从丙烯酸聚氨酯涂料的固化反应机理出发,系统分析了树脂、固化剂、催化剂和环境因素对丙烯酸聚氨酯涂层干燥速度的影响,重点讨论了羟基单体的种类和用量、亚胺结构的引入、玻璃化转变温度、相对分子质量及其分布、酸值及分子链结构等因素对树脂反应活性的影响.通过对目前低温快固化涂料研究中存在的问题的分析,指出精确控制树脂分子结构是实现修补涂料低温快固化的有效途径.
参考文献
| [1] | 汪盛藻.汽车修补涂料与涂装技术[M].北京:中国石化出版社,2006 |
| [2] | 黄微波.喷涂聚脲弹性体技术[M].北京:化学工业出版社,2006 |
| [3] | 丛树枫;喻露如.聚氨酯涂料[M].北京:化学工业出版社,2003 |
| [4] | 陈耀容,马晓阳,辜朝辉.4-丙烯酸羟丁酯的生产及其在汽车修补漆中的应用[J].上海涂料,2010(03):16-18. |
| [5] | Ley David A.;Quinn Richard J.;Fiori Denise E. .Optimization of acrylic polyols for low VOC two-component water reducible polyurethane coatings using tertiary isocyanate crosslinkers[J].Progress in Organic Coatings: An International Review Journal,1999(1/4):109-116. |
| [6] | HEINZ P R;MICHAEL B;ULRIKE R .Poly(meth-)acrylic resin-based coating agent which can be cross-lined with isoeyanate[P].US,6013739,2000-01-11. |
| [7] | 包启宇.汽车修补漆中相关问题探讨[J].上海涂料,2005(07):46-50. |
| [8] | 黄微波.喷涂聚脲弹性体技术--聚脲化学反应原理[J].上海涂料,2006(04):29-33. |
| [9] | 瞿金清,涂伟萍,杨卓如,陈焕钦.快干高固含量聚氨酯涂料羟基树脂的研制[J].材料保护,1999(11):24-25. |
| [10] | Nabuurs T.;Overbeek A.;Pears D. .Defect free coatings from two-pack isocyanate curable acrylic dispersions[J].Progress in Organic Coatings: An International Review Journal,1999(1/4):129-140. |
| [11] | 黎永津,夏正斌,涂伟萍,杨卓如,陈焕钦.高性能双组份丙烯酸聚氨酯涂料的研制[J].华南理工大学学报,2000(07):116. |
| [12] | 王季昌.涂料用丙烯酸树脂配方设计及其影响因素[J].中国涂料,2010(02):45-48. |
| [13] | 夏正斌,涂伟萍,陈焕钦.低分子量高固体分丙烯酸聚合物的合成及应用研究[J].合成材料老化与应用,2003(03):9-13,38. |
| [14] | HUYBRECHTS J T;TANGHE L M .2.1 VOC solvent borne 2K clear coats based on star oligsethers[J].Proress in Organic Coatings,2007,58(2/3):217-226. |
| [15] | VUKOVI(C) J;LECMNER M D;JOVANOVI(C) S .Properties of aliphatic hyperbranched polyesters in dilute solutions[J].Journal of the Serbian Chemical Society,2007,72(12):1493-1506. |
| [16] | Jikei M.;Kakimoto M. .Hyperbranched polymers: a promising new class of materials [Review][J].Progress in Polymer Science,2001(8):1233-1285. |
| [17] | Cheng XE;Huang ZG;Liu JH;Shi WF .Synthesis and properties of semi-crystalline hyperbranched poly (ester-amide) grafted with long alkyl chains used for UV-curable powder coatings[J].Progress in Organic Coatings: An International Review Journal,2007(4):284-290. |
| [18] | MEHTA PN .Hyperbranched pelymers:unique design tool for coatings[J].Surface Coatings International Part B: Coatings Transactions,2006,89(04):333-342. |
| [19] | Manczyk K.;Szewczyk P. .Highly branched high solids alkyd resins [Review][J].Progress in Organic Coatings: An International Review Journal,2002(2):99-109. |
| [20] | Zagar E;Huskic M;Zigon M .Structure-to-properties relationship of aliphatic hyperbranched polyesters[J].Macromolecular chemistry and physics,2007(13):1379-1387. |
| [21] | MATSUNO Y;ADACHI T;NUMA N .Application of graft copolymers using macromonomer method to two compoent polyurethane coatings[J].Progress in Organic Coatings,1999,35(1/4):117-127. |
| [22] | 李金旗.聚氨酯涂料用聚异氰酸酯固化剂[J].上海涂料,2009(10):28-30. |
| [23] | Wicks ZW.;Wicks DA.;Rosthauser JW. .Two package waterborne urethane systems [Review][J].Progress in Organic Coatings: An International Review Journal,2002(2):161-183. |
| [24] | 汤京强.双组分聚氨酯塑料清漆快干探讨[J].上海涂料,2006(10):30-33. |
| [25] | NICHOLS JAMES D;DICKENSON JOIN B .Orgsnotin catalysts for use in polyurethane systems[P].US,4987244,1991-01-22. |
| [26] | DEWHURST J01N E;NICHOLS JAMES D .Polyurethane rim elastomers obtained with hydroxyl-containing orgsnotin catalysts[P].US,5256704,1993-10-26. |
| [27] | Blank Werner J.;Hessell E.T.;He Z.A. .Catalysis of the isocyanate-hydroxyl reaction by non-tin catalysts[J].Progress in Organic Coatings: An International Review Journal,1999(1/4):19-29. |
| [28] | 余喜红;任娜娜;李红星 等.催化剂时水性双组分聚氨酯涂料的成膜及性能的影响[J].涂料工业,2010,40(01):27-31. |
| [29] | 王锡春.汽车用新型罩光涂料--UV和热双固化清漆[J].上海涂料,2005(04):29-32. |
| [30] | 蔡佳斌,施国萍,陈珀丽.微波干燥在聚氨酯水性木器涂料中的应用与研究[J].中国涂料,2008(07):69-72. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%