综述了国内外环氧树脂改性方法的研究现状及其在作为石质文物保护材料中的研究进展.其中环氧树脂的改性方法包括:橡胶弹性体改性、热塑性树脂改性、核壳聚合物改性、热致液晶聚合物改性、嵌段聚合物改性、齐聚倍半硅氧烷结构改性、互穿聚合物网络改性、超支化聚合物改性以及纳米粒子改性等,并比较讨论了各种方法的优缺点.同时论述了改性后的环氧树脂,特别是用纳米材料改性的环氧树脂在石质文物中的研究现状及应用前景.
参考文献
| [1] | I. Karatasios;P. Theoulakis;A. Kalagri;A. Sapalidis;V. Kilikoglou .Evaluation of consolidation treatments of marly limestones used in archaeological monuments[J].Construction and Building Materials,2009(8):2803-2812. |
| [2] | ZHEN D;LI Y F;YANG S et al.Kinetics and thermal properties of epoxy resins based on biphenol fluorine structure[J].European Polymer Journal,2009,33(45):1941-1948. |
| [3] | Ramos VD;da Costa HM;Soares VLP;Nascimento RSV .Modification of epoxy resin: a comparison of different types of elastomer[J].Polymer Testing,2005(3):387-394. |
| [4] | 江金强,刘敬成,张胜文,韩红军,周琼,刘晓亚.环氧树脂增韧改性方法及机理研究进展[J].江南大学学报（自然科学版）,2009(05):625-630. |
| [5] | MCGARRY F J;WILLNER A M .Toughening of an epoxy resin by an elastomer second phase[R].USA:MIT,1968. |
| [6] | SUL TAN J;MCGARRY F J .Epoxy resins toughened by CTBN[J].Polymer Engineering and Science,1973,13(01):291-230. |
| [7] | 陈青,宫大军,魏伯荣,柳丛辉.端羧基丁腈橡胶改性环氧树脂的研究[J].绝缘材料,2011(02):30-33,38. |
| [8] | 张俊生,陈庆民.液体端氨基丁腈橡胶和环氧树脂制备的密封胶及性能[J].高分子材料科学与工程,2011(04):135-138. |
| [9] | WEN C S;MAC C .Poly dimethylisiloxane containing isocyanate group modified epoxy resin:curing,characterization and properties[J].Lappl Polymer Science,1999,73(13):2739-2745. |
| [10] | PAK S J;LYLE G D;MERCIER R et al.Synthesis and characrerization of novel toughened thermosets derived from pendent amines on the backbone of poly (arylene ether sulphone) s[J].Polymer,1993,23(34):885-895. |
| [11] | BUCKNALL C B;PARTRIDGE I K .Phase separation separation in epoxy resins containing polyethersulfone[J].Polymer,1983,11(24):639-645. |
| [12] | BAUER R S.Toughened high performance epoxy resins,modificating with thermoplastic[A].,1990:232-234. |
| [13] | BUCKNALL C B;GILBERT A H .Toughening tetrafunctional epoxy resins using polyetherimide[J].Polymer,1989,10(30):213-217. |
| [14] | LIU Y;DU M .Rexdarch progress in modification techniques,new methods and mechanism of toughening epoxy resins[J].Chemistry and Adhesion,2007,29(03):197-205. |
| [15] | 孙攀,史翎,张军营.可溶性聚醚醚酮改性环氧树脂的研究[J].北京化工大学学报（自然科学版）,2011(02):36-41. |
| [16] | 杨鹏 .环氧树脂/二氧化硅纳米复合材料的制备与性能研究[D].复旦大学,2008. |
| [17] | Jiwon Choi;Albert F.Yee;Richard M.Laine .Toughening of Cubic Silsesquioxane Epoxy Nanocomposites Using Core-Shell Rubber Particles: A Three-Component Hybrid System[J].Macromolecules,2004(9):3267-3276. |
| [18] | GIANNAKOPOULOS G;MASANIA K;TAYLOR A C .Toughening of epoxy using core-shell particles[J].Journal of Materials Science,2010,10(12):1007-1019. |
| [19] | 张丽,王晔.核壳橡胶粒子低温增韧环氧树脂的研究[J].洛阳师范学院学报,2011(05):49-52. |
| [20] | 任圆.环氧树脂增韧改性研究进展[J].热固性树脂,2011(03):45-49. |
| [21] | 张凯,范敬辉,马艳,黄琨.环氧树脂灌封材料的增韧研究[J].电子元件与材料,2011(05):65-67. |
| [22] | LU S R;YANG X W;WEI C .Preparation and characterization of liquid crystalline epoxy/epoxy resin composites[J].Plastics,Rubber and Composites,2010,39(02):67-73. |
| [23] | Jerman I;Vuk AU;Kozelj M;Orel B;Kovac J .A structural and corrosion study of triethoxysilyl functionalized POSS coatings on AA 2024 alloy[J].Langmuir: The ACS Journal of Surfaces and Colloids,2008(9):5029-5037. |
| [24] | 黎学明,潘倩,林燕丹,游波,孙耀杰.环氧/聚有机硅倍半氧烷杂化材料的制备及性能[J].重庆大学学报,2011(05):112-117,122. |
| [25] | IKKALLA O;BRINKE T G .Functional materials based on self-assembly of polymeric supramolecules[J].Science,2002,29(05):2407-2409. |
| [26] | 王小兵,何尚锦,张保龙,郑威,金子明.丙烯酸酯嵌段共聚物合成及其改性环氧树脂的研究[J].工程塑料应用,2007(12):9-13. |
| [27] | Liu J;Sue HJ;Thompson ZJ;Bates FS;Dettloff M;Jacob G;Verghese N;Pham H .Nanocavitation in Self-Assembled Amphiphilic Block Copolymer-Modified Epoxy[J].Macromolecules,2008(20):7616-7624. |
| [28] | 周安安.复合阳离子型有机硅柔软剂的研制及应用[J].浙江科技学院学报,2005(02):102-105. |
| [29] | Mahesh KPO.;Alagar M. .Preparation and characterization of chain-extended bismaleimide modified polyurethane-epoxy matrices[J].Journal of Applied Polymer Science,2003(10):1562-1568. |
| [30] | 李永清,郑淑贞,朱锡.有机硅嵌段改性聚氨酯/环氧树脂互穿网络聚合物的研究[J].高分子材料科学与工程,2005(03):129-132. |
| [31] | 郑亚萍,余利波,张爱波,宁荣昌.超支化聚（胺-酯）增韧环氧树脂[J].华东理工大学学报（自然科学版）,2006(02):205-208. |
| [32] | 董杰,陈晓婷,李艳青,唐旭东.超支化聚膦酸酯改性环氧树脂的研究[J].天津科技大学学报,2010(06):30-32,38. |
| [33] | S.fellahi;M.Bakar;N.Chikhi .Modification of Epoxy Resin with Kaolin as a Toughening Agent[J].Journal of Applied Polymer Science,2001(4):861-878. |
| [34] | Rosso P;Ye L;Friedrich K;Sprenger S .A toughened epoxy resin by silica nanoparticle reinforcement[J].Journal of Applied Polymer Science,2006(3):1849-1855. |
| [35] | 廖希异,谢建良.环氧树脂增韧改性技术研究进展[J].四川化工,2007(01):15-19. |
| [36] | 张之圣,樊攀峰,李海燕.纳米SiO2/环氧树脂的制备与表征[J].材料工程,2004(10):50-53. |
| [37] | 刘刚,张代军,张晖,安学锋,益小苏,张忠.纳米粒子改性环氧树脂及其复合材料力学性能研究[J].材料工程,2010(01):47-53. |
| [38] | Yuan L;Liang GZ;Xie JQ;Li L;Guo J .Preparation and characterization of poly(urea-formaldehyde) microcapsules filled with epoxy resins[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(15):5338-5349. |
| [39] | Brown EN.;White SR.;Sottos NR. .Microcapsule induced toughening in a self-healing polymer composite[J].Journal of Materials Science,2004(5):1703-1710. |
| [40] | 徐茂伟,杜美利,杜伟,么秋香,刘静.碳纤维改性及其增强环氧树脂性能的研究[J].化工新型材料,2011(04):121-123. |
| [41] | 王镛先;杨卫疆 .透水胶粘剂的合成与表征[J].精细化工,1996,13(06):41-43. |
| [42] | 栾晓霞,许淳淳,王紫色,吉静.改性水性环氧树脂乳液对石质文物的保护效果[J].腐蚀与防护,2008(08):451-453. |
| [43] | 周继亮,涂伟萍.室温固化柔韧性水性环氧固化剂的合成与性能[J].高分子材料科学与工程,2006(01):52-55. |
| [44] | 王永珍,张亚峰,邝健政,高南,徐宇亮.潮湿基面用环氧灌浆材料的制备及性能研究[J].新型建筑材料,2011(01):84-88,91. |
| [45] | KOTLIK P;JUSTA P;ZELINGER J .The application of epoxy resins for the consolidation of porous stong[J].Studies in Conservation,1983,24(28):75-79. |
| [46] | Khoee, S.;Hassani, N. .Adhesion strength improvement of epoxy resin reinforced with nanoelastomeric copolymer[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2010(24/25):6562-6567. |
| [47] | P.Cardiano;R.C.Ponterio;S.Sergi;S.Lo Schiavo;P.Piraino .Epoxy-silica polymers as stone conservation materials[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(6):1857-1864. |
| [48] | 栾晓霞 .基于纳米材料改性的水性石质文物保护剂的研究[D].北京化工大学,2008. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%