学学报,1982,40(5):463-468. |
| [3] | CHEN Guangxu,XU Xiujuan,LIU Lijun.Mannich reaction of Aromatic Amines Synthesis ofβ-Amino Ketones from Aromatic Amine Hydrochloride[J].Chem J Chinese Univ,1982,3:83-90(in Chinese).陈光旭,徐秀娟,刘利军.芳香胺参加的Mannich反应-用芳胺盐酸盐合成β-氨基酮[J].高等学校化学学报,1982,3:83-90. |
| [4] | Manabe K,Kobayashi S.Mannich-type Reactions of Aldehydes,Amines,and Ketones in a Colloidal Dispersion System Created by a Br(o)nsted Acid-surfactant-combined Catalyst in Water[J].Org Lett,1999,1:1965-1967. |
| [5] | Limura S,Nobutou D,Manabe K,et al.Mannich-type Reactions in Water Using a Hydrophobic Polymer-supported Sulfonic Acid Catalyst[J].Chem Commun,2003:1644-1645. |
| [6] | Li J Z,Peng Y Q,Song G H.Mannich Reaction Catalyzed by Carboxyl-functionalized Ionic Liquid in Aqueous Media[J].Catal Lett,2005,102:159-162. |
| [7] | WANG Limin,HAN Jianwei,SHENG Jia,et al.Yb (OTf) 3 Catalyzed Mannich Reaction of Acetophenone with Aromatic Aldehydes and Aromatic Amines:Three Component One-pot Synthesis ofβ-Amino Ketone Derivatives[J].Chinese J Org Chem,2005,25:591-594(in Chinese).王利民,韩建伟,盛佳,等.Yb(OTf)3催化苯乙酮、芳香醛和芳香胺的Mannich反应:三组分“一锅法”合成β-氨基酮衍生物[J].有机化学,2005,25:591-594. |
| [8] | Wang L M,Han J W,Sheng J.Rare Earth Perfluorooctanoate[RE (PFO) 3]Catalyzed One-pot Mannich Reaction:Three Component Synthesis ofβ-Amino Carbonyl Compounds[J].Catal Co mmun,2005,6:201-204. |
| [9] | Aziri N,Torklyan L,Saidi M R.Highly Efficient One-pot Three-component Mannich Reaction in Water Catalyzed by Heleropoly Acids[J].Org Lett,2006,8 (10):2079-2082. |
| [10] | Chang C T,Liao B S,Liu S T.Mannich-type Reactions in a Colloidal Solutionformed by Sodium Tetrakis (3,5-Trifluoromethylphenyl) borate as a Catalyst in Water[J].Tetrahedron Lett,2006,47:9257-9259. |
| [11] | Wang R,Li B G,Huang T K,et al.NbCI5-Catalyzed One-pot Mannich-type Reaction:Three Component Synthesis of β-Amino Carbonyl Compounds[J].Tetrahedron Lett,2007,48(12):2071-2073. |
| [12] | Li Z,Ma X L,Liu J,et al.Silica-supported Alumillum Chloride:A Recyclable and Reusable Catalyst for One-pot Three-component Mannich-type Reactions[J].J Mol Catal A:Chem,2007,272:132-135. |
| [13] | WANG Min,SONG Zhiguo,TIAN Guifu.Synthesis of Multiaryl-substituted β-Amino Ketone Derivatives Catalysed by Aluminium Chloride[J].Chem Bull,2009,6:84-844(in Chinese).王敏,宋志国,田桂馥.氯化铝催化合成多芳基取代β-氨基酮衍生物[J].化学通报,2009,6:841-844. |
| [14] | SONG Zhiguo,LIANG Yan,WANG Min.Synthesis of β-Amino Ketone Derivatives Catalyzed by Aluminium Benzenesulfonate from Acetophenone,Aromatic Aldehydes and Aromatic Amines[J].Chem Res Appl,2010,22(11):1462-1466(in Chinese).宋志国,梁艳,王敏.苯磺酸铝催化苯乙酮、芳香醛和芳香胺合成β-氨基酮衍生物[J].化学研究与应用,2010,22(11):1462-1466. |
| [15] | WANG Min,LIANG Yan,SONG Zhiguo,et al.Efficient One-pot Synthesis of Amino Derivatives Catalysted by Aluminium p-Toluenesulfonate under Mild Conditions[J].ChineseJ Org Chem,2010,30(2):295-298(in Chinese).王敏,梁艳,宋志国,等.温和条件下对甲基苯磺酸铝高效催化一锅法合成-氨基同衍生物[J].有机化学,2010,30(2):295-298 |
| [16] | SONG Yang,TANG Xuesong,HOU Xiaomeng,et al.Advances of Iron (Ⅲ) Chloride-catalyzed Organic Reactions[J].Chinese J Org Chem,201,33:76-89 (in Chinese).宋阳,唐雪松,侯晓萌,等.三氯化铁催化的有机反应研究进展[J].有机化学,2013,33:76-89. |
| [17] | ZHENG Changwu,CHAI Zhuo,ZHAO Gang.Polymer-Supported Catalysts Designing,Synthesis and Their Application on Organic Synthetic Reaction[J].Prog Chem,2010,22(7):1442-1456(in Chinese).郑昌武,柴卓,赵刚.高分子负载催化剂的设计、合成及其在有机合成反应中的应用[J].化学进展,2010,22(7):1442-1456. |
| [18] | XlAO Liwei,JING Xuemin,KONG Jie.Synthesis and Catalytic Behaviors Toward Styrene Polymerization of Zinc Complexes Bearing 6-Benzimidazolyl-2-aryliminoethyl Pyridine[J].ChineseJOrg Chem,2013,33(8):1828-1833(in Chinese).肖立伟,景学敏,孔洁.6-苯并咪唑基-2-芳亚胺乙基吡啶锌配合物的合成及其对苯乙烯聚合的催化性能[J].有机化学,2013,33(8):1828-1833. |
| [19] | LIU Fuan,LV Yan,HUANG Huamin.Synthesis of Polymer Catalysts and Its Use for Addition and Esterification Reaction[J].Petrochem Technol,1990,19:814-818(in Chinese).刘福安,吕燕,黄化民.高分子载体FeCl3催化剂的合成及在加成酯化反应中的应用[J].石油化工,1990,19:814-818. |
| [20] | WU Qin,DONG Binqi,HAN Minghan,et al.Synthesis and Characterization of Novel Br(o)nsted Acidic Ionic Liquids[J].Spectrosc Spectr Anal,2007,27(3):2027-2031(in Chinese).吴芹,董斌琦,韩明汉,等.新型Br(o)nsted酸性离子液体的合成与表征[J].光谱学与光谱分析,2007,27(3):2027-2031. |
| [21] | YANG Yali,WANG Xiaohua,KOU Yuan.Determination of Acidity of Ionic Liquids and Alkylation of Isobutane with Butene by Chloroaluminate Ionic Liquids[J].Chinese J Catal,2004,25:60-64(in Chinese).杨雅立,王晓化,寇元.离子液体的酸性测定及其催化的异丁烷/丁烯烷基化反应[J].催化学报,2004,25:60-64. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%