用原位聚合法在凹凸棒土 (ATP)的表而包覆上5-磺基水杨酸(SSA)掺杂的聚苯胺)PANI),合成了SSA-PAN/ATP纳米复合材料,研究了SSA掺杂量,聚合温度,苯胺包覆率,聚合时间和过硫酸铵(APS)用量对复合材料体积电阻率的影响,结果表明:在m)An):m)APS):m)ATP):m)SSA)=1:2,45:3,33:2,08,聚合温度为20℃,聚合时问为4 h时,复合材料体积电阻率可达到3,5 Ω·cm,并通过TG-DTA,XRD,FTIR和TEM对该条件下制备的纳米复合材料进行了表征.
参考文献
[1] | 李雪艳,王德松,安静,罗青枝,殷蓉,王彦红,王景慧.导电聚合物/无机纳米复合材料的研究进展[J].材料导报,2007(z1):174-178. |
[2] | Chuang FY;Yang SM .Cerium dioxide/polyaniline core-shell nanocomposites[J].Journal of Colloid and Interface Science,2008(1):194-201. |
[3] | ASIM NILOFAR;RADIMAN S;YARMO M ABIN.Preparation and characterization of core-shell polyaniline/V2O5 nanecomposite via microemulsion method[J].Materials Letters,2008(62):1044-1047. |
[4] | YAN WEI;FENG XIAOMIAO;CHEN XIAOJUN.A selective dopamine biosensor baaed on AgCl polyaniline core-shell nanocompesites[J].Bioelectrochemistry,2008(72):21-27. |
[5] | PHANG S W;TADOKORO M;WATANABE J et al.Microwave absorption behaviors of polyaniline nanocomposites containing TiO2 nanopartieles[J].Current Applied Physics,2008,8(3-4):391-394. |
[6] | Qi YN;Xu F;Ma HJ;Sun LX;Zhang J;Jiang T .Thermal stability and glass transition behavior of PANI/gamma-Al2O3 composites[J].Journal of thermal analysis and calorimetry,2008(1):219-223. |
[7] | SONG GENPING;HAN JIE;GUO RONG .Synthesis of polyaniline/NiO nanobehs by a self-assembly process[J].Synthetic Metals,2007,157(4-5):170-175. |
[8] | Binitha NN;Sugunan S .Polyaniline/Pillared montmorillonite clay composite nanofibers[J].Journal of Applied Polymer Science,2008(5):3367-3372. |
[9] | Singla ML;Awasthi S;Srivastava A .Humidity sensing; using polyaniline/Mn3O4 composite doped with organic/inorganic acids[J].Sensors and Actuators, B. Chemical,2007(2):580-585. |
[10] | Gok A;Omastova M;Prokes J .Synthesis and characterization of red mud/polyaniline composites: Electrical properties and thermal stability[J].European Polymer Journal,2007(6):2471-2480. |
[11] | 郑茂松;王爱勤;詹庚申.凹凸棒土石黏土应用研究[M].北京:化学工业出版社,2007 |
[12] | Yang SM.;Chen JT. .THE EFFECT OF SYNTHESIS CONDITIONS ON THE PROPERTIES OF POLYANILINE FILM[J].Synthetic Metals,1995(1/3):153-154. |
[13] | G 奥迪安.聚合反应原理[M].北京:科学出版社,1987:185-186. |
[14] | JAROSLAV STEJSKAL .The formation of polyaniline and the nature of its struetures[J].Polymer,1996,37(02):367-368. |
[15] | 陈天虎 .苏皖凹凸棒石粘土纳米尺度矿物学及地球化学[D].合肥工业大学,2003. |
[16] | 杨婕,陈敬中.江苏盱眙坡缕石的矿物学特征[J].资源调查与环境,2004(03):190-196. |
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