欢迎登录材料期刊网

材料期刊网

高级检索

用电沉积的方法制备了Co-Ni-W合金电极.用稳态极化曲线法和交流阻抗技术研究了其在7 mol·L-1NaOH溶液中的析氢电催化活性.结果表明:在碱性条件下,Co-Ni-W合金电极比Ni-Co,Ni-W合金电极具有更低的析氢过电位,其析氢的表观活化能为44.2 kJ·mol-1,具有较高的析氢催化活性,是一种有工业应用前景的的析氢电催化活性电极.

参考文献

[1] Paseka I .Sorption of hydrogen and kinetics of hydrogen evolution on amorphous Ni-Sx electrodes[J].Electrochimica Acta,1993,38:2449.
[2] Borucinshy Th;Rausch T;Wendt S et al.Raney nickel coating for cathodic hydrogen evolution by chemical gas phase reaction of nickel electrode surfaces[J].Journal of Applied Electrochemistry,1997,27:762.
[3] 刘善淑,成旦红,应太林,徐伟一.电沉积Ni-P-ZrO2复合电极析氢电催化性能的研究[J].电镀与涂饰,2001(06):4-7.
[4] 常天义,张宝宏,丛文博,骆耀.Ni-Sn电极析氢性能研究[J].电化学,2002(03):343-347.
[5] 杨辉;卢文庆.应用电化学[M].北京:科学出版社,2001:60.
[6] 杨静,吴仲达.镍钼合金电极的析氢性能研究[J].稀有金属,1998(04):251-253.
[7] Fan Chonglun;Piron D L;Paradis P .Hydrogen evolution on electrodeposited nickel-cobalt-molybdenum in alkaline water electrolysis[J].Electrochimica Acta,1994,39:2715.
[8] Ananth M V;Parthasaradhy N V .Hydrogen evolution characteristic of electrodeposited Ni-Zn-Fe coating in alkaline solutions[J].,1997,22(08):747.
[9] 胡伟康;张允什;宋德瑛 等.非晶态Ni-Mo-Fe合金作电解水析氢反应电极[J].功能材料,1995,26(05):456.
[10] Arularj I;Vasu K I .Transition metal-based hydrogen electrodes in alkaline solution electrocatalysis on nickel based binary alloy coatings[J].,1990,20:32.
[11] 查全性.电极过程动力学导论[M].北京:科学出版社,2002:250.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%