采用铝盐与尖晶石LiMn2O4的高温固相反应, 制备出改性的尖晶石锂锰氧化物材料.对材料进行了XRD和SEM分析及电性能等测试. 结果表明: 改性材料均基本保持了尖晶石主体结构;材料表面形貌与铝盐阴离子根极性强弱有关, 改性前的LiMn2O4在50 ℃下10次循环后, 容量衰减率为24.4%,而由铝盐酸性后材料的在8.3%~16%, 其中草酸铝对材料高温循环性能改善最为明显.
参考文献
[1] | 许名飞,李新海,张云河,吴显明.层状锰酸锂的制备及改性[J].电源技术,2003(04):366-369. |
[2] | BROUN S .Recent advances in lithium ion battery materials[J].Electrochimica Acta,2000,45:2461. |
[3] | PASUIER A DU;Blyr A;Courjal P et al.Mechanism for limited 55 ℃ storage performance of Li1.05Mn1.95O4 electrodes[J].Journal of the Electrochemical Society,1999,146:428. |
[4] | 王小兵;胡国和;陈方 等.功能聚合物修饰LiMn2O4的研究[J].中国稀土学报,2004,22:123. |
[5] | Gao Y;Yakovleva M V;Ebner W B .Novel Li1-xTix/2Mgx/2O2 compounds as cathode materials for safer lithium-ion batteries[J].Electrochemical and Solid State Letters,1998,1(03):117. |
[6] | Hayashi N;Ikuta H;Wakhara M .Cathode of LiMgyMn2-yO4 and LiMgyMn2-yO4-δ spinel phase for lithium secondary batteries[J].Journal of the Electrochemical Society,1999,146(04):1351. |
[7] | Amatucci G G;Schmutz C N;Blyr A et al.Materials effects on the elevated and room temperature performance of C/LiMn2O4 Li-ion batteries[J].Journal of Power Sources,1997,69:11. |
[8] | Song D.;Uchida T.;Wakihara M.;Ikuta H. .Spinel phases LiAlyMn2-yO4 (y = 0, 1/12, 1/9, 1/6, 1/3) and Li(Al,M)1/6Mn11/6O4 (M = Cr, Co) as the cathode for rechargeable lithium batteries[J].Solid state ionics,1999(1/2):151-156. |
[9] | AMATUCCI G;Pasquier A Du;Blyr A et al.The elevated temperature performance of the LiMn2O4/C system:failure and solutions[J].Electrochimica Acta,1999,45:255. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%