采用液相法结合微波干燥技术,以轻质MgO为原料,聚乙烯醇(PVA)为成膜剂制得乳胶液,在不锈钢基板上成功制备出不同厚度的MgO涂层,并对所制得的MgO涂层采用扫描电镜(SEM)、X射线衍射(XRD)和差热及热重( TG - DTA)等分析测试手段进行了表面形貌、结构和组成等的表征.结果表明:利用微波液相法得到的MgO涂层,MgO颗粒分散均匀(平均粒径400 ~ 500 nm),无其他副产物产生,加入的PVA能够形成凝胶骨架网,不仅具有一定应变能力,在一定程度上防止了涂层裂纹,而且还能有效地控制MgO粒子尺寸防止团聚现象.
参考文献
[1] | FAGHIHI-SANI M A;YAMAGUCHI A .Oxidation kinetics of MgO-C refractory bricks[J].Ceramics International,2002,28(08):835-839. |
[2] | IDA T;KIMURA Y;SANO T .Trapped field measurements of Gd-Ba-Cu-O bulk superconductor in controlled pulse field magnetizing[J].Journal of Physics:Condensed Matter,2008,97:012292:1-012292:5. |
[3] | Jeong Soo Lee;Byung Gil Ryu;Hyun Ja Kwon;Young Woo Jeong;Hyun Ha Kim .Texture and cross-sectional microstructure of MgO films grown on silicon dioxide by electron-beam evaporation[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1999(1/2):82-86. |
[4] | Akira Sugawara;K. Mae .Faceting of homoepitaxial MgO(110) layers prepared by electron beam evaporation[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,2004(1/3):211-217. |
[5] | 王维,乔学亮,邱小林,陈建国,李海军.PEG对沉淀法制备纳米MgO形貌的影响[J].人工晶体学报,2007(06):1399-1402. |
[6] | XU B Q;WEI J M;WANG H Y et al.Nano-MgO:novel preparation and application as support of Ni catalyst for CO2 reforming of methane[J].Catalysis Today,2001,68(1-3):217-225. |
[7] | 蓝冬雪,林丹,赵会民,马丽,淳远.以脱脂棉为模板制备高比表面积Al2O3-MgO固体酸碱双功能材料[J].催化学报,2011(07):1214-1219. |
[8] | 孙明,余林,余坚,郝志峰,余倩,彭兰乔.微波固相法合成纳米氧化镁[J].功能材料,2006(12):1978-1981,1984. |
[9] | Fereshteh Meshkani;Mehran Rezaei .Facile synthesis of nanocrystalline magnesium oxide with high surface area[J].Powder Technology: An International Journal on the Science and Technology of Wet and Dry Particulate Systems,2009(1):85-88. |
[10] | Gandhi, S.;Abiramipriya, P.;Pooja, N.;Jeyakumari, J.J.L.;Arasi, A.Y.;Dhanalakshmi, V.;Nair, M.R.G.;Anbarasan, R. .Synthesis and characterizations of nano sized MgO and its nano composite with poly(vinyl alcohol)[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2011(1):181-185. |
[11] | DOYMAZ N I .Thin-layer drying characteristics of sweet potato slices and mathematical modeling[J].Heat and Mass Transfer,2011,47(03):277-285. |
[12] | 孙晓峰,马世宁,朱乃姝,钱海峰,胡春华.微波固化改性环氧树脂/碳纤维复合材料研究[J].材料工程,2008(z1):190-193,198. |
[13] | 李娜娜,肖长发,安树林.PVDF/PVA共混膜的研究[J].功能材料,2007(12):1975-1980. |
[14] | 酒金婷,李立平,葛钥,张涑戎,屠凡,花智仁,聂凌.用高分子保护的纳米MgO的合成[J].无机化学学报,2001(03):361-365. |
[15] | BANFIELD J F;WELCH S A;ZHANG H Z et al.Aggregation based crystal growth and microstructure development in natural iron oxyhydroxide biomineralization products[J].Science,2000,289(5480):751-754. |
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