采用反气相色谱法研究了343.15 ～ 373.15 K温度范围内离子液体1-己基-3-甲基咪唑三氟甲磺酸盐([HMIM] OTF)的热力学参数.根据18种探针溶剂的保留时间计算出探针溶剂与[HMIM] OTF之间的摩尔吸附焓、无限稀释的摩尔混合焓、摩尔蒸发焓、质量部分活度系数、Flory-Huggins相互作用参数及[HMIM] OTF的溶解度参数.结果表明,所选溶剂中正构烷烃、四氢呋喃、乙醚、环己烷和苯为[HMIM] OTF的不良溶剂;二氯甲烷、丙酮、氯仿、乙酸乙酯、四氯化碳、乙酸甲酯、甲苯和甲醇为[HMIM] OTF的良溶剂;运用外推法得到了室温(298.15K)时[HMIM] OTF的溶解度参数为20.74 (J/cm3)0.5.本研究为离子液体的应用及相关工作提供了参考.
参考文献
| [1] | Zhu G L.Chinese Journal of Chemical Physics(朱光来.物理化学学报),2011,27(4):971 |
| [2] | Chen Y L,Wang Q,Zhang Z F,et al.Ind Eng Chem Res,2012,51(46):15293 |
| [3] | ChenY L,Wang Q,Deng L S,et al.Chinese Journal of Chromatography(陈亚丽,王强,邓丽霜,等.色谱),2013,31(2):147 |
| [4] | Laali K K,Borodkin G I.J Chem Soc Perkin Trans 2,2002(5):953 |
| [5] | Pu Y,Jiang N,Ragauskas A J.J Wood Chem Technol,2007,27(1):23 |
| [6] | Yu Y.Chinese Journal of Applied Chemistry(于游.应用化学),2011,28(5):602 |
| [7] | Berthod A,Ruiz-Angel M J,Carda-Broch S.J Chromatogr A,2008,1184(1):6 |
| [8] | Manuyama S,Takeyama Y,Taniguchi H,et al.ACS Nano,2010,4(10):5946 |
| [9] | Mejía I,Stanley K,Canales R,et al.J Chem Eng Data,2013,58(9):2642 |
| [10] | Ramanaiah S,Rani P R,Sreekanth T V M,et al.J Macromol Sci B,2011,50(3):551 |
| [11] | Yazici D T,Askin A,Butun V.Chromatographia,2008,67(9/10):741 |
| [12] | Yagi Y,Inomata H,Saito S.Macromolecules,2002,25(11):2997 |
| [13] | Sun Z J,Zhang X Y,Huang H,et al.China Rubber Industry(孙志娟,张心亚,黄洪,等.橡胶工业),2007,54(1):54 |
| [14] | Acree W E Jr,Abraham M H.J Chem Technol Biot,2006,81(8):1441 |
| [15] | Carlisle T K,Bara J E,Gabriel C J,et al.Ind Eng Chem Res,2008,47(18):7005 |
| [16] | Chen Y L,Wang Q,Tang J,et al.Chromatographia,2013,76(1/2):91 |
| [17] | Adamska K,Bellinghausen R,Voelkel A.J Chromatogr A,2008,1195:146 |
| [18] | Papadopoulou S K,Panayiotou C.J Chromatogr A,2012,1229:230 |
| [19] | Diez E,Ovejero G,Romero M D,et al.Fluid Phase Equilibr,2011,308(1/2):107 |
| [20] | Price G J,Shillcock I M.J Chromatogr A,2002,964:199 |
| [21] | Ocak H,Sakar D,Cakar F,et al.Liq Cryst,2008,35(12):1351 |
| [22] | Sreekanth T,Ramanaiah S,Rani P R,et al.Polym Bull,2009,63(4):547 |
| [23] | Cakar F,Cankurtaran O.Polym Bull,2005,55(1/2):95 |
| [24] | Domanska U,KrólikowskiM.J Phys Chem B,2011,115(22):7397 |
| [25] | Du Q,Chen W,Munk P.Macromolecules,1999,32(5):1514 |
| [26] | Adamska K,Voelkel A.Int J Pharm,2005,304(1/2):11 |
| [27] | Ovejero G,Pérez P,Romero M,et al.Eur Polym J,2009,45(2):590 |
| [28] | Yazici O,Sakar D,Cankurtaran O,et al.J Appl Polym Sci,2011,122(3):1815 |
| [29] | Mutelet F,Jaubert J-N.J Chem Thermodyn,2007,39(8):1144 |
| [30] | Papadopoulou S K,Panayiotou C.J Chromatogr A,2012,1229:230 |
| [31] | Liu G Q,Ma L X,Liu J.Handbook of Substances Properties Data in Chemical and Engineering:Organic Volume.Beijing:Chemical Industry Press(刘光启,马连相,项曙光.化学化工物性数据手册:有机卷.北京:化学工业出版社),2002 |
| [32] | Marciniak A.Int J Mol Sci,2010,11(5):1973 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%