首先分别简述了气体雾化法、熔体快淬法和铸带法制备储氢合金的微观组织结构特征和电化学性能. 其次从合金电极充-放电机理出发分析了具有易活化、高容量、长寿命及高倍率性能等优异电化学性能的储氢合金应该具有的理想微观组织特征. 说明了气体雾化法和快淬法在储氢合金制备中固有的弊端, 指出铸带法是3种特种工艺方法中制备高性能AB5型储氢合金的最佳选择.
参考文献
| [1] | Willems J J G .[J].Philips Journal of Research,1984(39):1. |
| [2] | Ogawa H;Ikoma M;Kawano H.[A].Bournemouth,1989:393. |
| [3] | Sakai T;Miyamura H;Kurigama N et al.[J].Journal of the Less-Common Metals,1990,159:127. |
| [4] | Notten P H L;Einerhand R E F;Daams J L C .[J].Journal of the Less-Common Metals,1994,210:221. |
| [5] | Li C J;Wang X L;Wang C Y .[J].Journal of Power Sources,1998,74:255. |
| [6] | 郭宏,张少明,张曙光,石力开.气体雾化储氢合金及其MH/Ni电池性能[J].电池,2000(03):120-122. |
| [7] | Sasaki S;Hasegawa H;HIROSE Y et al.Method for producing cast alloy alloy andMagnet[P].US 5963774,1999. |
| [8] | Mishima R;Miyamura H;Sakai T et al.[J].Journal of Alloys and Compounds,1993,192:176. |
| [9] | 陈梅艳,张羊换,林玉芳,祁焱,李蓉,王新林.快淬对合金Mm（NiCoMnAl）5.1B0.1组织及电化学性能的影响[J].稀有金属,2003(06):726-729. |
| [10] | Li CJ.;Wang CY.;Wang XL. .Investigations on ML(NiCoMnTi)(5) alloys prepared with different solidification rates[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):300-306. |
| [11] | Zhou Y;Zhang Y F;Lei Y Q et al.[J].International Journal of Hydrogen Energy,1998,23(03):183. |
| [12] | Yayama H;Hirakawa K;Tomokiyo A .[J].Japanese Journal of Applied Physics,1986,25:739. |
| [13] | 查全性.电极过程动力学导论[M].北京:科学出版社,1987:10. |
| [14] | Matsuda H;Ayabe Y .[J].Zeitschrift Fur Elektrochemie,1955,59:494. |
| [15] | Rijswick M H.[J].Journal of Proc Int Symp Hydrides for Energy Storage,Geilo,1977:261. |
| [16] | Wakao S;Yonemura Y .[J].Journal of the Less-Common Metals,1983,89:481. |
| [17] | Sakai T;Miyamura H;Kuriyama N et al.[J].Z Fur Phys Chem,1994,183:1373. |
| [18] | Koushiro K;Hara M;Takeshita Y.[A].:159. |
| [19] | Li CJ.;Wang XL. .The influence of the annealing temperature on the electrochemical properties and the structure of the melt-spun ML(NiMnTiCo)(5) hydrogen-storage alloy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):278-283. |
| [20] | 经海;张曙光;郭宏 等.[J].功能材料,2001,32:1016. |
| [21] | Notten P H L;Daams J L C;Einerhand R E F .[J].Berichte der Bunsengesellschaft fuer Physikalische Chemie,1992,96:656. |
| [22] | Jasic M M .[J].Materials Chemistry and Physics,1989,22:1. |
| [23] | 崔舜,曾庆学,张维玉.贮氢电极合金产业化关键技术研究[J].电源技术,1999(04):215. |
| [24] | 经海,张曙光,张少明,郭宏,马自力,卢彩涛,石力开.气雾化低钴贮氢AB5型合金的电化学性能和 Rietveld 分析[J].稀有金属,2001(04):247-251. |
| [25] | 张深根;应启明;李红卫 等.钕铁硼合金快冷厚带及其制造方法[P].CN 1409332A,2003. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%