先利用混酸体系和3-氨丙基三乙氧基硅烷偶联剂(KH550)对多壁碳纳米管(MWCNTs)进行表面修饰,然后将修饰后的MWCNTs加入苯丙乳液中,成功制备了具有良好抗静电性能和力学性能的碳纳米管/苯丙乳液改性内墙涂料.利用透射电镜,对修饰前后的MWCNTs进行了热重分析.结果表明:KH550成功地接枝到MWCNTs表面,修饰后的MWCNTs能实现很好的分散.研究了MWCNTs用量对所制备涂料的导电性能、力学性能的影响.研究表明当MWCNTs添加量达到2.50%时,涂料的表面电阻最小,为1.42×107Ω,力学性能最佳.
参考文献
[1] | HYPERION C.Carbon nanotubes for static dissipation[J].Plastis Additives and Compounding,2001(09):20-22. |
[2] | Peng Cheng Ma;Jang-Kyo Kim;Ben Zheng Tang .Functionalization of carbon nanotubes using a silane coupling agent[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(15):3232-3238. |
[3] | Ying-Ling Liu;Wei-Hong Chen .Modification of Multiwall Carbon Nanotubes with Initiators and Macroinitiators of Atom Transfer Radical Polymerization[J].Macromolecules,2007(25):8881-8886. |
[4] | KIM S D;KIM J W;IM J S et al.A comparative on properties of multi -walled carbon nanotubes(MWCNTs) modified with acids and oxyfluorination[J].Journal of Fluorine Chemsitry,2007,128:60-64. |
[5] | Kathi, J.;Rhee, K.Y. .Surface modification of multi-walled carbon nanotubes using 3-aminopropyltriethoxysilane[J].Journal of Materials Science,2008(1):33-37. |
[6] | John Kathi;Kyong-Yop Rhee;Joong Hee Lee .Effect of chemical functionalization of multi-walled carbon nanotubes with 3-aminopropyltriethoxysilane on mechanical and morphological properties of epoxy nanocomposites[J].Composites, Part A. Applied science and manufacturing,2009(6/7):800-809. |
[7] | 冯辉昌,王静,徐杰,张威震,孙继亮.储油罐纳米碳管导静电防腐涂料的研制[J].中国涂料,2006(11):24-26,38. |
[8] | 杨正龙;秦深;浦鸿汀 .一种含碳纳米管水性聚氨酯导电涂料及其制备方法[P].中国,CN101165127A,2008-04-23. |
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