稀土离子激活的铝酸盐系长余辉发光材料因其余辉时间长、余辉亮度高、性能稳定、不含放射性等优点受到了广泛关注. 由于其性能优越, 大大拓宽了长余辉材料的应用领域, 因此它已经成为储能节能发光材料研究的新中心. 近几十年来, 无论材料的制备还是应用开发都已经取得了很大的进展. 主要综述了铝酸盐系长余辉发光材料的研究历史, 特别是近十几年的研究进展, 对长余辉发光材料余辉机制、制备方法进行了总结, 同时也介绍了国内外长余辉发光材料开发应用现状, 对其今后的研究与应用前景进行了展望.
参考文献
[1] | Froelich H C .Strontium Aluminate Phosphor[P].US 2392814,1946. |
[2] | Palilla F C;Lecine A K;Tomkus M R .Fluorescent properties of alkaline earth aluminates of the type MAl2O4:activated by divalent europium[J].Journal of the Electrochemical Society,1968,115(05):642. |
[3] | Abbruscato V .Optical and electrical properties of SrAl2O4:Eu2+[J].Journal of the Electrochemical Society,1971,118(08):930. |
[4] | 宋庆梅;黄锦斐;吴茂钧 .长余辉磷光材料及其制备[P].CN 1318601A,1991. |
[5] | 宋庆梅,黄锦斐,吴茂钧,陈暨跃.铝酸锶铕的合成与发光的研究[J].发光学报,1991(02):144-150. |
[6] | 唐明道,李长宽,高志武,许少鸿,蒋雪茵,蔡锟.SrAl2O4:Eu2+的长余辉发光特性的研究[J].发光学报,1995(01):51-56. |
[7] | 宋庆梅;陈暨耀;吴中亚 .掺镁的铝酸锶铕磷光体的发光特性[J].复旦学报(自然科学版),1995,34(01):103. |
[8] | Yamamoto H;Matsuzawa T .Mechanism of long phosphorescence of SrAl2O4:Eu2+, Dy3+ and CaAl2O4:Eu2+, Nd3+[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,1997(0):287-289. |
[9] | Wei Yi;Jia Huabiao;Yuan Lizhu et al.Phosphorescent dynamics in SrAl2O4:Eu2+,Dy3+ single crystal fibers[J].Journal of Luminescence,1998,76-77:424. |
[10] | 张天之,苏锵,王淑彬.MAl2O4:Eu2+、RE3+长余辉发光性质的研究[J].发光学报,1999(02):170-175. |
[11] | Haranath D;Virendra Shanker et al.Studies on the decay characteristics of strontium aluminate phosphor on themral treatment[J].Materials Chemistry and Physics,2002,78:6. |
[12] | Keizo Kato;Itaur Tsutai;Takuya Kamimura;Futao Kaneko;Kazunair Shinbo;Masatoshi Ohta;Takahiro Kawakami .Thermoluminescence properties of SrAl_2O_4: Eu sputtered films with long phosphorescence[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,1999(3):213-220. |
[13] | Peng Mingying;Pei Zhiwu;Hong Guangyan et al.Study on the reduction of Eu3+→Eu2+ in Sr4Al14O25:Eu prepared in air atmosphere[J].Chemical Physics Letters,2003,371:1. |
[14] | Wang D.;Yin QR.;Li YX.;Wang MQ. .Concentration quenching of Eu2+ in SrO.Al2O3 : Eu2+ phosphor[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2002(1):1-6. |
[15] | 马伟,万发荣,龙毅,尚成嘉.SrAl2O4:Eu,Dy的粉末粒度与发光性能的关系[J].发光学报,2003(01):95-99. |
[16] | Lin Yuanhua;Tang Zilong;Zhang Zhongtai et al.Influence of co-doping different rare earth ions on the luminescence of CaAl2O4-based phosphors[J].Journal of the European Ceramic Society,2003,23:175. |
[17] | 宋庆梅;陈暨耀;吴中亚 .掺镁的铝酸锶铕磷光体的发光特性[J].复旦学报(自然科学版),1995,34(01):103. |
[18] | Patil K C;Ekambaram S .Synthesis and properties of Eu2+ activated blue phosphors[J].Journal of Alloys and Compounds,1997,248:7. |
[19] | 杨志平,杨勇,朱胜超,刘冲,冯建伟.水解对SrAl2O4∶ Eu2+,Dy3+稳定性的影响[J].硅酸盐学报,2004(09):1050-1053. |
[20] | 吕兴栋,舒万艮,谭爱东,周文华.碱土铝酸盐长余辉发光颜料表面包膜的研究[J].无机材料学报,2004(06):1373-1378. |
[21] | Peng Tianyou;Liu Huajun;Yang Huanping et al.Synthesis of SrAl2O4∶Eu,Dy phosphor nanometer powders by sol-gel processes and its optical properties[J].Materials Chemistry and Physics,2004,85:68. |
[22] | Yamamoto H;Matsuzawa T .Mechanism of long phosphorescence of SrAl2O4:Eu2+, Dy3+ and CaAl2O4:Eu2+, Nd3+[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,1997(0):287-289. |
[23] | Kamada M.;Ohno N.;Murakami J. .Excitation spectra of a long-persistent phosphor SrAl2O4 : Eu, Dy in vacuum ultraviolet region[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2000(0):1042-1044. |
[24] | Akiyama M.;Matsui H.;Nonaka K.;Watanabe T.;Xu C. .Photostimulated luminescence phenomenon of Sr(4)AI(14)O(25): Eu, Dy using only visible lights[J].Journal of Materials Science Letters,2000(13):1163-1165. |
[25] | 林元华,张中太,张枫,阎肃.铝酸盐长余辉光致发光材料的制备及其发光机理的研究[J].材料导报,2000(01):35-37. |
[26] | 张天之,苏锵,王淑彬.MAl2O4:Eu2+、RE3+长余辉发光性质的研究[J].发光学报,1999(02):170-175. |
[27] | Kinoshita T;Yamazaki M;Kawazoe H et al.Long lasting phosphorescence and photo-stimulated luminescence in Tb-ion-activated reduced calcium aluminate glasses[J].Journal of Applied Physiology,1999,86:3729. |
[28] | Mastsuzama T;Takeuchi N et al.A new long phosphorescent phosphor with high brightness SrAl2O4∶Eu2+,Dy3+[J].Journal of the Electrochemical Society,1996,143(08):2670. |
[29] | Jia Weiyi;Yuan Huabiao;Lu Lizhu et al.Phosphorescent dynamics in SrAl2O4:Eu2+,Dy3+ single crystal fibers[J].Journal of Luminescence,1998,76-77:424. |
[30] | 张天之,苏锵,王淑彬.MAl2O4:Eu2+、RE3+长余辉发光性质的研究[J].发光学报,1999(02):170-175. |
[31] | Mastsuzama T;Aoki Y;Takeuchi N et al.A new long phosphorescent phosphor with high brightness SrAl2O4:Eu2+,Dy3+[J].Journal of the Electrochemical Society,1996,143(08):2670. |
[32] | 李晓云,陆天长,梁爽.铝酸锶系长余辉发光粉的制备及其光学性能[J].南京化工大学学报(自然科学版),2001(02):32-35. |
[33] | 林元华,张中太,张枫,阎肃.铝酸盐长余辉光致发光材料的制备及其发光机理的研究[J].材料导报,2000(01):35-37. |
[34] | 王惠琴;张磊;马林 等.燃烧法快速合成铝酸锶铕及其发光性能[J].复旦学报(自然科学版),1997,36(01):66. |
[35] | 陈仲林;万体智;张玉奇 等.燃烧法快速合成长余辉材料[J].重庆建筑大学学报,1998,20(06):67. |
[36] | 袁曦明,许永胜,于江波,田熙科.溶胶-凝胶法制备长余辉发光材料SrAl2O4:Eu2+,Dy3+的研究[J].稀土,2002(04):33-38. |
[37] | Kutty T R N;Jagannathan R .Luminecence of Eu2+ in strontium aluminates prepared by the hydrothermal method[J].Materials Research Bulletin,1990,25:1355. |
[38] | 任新光,孟继武.电弧法SrAl2O4:Eu2+长余辉发光陶瓷的制备及其光谱分析[J].光谱学与光谱分析,2000(03):268-269. |
[39] | Katsumata T.;Sasajima K.;Matsuzawa T.;Nabae T. .Growth and characteristics of long persistent SrAl2O4- and CaAl2O4-based phosphor crystals by a floating zone technique[J].Journal of Crystal Growth,1998(3):361-365. |
[40] | Liu Yingliang,Feng Dexiong,Yang Peihui.Preparation of Phosphors MAl2O4∶Eu2+(M=Ca,Sr,Ba) by Microwave Heating Technique and Their Phosphorescence[J].稀有金属(英文版),2000(04):297-300. |
[41] | Jia Weiyi;Yuan Huabiao;Lu Lizhu et al.Crystal growth and characterization of Eu2+,Dy3+:SrAl2O4 and Eu2+,Nd3+:CaAl2O4 by the LHPG method[J].Journal of Crystal Growth,1999,200:179. |
[42] | 耿秀娟,陈永杰,肖林久,关瑾,王丹焱,牟江南.微乳液法制备长余辉发光材料CaAl2O4:Eu2+,Dy3+[J].沈阳化工学院学报,2004(04):241-243. |
[43] | Qiu JR.;Hirao K. .Long lasting phosphorescence in Eu2+-doped calcium aluminoborate glasses[J].Solid State Communications,1998(12):795-798. |
[44] | Qiu J.;Tanaka K.;Shimizugawa Y.;Hirao K.;Kawasaki M. .Phenomenon and mechanism of long-lasting phosphorescence in Eu2+-doped aluminosilicate glasses[J].The journal of physics and chemistry of solids,1998(9):1521-1525. |
[45] | 林元华,张中太,陈清明,唐子龙,龚江宏.长余辉光致发光玻璃的制备及其性能研究[J].材料科学与工艺,2000(01):1-6. |
[46] | 张希艳,郭瑜,柏朝晖,王学荣,曹志峰.SrAl2O4:Eu2+,Dy3+光致发光搪瓷涂层的制备[J].材料科学与工艺,2002(03):314-317. |
[47] | 浦鸿汀;苏发英;王坚 等.光致发光聚甲基丙烯酸甲酯塑料的研究[J].塑料工业,1998,26(04):113. |
[48] | Chang Chengkang;Mao Dali;Shen Jianfeng et al.Preparation of long persistent SrO·2Al2O3 ceramics and their Luminescent properties[J].Journal of Alloys and Compounds,2003,348:224. |
[49] | Qiu J;Miura K;Inouye H et al.Femtosecond laser induced three-demensional bright and long-lasting phosphorescence inside calcium aluminosilicate glasses doped with rare earth ions[J].Applied Physics Letters,1998,73:1763. |
[50] | Su Qiang;Li Chengyu;Lu Yuehua .Preparation of the glasses and glass-ceramics with long-lasting phosphorescence and photo-stimulated long-lasting phosphorescence for optical memory[P].CN 1160266,2004. |
[51] | Kowtari M;Koyama D;Satoh Y et al.The temperature dependence of luminescence from a long-lasting phosphors exposed to ionizing radiation[J].Nuclear Instruments and Methods in physics Research,2002,480:431. |
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