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分子间氢键棒状手性液晶因其兼具手性液晶奇特的光电性能和氢键液晶的便捷制备以及独特的外界刺激响应性,在功能材料、非线性光学、生物医学等领域具有潜在的应用价值,一直是超分子液晶领域的研究热点.文章按照形成氢键互补基团的不同,将其划分为3种类型,即羧酸-羧酸类、羧酸吡啶类和其他类型氢键,介绍了此三类氢键棒状手性液晶近年来的研究进展.详细归纳了氢键质子给受体的分子结构、氢键稳定性、手性中心位置、取代基、柔性链长度等对液晶性能的影响,并在此基础上,对其未来发展做了展望.

参考文献

[1] 王新久.液晶光学与液晶显示[M].北京:科学出版社,2006:31-36.
[2] Dhar R.Twisted grain boundary (TGB) phases:nanostructured liquid-crystal analogue of Abrikosov vortex lattices[J].Phase Transitions,2006,79(3):175-199.
[3] Kikuchi H.Liquid Crystalline Blue Phases[M].Kato T.Heidelberg:Springer Berlin,2008:99-117.
[4] Paleos C M,Tsiourvas D.Supramolecular hydrogen-bonded liquid crystals[J].Liq.Cryst.,2001,28 (8):1127-1161.
[5] Kato T,MizoshitaN,KishimotoK.Functional liquid-crystalline assemblies:self-organized soft materials[J].An gew.Chem. Int.Ed.Engl.,2005,45(1):38-68.
[6] Kato T,Frechet J M J.A new approach to mesophase stabilization through hydrogen bonding molecular interactions in binary mixtures[J].J.Am.Chem.Soc.,1989,111(22):8533-8534.
[7] Kato T,Frechet J M J.Stabilization of a liquid-crystalline phase through noncovalent interaction with a polymer side chain[J].Macromolecules,1989,22(9):3818-3819.
[8] Fouquey C,Lehn J M,Levelut A M.Molecular recognition directed self assembly of supramolecular liquid crystal line polymers from complementary chiralcomponents[J].Adv.Mater.,1990,2(5):254-257.
[9] Meyer R B,Liebert L,Strzelecki L.et al.Ferroelectric liquid crystals[J].J.Physique Lett.,1975,36(3):69-71.
[10] Sridevi B,Chalapathi P V,Srinivasulu M,et al.Influence of hydrogen bonding on phase abundance in ferroelectric liquid crystals[J].Liq.Cryst.,2004,31(3):303-310.
[11] Sreedevi B,Chalapathi P V,Kotikalapudi V K M,et al.Tilt angle,spontaneous polarization and LF dielectric relaxation investigations in the chiral nematic and smectic-C* phases of a hydrogen bonded ferroelectric liquid crystal (HBFLC)-11bpa[J].Ferroelectrics,2007,361(1):18-36.
[12] Sreedevi B,Chalapathi P V,Kotikalapudi V K M,et al.Influence of hydrogen bonding on device parameters and field response in N* and SmC* phases of a ferroelectric liquid crystal,HBFLC:12 bpa[J]. Mol. Cryst. Liq.Cryst.,2009,515(1):71-98.
[13] Vijayakumar V N,Madhu Mohan M L N.A study of field induced transitions (FiT) in the nematic phase of an inter hydrogen bonded ferroelectric liquid crystal[J].Solid State Sciences,2010,12(4):482-489.
[14] Vijayakumar V N,Madhu Mohan M L N.Design and characterization of hydrogen bonded ferroelectric liquid crystals:A study of light modulation in nematic and smectic orderings[J].Optik International Journal for Light and Electron Optics,2012,123(12):1044-1050.
[15] Vijayakumar V N,Madhu Mohan M L N.Study of thermal and electrical properties exhibited by two ferroelectric self assembly systems[J].J.Mol.Struct.,2011,991(1-3):60-67.
[16] Vijayakumar V N,Mohan M L N M.Design,synthesis and characterization of hydrogen-bonded ferroelectric liquid crystals[J].Mol.Cryst.Liq.Cryst.,2010,524(1):54-67.
[17] Vijayakumar V N,Mohan M L N M.Synthesis and characterization of double hydrogen bonded ferroelectric liquid crystals exhibiting reentrant smectic ordering[J].Ferroelectrics,2009,392(1):81-97.
[18] Vijayakumar V,Madhu Mohan M.Experimental evidence of an optical shutter in cholesteric phase of a double hydrogen bonded liquid crystal[J].Brazilian Journal of Physics,2009,39(4):677-683.
[19] Vijayakumar V N,Madhu Mohan M L N.Double hydrogen bonded ferroelectric liquid crystals:A study of field in duced transition (FiT)[J].Solid State Commun,2009,149(45 46):2090-2097.
[20] Vijayakumar V N,Mohan M L N M.Study of optical shutter in cholesteric phase of a double hydrogen-bonded ferroelectric liquid crystal with two chiral carbons[J].Mol.Cryst.Liq.Cryst.,2010,528(1):163-177.
[21] 李文,白宗庆,白进,等.原位漫反射新方法研究煤中氢键的分解动力学[J].燃料化学学报,2011,39(5):321-327.
[22] Kato T,Kihara H,Uryu T,et al.Hydrogen-bonded ferroelectric liquid crystalline complexes based on a chiral benzoic acid and stilbazoles.induction of chiral smectic C phases by molecular self-assembly[J].Ferroelectrics,1993,148(1):161-167.
[23] Kihara H,Kato T,Uryu T,et al.Supramolecular ferroelectric liquid crystals. Hydrogen-bonded complexes between benzoic acids and chiral stilbazoles[J].Liq.Cryst.,1996,21(1):25-30.
[24] Yu L J.Hydrogen bond induced ferroelectric liquid crystals[J].Liq.Cryst.,1993,14(5):1303-1309.
[25] Tian Y,Su F,Zhao Y,et al.Synthesis and variable-temperature FTIR study of five chiral liquid crystals induced by intermolecular hydrogen bonding[J].Liq.Cryst.,1995,19(6):743-748.
[26] Tian Y,Xu X,Zhao Y,et al.Temperature-dependent FTIR study on self-assembly chiral liquid crystals through intermolecular hydrogen bonding[J]. Thin Solid Films,1996,284:603-605.
[27] Grunert M,Alan Howie R,Kaeding A,et al.Supramolecular chiral liquid crystals.The liquid crystalline behaviour of mixtures of 4,4[prime or minute]-bipyridyl and 4-[(S)-(-)-2-methylbutoxy]benzoic acid[J].J.Mater.Chem.,1997,7(2):211-214.
[28] Chen F,Guo J,Qu Z,et al.Novel photo-polymerizable chiral hydrogen-bonded self-assembled complexes:Preparation,characterization and the utilization as a thermal switching reflective color film[J].J.Mater Chem.,2011,21(24):8574.
[29] He W,Pan G,Yang Z,et al.Wide blue phase range in a hydrogen-bonded self-assembled complex of chiral fluorosubstituted benzoic acid and pyridine derivative[J].Adv.Mater.,2009,21(20):2050-2053.
[30] Yelamaggad C V,Bonde N L,Achalkumar A S,et al.Frustrated liquid crystals:synthesis and mesomorphic behavior of unsymmetrical dimers possessing chiral and fluorescent dntities[J]. Chem. Mater.,2007,19 (10):2463-2472.
[31] Yelamaggad C V,Shanker G,Hiremath U S,et al.Cholesterol-based nonsymmetric liquid crystal dimers:an overview[J].J.Mater.Chem.,2008,18(25):2927.
[32] Mallia V A,Tamaoki N.Design of chiral dimesogens containing cholesteryl groups; formation of new molecular organizations and their application to molecular photonics[J].Chem.Soc.Rev.,2004,33(2):76-84.
[33] Yelamaggad C V,Nagamani S A,Hiremath U S,et al.Cholesterol-based dimeric liquid crystals:synthesis and me somorphic behaviour[J].Liq.Cryst.,2001,28(7):1009-1015.
[34] Wu C.Synthesis and characterization of a novel series of unsymmetric dimesogenic compounds containing cholesteryl ester and nitroazobenzene moieties[J].Mater.Lett.,2007,61(6):1380-1383.
[35] Wu C C.Synthesis and liquid crystalline properties of a series of cholesterol-based dimesogenic compounds[J].Liq.Cryst.,2007,34(3):283-288.
[36] Zhan X,Jing X,Wu C.Synthesis and mesomorphic properties of a novel series of cholesterol-based liquid crystalline,tetramers[J].Liq.Cryst.,2009,36(12):1349-1354.
[37] Tian Y,Xu X,Zhao Y,et al.New cholesteric liquid crystals induced by intermolecular hydrogen bonding[J].Liq.Cryst.,1997,22(1):87-96.
[38] 吴英,周宏伟,卜凤泉,等.羧酸吡啶类分子间氢键对光致异构化及光化学稳定性影响的谱学研究[J].光谱学与光谱分析,2008,28(3):503-506.
[39] Lee J W,Jin J I,Achard M F,et al.Incommensurability induced by intermolecular hydrogen bonding[J].Liq.Cryst,2001,28(5):663-671.
[40] Lee J W,Jin J I,Achard M F,et al.Cholesterol-based hydrogen-bonded liquid crystals[J].Liq.Cryst.,2003,30(10):1193-1199.
[41] Takahashi A,Mallia V A,Tamaoki N.Novel supramolecular hydrogen-bonded cholesteric mesogens:liquid crystalline,thermoptical and glass-forming properties[J].J.Mater.Chem.,2003,13(7):1582-1587.
[42] 沈永涛,要旸,产启林,等.新型二元胆甾相液晶的超分子自组装比较研究[J].液晶与显示,2006,21(6):599-603.
[43] Ma X J,Shen Y T,Deng K.Matrix-molecule induced chiral enhancement effect of binary supramolecular liquid crystals[J].J.Mater.Chem.,2007,17(44):4699-4704.
[44] Hou Q,Wang S,Zang L,et al.Hydrogen-bonding A(LS)2-type low-molecular-mass gelator and its thermotropic mesomorphic behavior[J].J.Colloid Interface Sci.,2009,338(2):463-467.
[45] Mallia V A,Antharjanam P K S,Das S.Chiral nematic glasses from novel hydrogen-bonded mesogens[J].Chem.Lett.,2001,30(8):752-753.
[46] Mallia V A,Das S.Synthesis and studies of some cholest-5-en-3-ol-(3β)[4-phenylpyridylazo]carbonate-containing supramolecular hydrogen-bonded mesogens[J].Liq.Cryst.,2001,28(2):259-264.
[47] B M F,Q K,M G Y.Advances in Fluorinated Liquid Crystals[J].Progress in Chem.,2008,20(4):499-507.
[48] Zhang L,He W,Yuan X,et al.Broadband reflection characteristic of polymer-stabilised cholesteric liquid crystal with pitch gradient induced by a hydrogen bond[J].Liq.Cryst.,2010,37(10):1275-1280.
[49] Guo J,Chen F,Qu Z,et al. Electrothermal switching characteristics from a hydrogen-bonded polymer network structure in cholesteric liquid crystals with a double-handed circularly polarized light reflection band[J].J.Phys.Chem.B,2011,115(5):861-868.
[50] Itahara T,Sunose M,Kameda T,et al.Control of liquid-crystalline properties by base pairing of adenine and thy mine[J].Chem.Phys.Chem.,2002,3(4):378-379.
[51] Mccubbin J A,Tong X,Wang R,et al.Directed metalation route to ferroelectric liquid crystals with a chiral fluorenol core:The effect of restricted rotation on poler order[J].J.Am.Chem.Soc.,2004,126(4):1161-1167.
[52] Mccubbin J A,Tong X,Zhao Y,et al.Directed metalation-cross coupling route to ferroelectric liquid crystals with a chiral fluorenol core:The effect of intermolecular hydrogen bonding on polar order[J].Chem.Mater.,2005,17(10):2574-2581.
[53] Ossowska-Chru(s)ciel M D.A convenient synthesis and the mesomorphic properties of new chiral ferroelectric thio benzoates[J].Liq.Cryst.,2004,31(8):1159-1165.
[54] 李发胜,王磊,齐琳,等.紫外吸收染料诱导的具有宽波反射特性的胆甾相液晶聚合物薄膜[J].液晶与显示,2011,26(5):573-576.
[55] Bai Y,Abbott N L.Enantiomeric interactions between liquid crystals and organized monolayers of tyrosine-containingdipeptides[J].J.Am.Chem.Soc.,2011,134(1):548-558.
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