欢迎登录材料期刊网

材料期刊网

高级检索

微乳液聚合已被广泛用于合成各种具有纳米结构和尺寸的聚合物乳液及功能粒子,特别是功能性无机纳米颗粒以及聚合物/无机复合材料.本文系统地讨论了影响微乳液聚合的主要因素,概括了提高单体/乳化剂比的各种改进的微乳液聚合工艺,着重介绍了目前微乳液聚合在功能涂料领域的应用和广阔的研究前景.

参考文献

[1] HOAR T P;SCHULMAN J H .Tranparent water-in-oil dispersions:the olepathic hydro-micelle[J].Nature,1943,152(3847):102-103.
[2] DESAI S D;GORDON R D;GRONDA A M et al.Polymerized microemulsions[J].Current Opinion in Colloid and Interface Science,1996,1(04):519-522.
[3] S.C. Tjong .Structural and mechanical properties of polymer nanocomposites[J].Materials Science & Engineering, R. Reports: A Review Journal,2006(3/4):73-197.
[4] JIMMIE R. BARAN JR.;GARY A. POPE;WILLIAM H. WADE;VINITHA WEERASOORIYA .Water/Chlorocarbon Winsor Ⅰ <=> Ⅲ <=> Ⅱ Microemulsion Phase Behavior with Alkyl Glucamide Surfactants[J].Environmental Science & Technology: ES&T,1996(7):2143-2147.
[5] Nie LX;Yang WL;Zhang HD;Fu SK .Monte Carlo simulation of microemulsion polymerization[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(9):3175-3184.
[6] Chern CS;Tang HJ .Microemulsion polymerization kinetics and mechanisms[J].Journal of Applied Polymer Science,2005(5):2005-2013.
[7] Hermanson KD.;Kaler EW. .Kinetics and mechanism of the multiple addition microemulsion polymerization of hexyl methacrylate[J].Macromolecules,2003(6):1836-1842.
[8] Hermanson KD;Kaler EW .Transition from microemulsion to emulsion polymerization: Mechanism and final properties[J].Journal of Polymer Science, Part A. Polymer Chemistry,2004(20):5253-5261.
[9] Xiao Tang;Jueshi Qian;Jiamu Huang .Application of tetrahydrofuran dispersant in microemulsion for fabricating titania mesoporous thin film[J].Journal of Colloid and Interface Science,2007(2):584-588.
[10] Tze Han Lim;Mun Pun Tham;Zhaolin Liu;Liang Hong;Bing Guo .Nano-structured proton exchange membranes molded by polymerizing bi-continuous microemulsion[J].Journal of Membrane Science,2007(1/2):146-152.
[11] Ben Li;Shengnan Yu;Zhongyi Jiang;Wanpeng Liu;Ruijian Cao;Hong Wu .Efficient desulfurization by polymer-inorganic nanocomposite membranes fabricated in reverse microemulsion[J].Journal of hazardous materials,2012(Apr.15):296-303.
[12] Capek I. .Microemulsion polymerization of styrene in the presence of a cationic emulsifier[J].Advances in Colloid and Interface Science,2001(1/3):195-233.
[13] Arellano, J.;Flores, J.;Zuluaga, F.;Mendizábal, E.;Katime, I. .Effect of monomer water solubility on cationic microemulsion polymerization of three components (water, surfactant, and monomer)[J].Journal of Polymer Science, Part A. Polymer Chemistry,2011(14):3014-3019.
[14] Wang, H.;Pan, Q.;Hammond, M.;Rempel, G.L. .Preparation of poly(methyl methacrylate)-poly(acrylonitrile-co-butadiene) core-shell nanoparticles[J].Journal of Polymer Science, Part A. Polymer Chemistry,2012(4):736-749.
[15] LOPEZ-QUINTELA M A .Synthesis of nanomaterials in microemulsions:formation mechanisms and growth control[J].Interface Science,2003,8(02):137-144.
[16] XIANG L X;XUE W G;QIANG Y et al.Growth of polymer nanoparticles in microemulsion polymerization initiated with γ ray[J].Radiation Physics and Chemistry,1999,54(03):279-283.
[17] VA(S)KOV(A) V;HLOU(S)KOV(A) Z;BARTO(N) J et al.Polymerization in inverse microemulsions,4 locus of initiation by ammonium peroxodisulfate and 2,2'-azoisobutyronitrile[J].Die Makromolekulare Chemie,1992,193(03):627-637.
[18] POTISK P;CAPEK I;KLIMOVA M .Polymerization of butyl acrylate in microemulsion:Locus of initation[J].Die Angewandte Makromolekulare Chemie,1996,236(4105):43-53.
[19] CAPEK I .Microemulsion and emulsion polymerization of butyl acry late-i.effect of the initiator type and temperature[J].Journalof European Polymer,1995,31(12):1269-1277.
[20] PUIG J E;MACIAS E R;RODRIGUEZL B E et al.Comparison of oil-soluble and water-soluble initiation of styrene polymerization in a three-component microemulsion[J].Polymer,1993,123:114-123.
[21] Poghosyan, A.H.;Arsenyan, L.H.;Gharabekyan, H.H.;Falkenhagen, S.;Koetz, J.;Shahinyan, A.A. .Molecular dynamics simulations of inverse sodium dodecyl sulfate (SDS) micelles in a mixed toluene/pentanol solvent in the absence and presence of poly(diallyldimethylammonium chloride) (PDADMAC)[J].Journal of Colloid and Interface Science,2011(1):175-181.
[22] Sahiner, N.;Butun, S.;Ilgin, P. .Hydrogel particles with core shell morphology for versatile applications: Environmental, biomedical and catalysis[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2011(1/3):16-24.
[23] Andres Guerrero-Martinez;Jorge Perez-Juste;Luis M. Liz-Marzan .Recent Progress on Silica Coating of Nanoparticles and Related Nanomaterials[J].Advanced Materials,2010(11):1182-1195.
[24] 李晓,高静,张卫英,曾伟杰.丙烯酸酯反相微乳液聚合动力学[J].化工学报,2004(07):1168-1172.
[25] Stefan Burauer;Thomas Sachert;Thomas Sottmann;Reinhard Strey .On microemulsion phase behavior and the monomeric solubility of surfactant[J].Physical chemistry chemical physics: PCCP,1999(18):4299-4306.
[26] Tomsic M;Bester-Rogac M;Jamnik A;Kunz W;Touraud D;Bergmann A;Glatter O .Ternary systems of nonionic surfactant Brij 35, water and various simple alcohols: Structural investigations by small-angle X-ray scattering and dynamic light scattering[J].Journal of Colloid and Interface Science,2006(1):194-211.
[27] Francoise Candau;Martial Pabon;Jean-Yves Anquetil .Polymerizable microemulsions: some criteria to achieve an optimal formulation[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,1999(1/3):47-59.
[28] Jyongsik Jang;Xiang Li Li;Joon Hak Oh .Facile fabrication of polymer and carbon nanocapsules using polypyrrole core/shell nanomaterials[J].Chemical communications,2004(7):794-795.
[29] GAN L M;CHEW C H .Microporous polymer composites from microemulsion polymerization[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1997,123-124:681-693.
[30] GAN L;LIAN N;CHEW C .Polymerization of styrene in a winsor I-like system[J].Langmuir,1994,10:2197-2201.
[31] Ming W.;Fu SK.;Jones FN. .High solids-content nanosize polymer latexes made by microemulsion polymerization[J].Macromolecular chemistry and physics,1998(6):1075-1079.
[32] XU X;CHEW C;SIOW K.Microemulsion polymerization of styrene for obtaining high ratios of polystyrene/surfactant[J].Langmuir,1999(17):8067-8071.
[33] CHEN W;LIU X;LIU Y et al.Synthesis of PMMA and PMMA/PS nanoparticles by microemulsion polymerization with a new vapor monomer feeding system[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects Elsevier B V,2010,364(1-3):145-150.
[34] 杨东,薛垠,胡建华,府寿宽.改进的微乳液聚合制备的聚甲基丙烯酸甲酯的力学和光学性能研究[J].化学学报,2009(12):1370-1374.
[35] 黄永毅,李毅伟,曾小兰,吕莉,林国良.微乳液聚合制备含氟丙烯酸酯共聚物[J].厦门大学学报(自然科学版),2011(06):1095-1098.
[36] Wan T;Hu ZW;Ma XL;Yao H;Lu K .Synthesis of silane monomer-modified styrene-acrylate microemulsion coatings by photopolymerization[J].Progress in Organic Coatings: An International Review Journal,2008(2):219-225.
[37] BOONME P;KRAUEL K;GRAF A et al.Characterization of microemulsion structures in the pseudoternary phase diagram of isopropyl palmitate/water/brij 97:1-butanol[J].AAPS PHARMSCITECH,2006,7(02):3-8.
[38] Chen, B;Deng, JP;Liu, XQ;Yang, WT .Novel Category of Optically Active Core/Shell Nanoparticles: The Core Consisting of a Helical-Substituted Polyacetylene and the Shell Consisting of a Vinyl Polymer[J].Macromolecules,2010(7):3177-3182.
[39] Nilofar Asim;S. Radiman;M.A.bin Yarmo .Preparation and characterization of core-shell polyaniline/V_2O_5 nanocomposite via microemulsion method[J].Materials Letters,2008(6/7):1044-1047.
[40] Jang J;Oh JH .Fabrication of a highly transpartent conductive thin film from polypyrrole/poly(methyl methacrylate) core/shell nanospheres[J].Advanced functional materials,2005(3):494-502.
[41] Jang J.;Ha H. .Fabrication of hollow polystyrene nanospheres in microemulsion polymerization using triblock copolymers[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(14):5613-5618.
[42] Aguiar A.;Rabelero M.;Mendizabal E.;Puig J.E.;Dominguez J.M.;Katime I.;Gonzalez-Villegas S. .Core-shell polymers with improved mechanical properties prepared by microemulsion polymerization[J].Macromolecules,1999(20):6767-6771.
[43] 杨杰,舒武炳,秦卫.双连续相微乳液聚合制备多孔材料[J].功能材料,2010(01):148-152.
[44] 杨杰,舒武炳,秦卫.微乳液聚合制备多孔高吸油甲基丙烯酸酯类树脂的研究[J].高分子学报,2010(07):910-917.
[45] CHOW P Y;GAN L M.Microemulsion polymerizations and reactions[J].Advances in Polymer Science,2005(175):257-298.
[46] KOETZ J;BAHNEMANN J;LUCAS G et al.Polyelectrolyte modified microemulsions as new templates for the formation of nanoparticles[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2004,250(1-3):423-430.
[47] Sinha, B.;Dan, A.;Wongkamlue, A.;Chanakul, A.;Charinpanitkul, T.;Moulik, S.P.;Panda, A.K. .Synthesis and characterization of dispersions of ZnCrO_4 prepared in AOT stabilized water/heptane microemulsion[J].Journal of Molecular Liquids,2011(3):171-177.
[48] HUANG K L;YIN L G;LIU S Q.Preparation and formation mechanism of Al2 O3 nanoparticles by reverse microemulsion[J].Transaction Nonferrous Metals Society of China,2007(17):633-638.
[49] Li F.;Vipulanandan C.;Mohanty KK. .Microemulsion and solution approaches to nanoparticle iron production for degradation of trichloroethylene[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2003(1/3):103-112.
[50] Chen Jing;Shi Xiaobo Hanbing .The preparation and characteristics of cobalt blue colored mica titania pearlescent pigment by microemulsions[J].Dyes and Pigments,2007(3):766-769.
[51] Kanda Wongwailikhit;Saranporn Horwongsakul .The preparation of iron (Ⅲ) oxide nanoparticles using W/O microemulsion[J].Materials Letters,2011(17/18):2820-2822.
[52] Mariana Filali;Michael A.R.Meier;Ulrich S.Schubert;Jean-Francois Gohy .Star-Block Copolymers as Templates for the Preparation of Stable Gold Nanoparticles[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(17):7995-8000.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%