回顾了熔融法、固相反应法、机械合金化和放电等离子烧结技术等方钴矿热电材料的制备方法及其特点,重点阐述了在方钴矿化合物中固溶Fe,Ni等元素,以及在方钴矿化合物中填充碱土或稀土元素对热电性能的改进;同时介绍了低维化对方钴矿化合物的热电传输特性的影响.提出了优化方钴矿化合物热电性能的途径.
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