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  4. 膨胀阻燃体系的研究进展

涂料工业 , 2009, 39(9): 4-9. doi: 10.3969/j.issn.0253-4312.2009.09.002

膨胀阻燃体系的研究进展

李国新 1, , 何廷树 2, , 黄汝杰 3,

1.西安建筑科技大学材料与科学博士后流动站,西安,710055;西安建筑科技大学材料科学与工程学院,西安,710075

2.西安建筑科技大学材料与科学博士后流动站,西安,710055;西安建筑科技大学材料科学与工程学院,西安,710075

3.西安建筑科技大学材料科学与工程学院,西安,710075

基金项目:   陕西省产业化培育项目(08JC11)   陕西省教育厅专项课题(05JK234)  

关键词： 膨胀阻燃 , 增效 , 新型成炭剂

Research Progress in Intumescent Flame Retardant System

通过对阻燃体系的几类增效材料的作用效果和作用机理的分析,介绍了新型成炭剂和膨胀阻燃体系的最新研究成果,说明增效材料和新型膨胀阻燃体系依然是膨胀阻燃领域的研究热点,多种材料协同作用可更好地改善体系的性能.

参考文献

[1] W KLINGSCH .Fire resistance of solid steel columns[J].Fire Safety Journal,1982,4(04):237-241.
[2] VIJAY MOHAN BHATNAGAR;JEAN-MAURICE VERGNAUD .Clear intumescent fire retardant coating consisting of chlorinated paraffins and polyurethanes[J].Fire Safety Journal,1982,4(03):163-167.
[3] J H TROITZSCH .Methods for the fire protection of plastics and coatings by flame retardant and intumescent systems[J].Progress in Organic Coatings,1983,11(01):41-69.
[4] G CAMINO;L COSTA;L TROSSARELLI .Study of the mechanism of intumescence in fire retardant polymers:Part Ⅰ-Thermal degradation of ammonium,polypbosphate-pentaerythrilol mixtures[J].Polymer Degradation and Stability,1984,6(04):243-252.
[5] G CAMINO;L COSTA;L TROSSARELLi .Study of the mechanism of intumescence in fire retardant polymers:Part Ⅱ-Mechanism of action in polypropylene-ammonium polyphosphate-pentaerythritol mixtures[J].Polymer Degradation and Stability,1984,7(01):25-31.
[6] G CAMINO;L COSTA;L TROSSARELLI .Study of the mechanism of intumescence in fire retardant polymers:part Ⅲ-effect of urea on the ammonium polyphosphate-pentaerythritol system[J].Polymer Degradation and Stability,1984,7(04):221-229.
[7] G CAMINO;L COSTA;L Trossarelli et al.Study of the mechanism of intumescence in fire retardant polymers:Part Ⅳ-Evidence of ester formation in ammonium polyphosphate-pentaerythritol mixtures[J].Polymer Degradation and Stability,1984,8(01):13-22.
[8] G CAMINO;L COSTA;Trossarelli et al.Study of the mechanism of intumescence in fire retardant polymers:part Ⅵ-mechanism of ester formation in ammonium polyphosphate-pentaerythritol mixtures[J].Polymer Degradation and Stability,1985,12(03):213-228.
[9] G CAMINO;L COSTA;G MARTINASSO .Intumescent fire-retardant systems[J].Polymer Degradation and Stability,1989,23(04):359-376.
[10] G CAMINO;G MARTINASSO;L COSTA .Thermal degradation of pentaerythritol diphosphate,model compound for fire retardant intumescent systems:part 1-overall thermal degradation[J].Polymer Degradation and Stability,1990,27:285-296.
[11] G CAMINO;G MARTINASSO;L COSTA et al.Thermal degradation of pentaerythritol diphosphate,model compound for fire retardant intumescent systems:part Ⅱ-intumescence step[J].Polymer Degradation and Stability,1990,28:17-38.
[12] SERGE BOURBIGOT;MICHEL LE BRAS;REN DELOBEL .Carbonization mechanisms resulting from intumescence association with the ammonium polyphosphate-pentaerythritol fire retardant system[J].Carbon,1993,31(08):1219-1230.
[13] Serge Bourbigot;Michel Le Bras;Rene Delobel;Patrice Breant;Jean-Michel Tremillon .CARBONIZATION MECHANISMS RESULTING FROM INTUMESCENCE-PART Ⅱ. ASSOCIATION WITH AN ETHYLENE TERPOLYMER AND THE AMMONIUM POLYPHOSPHATE-PENTAERYTHRITOL FIRE RETARDANT SYSTEM[J].Carbon: An International Journal Sponsored by the American Carbon Society,1995(3):283-294.
[14] SERGE BOURBIGOT;MICHEL LE BRAS;LEON GENGEMBRE et al.XPS study of an intumescent coating application to the ammonium polyphosphate/pentaerythritol fire-retardant system[J].Applied Surface Science,1994,81(03):299-307.
[15] XILING CHEN;KEMIN SONG;JIHUI LI;JINPENG LIU .Preparation of lower-sulfur content and expandable graphite[J].Carbon: An International Journal Sponsored by the American Carbon Society,1996(12):1599-1600.
[16] MI GUOMIN .New method to synthesize expandable graphite with less pollution[J].Journal of Wuhan University of Technology(Materials Science Edition),1994,9(03):144-148.
[17] 赵正平.可膨胀石墨及其制品的应用及发展趋势[J].中国非金属矿工业导刊,2003(01):7-9.
[18] Duquesne S.;Bourbigot S.;Delobel R.;Camino G.;Eling B. Lindsay C.;Roels T.;Le Bras M. .Thermal degradation of polyurethane and polyurethane/expandable graphite coatings[J].Polymer Degradation and Stability,2001(3):493-499.
[19] 王震宇,韩恩厚,柯伟.可膨胀石墨改性APP/PER/EN防火涂料热降解行为[J].复合材料学报,2005(05):52-59.
[20] 刘学军,付若愚,咸才军,郭保文,郭奋.可膨胀石墨在膨胀型钢结构防火涂料中的应用[J].精细化工,2005(05):328-330,341.
[21] 张龙,王建祺.新型无卤可膨胀石墨防火涂料[J].北京理工大学学报,2001(05):649-652.
[22] 李国新,梁国正,杨秦莉,宋学锋.可膨胀石墨改性APP/PER/MEL防火涂料的热降解研究[J].涂料工业,2006(11):11-14,18.
[23] 李国新 .膨胀型防火涂料的改性及机理研究[D].西安:西北工业大学,2007.
[24] SERGE BOURBIGOT;MICHEL LE BRAS;RENE DELOBEL et al.Zeolites:new synergistic agents for intumescent fire retardant thermoplastic formulations-criteria for the choice of the zeolite[J].Fire and Materials,1996,20:145-154.
[25] 韦平,王建祺.4A分子筛对APP/PER膨胀阻燃剂协同作用的TGA/XPS[J].高分子材料科学与工程,2003(03):179-181,186.
[26] Estevao LRM.;Nascimento RSV. .The use of heating microscopy in the study of intumescence in waste catalyst containing polymer systems[J].Polymer Degradation and Stability,2002(3):517-533.
[27] Estevao LRM;Le Bras M;Delobel R;Nascimento RSV .Structure-property relationship in intumescent polymeric formulations containing waste zeolite-based material as a synergistic agent[J].European Polymer Journal,2004(7):1503-1513.
[28] 李秀瑜.阻燃刑的最新进展[J].河北化工,1998(04):30-33.
[29] ZHENYU WANG;ENHOU HAM;WEI KE .Effect of acrylic polymer and nanocompesite with nano-SiO2 on thermal degradation and fire resistance of APP-DPER-MEL coating[J].Polymer Degradation and Stability,2006,91:1937-1947.
[30] ZHENYU WANG;ENHOU HAN;WEi KE .Effect of nanopanicles on the improvement in fire-resistant and anti-ageing properties flame-retardant coating[J].Surface and Coatings Technology,2006,200:5706-5716.
[31] Wang ZY;Han EH;Ke W .Influence of nano-LDHs on char formation and fire-resistant properties of flame-retardant coating[J].Progress in Organic Coatings: An International Review Journal,2005(1):29-37.
[32] Wang ZY;Han EH;Ke W .An investigation into fire protection and water resistance of intumescent nano-coatings[J].Surface & Coatings Technology,2006(3/4):1528-1535.
[33] 王震宇,韩恩厚,柯伟.纳米阻燃母液提高APP/PER/MEL防火涂料耐水性研究[J].中国腐蚀与防护学报,2006(02):103-108.
[34] 咸才军,刘学军,付若愚.纳米SiO2在钢结构防火涂料中的应用[J].纳米科技,2005(03):7-9,14.
[35] 咸才军,孟惠民,孙冬柏,刘学军,王旭东.纳米材料在水性超薄膨胀型钢结构防火涂料中的应用[J].材料工程,2006(08):40-44.
[36] 邹敏,王琪琳,马光强,刘国钦.纳米TiO2改善钢结构防火涂料的性能研究[J].四川大学学报（自然科学版）,2006(04):864-867.
[37] 杨秦莉,李国新,周文英,何廷树.MoO3对膨胀型防火涂料残炭的影响[J].涂料工业,2006(05):24-28.
[38] Guoxin Li;Guozheng Liang;Tingshu He;Qinli Yang;Xuefeng Song .Effects of EG and MoSi_2 on thermal degradation of intumescent coating[J].Polymer Degradation and Stability,2007(4):569-579.
[39] Li GX;Yang JF;He TS;Wu YH;Liang GZ .An Investigation of the thermal degradation of the intumescent coating containing MoO3 and Fe2O3[J].Surface & Coatings Technology,2008(13):3121-3128.
[40] 李国新,梁国正,杨秦莉,何廷树,伍勇华.MoO3与可膨胀石墨改性聚磷酸铵/季戊四醇/三聚氰胺防火涂料研究[J].现代化工,2006(08):28-31,33.
[41] Michel le Bras;Serge bourbigot;yannick Le Tallec .Synergy in intumescence-application to β-cyclodextrin carbonisation agent in intumescent additives for fire retardant polyethylene formulations[J].Polymer Degradation and Stability,1997(1):11-21.
[42] WANG JINCHENG;YANG SHENGLIN;LI GUANG;JIANG JIANMING .Synthesis of a New-type Carbonific and Its Application in Intumescent Flame-retardant (IFR)/ Polyurethane Coatings[J].Journal of fire sciences,2003(4):245-266.
[43] Wang JC.;Li G.;Yang SL.;Jiang JM. .New intumescent flame-retardant agent: Application to polyurethane coatings[J].Journal of Applied Polymer Science,2004(2):1193-1206.
[44] Chen YH.;Liu YA.;Wang Q.;Yin HA.;Aelmans N.;Kierkels R. .Performance of intumescent flame retardant master batch synthesized through twin-screw reactively extruding technology: effect of component ratio[J].Polymer Degradation and Stability,2003(2):215-224.
[45] Qi Wang;Yinghong Chen;Yuan Liu;Huan Yin;Nico Aelmans;Rene Kierkels .Performance of an intumescent-flame-retardant master batch synthesized by twin-screw reactive extrusion: effect of the polypropylene carrier resin[J].Polymer international,2004(4):439-448.
[46] Hongbo Liang;Wenfang Shi .Thermal behaviour and degradation mechanism of phosphate di/triacrylate used for UV curable flame-retardant coatings[J].Polymer Degradation and Stability,2004(3):525-532.
[47] HONGBO LIANG;ANILA ASIF;WENFANG SHI .Thermal degraclarion and flame retardancy of a novel methacrylated phenolic melamine used for UV curable flame retardant coatings[J].Polymer Degradation and Stability,2005,87:495-501.
[48] Hongbo Liang;Wenfang Shi;Ming Gong .Expansion behaviour and thermal degradation of tri(acryloyloxyethyl) phosphate/methacrylated phenolic melamine intumescent flame retardant system[J].Polymer Degradation and Stability,2005(1):1-8.
[49] Li B;Xu MJ .Effect of a novel charring-foaming agent on flame retardancy and thermal degradation of intumescent flame retardant polypropylene[J].Polymer Degradation and Stability,2006(6):1380-1386.
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