综述了钌催化剂催化的主要几类有机合成反应, 包括氢化、氧化、异构化、复分解. 重点介绍了钌催化剂催化选择性氢化反应和烯烃复分解反应的研究进展, 指出了今后钌催化剂研究的几个重要方向, 并对钌催化剂的工业应用前景作了展望.
参考文献
| [1] | 黄葆同;李悦生.后过渡金属聚合催化[M].北京:化学工业出版社,2005 |
| [2] | 熊晓东,王胜国,梁敬博,李茂良,张曦.铑在均相催化工业中的应用[J].稀有金属,2005(04):403-407. |
| [3] | Seddon E A;Seddon K R.The Chemistry of Ruthenium[M].Amsterdam:Elsevier,1984 |
| [4] | Komiya S;Hirano M.In Synthesis of Organometallic Compounds[M].Chichester:John Wiley and Sons Inc,1997:159. |
| [5] | Siegel S.Encyclopedia of Reagents for Organic Synthesis[M].Chichester:John Wiley and Sons Inc,1996:4410. |
| [6] | James B R.Homogeneous Hydrogenation[M].New York:Wiley,1973 |
| [7] | Hallman P S;Evans D;Osborn J A;Wilkinson G.Selective catalytic homogeneous hydrogenation of terminal olefins using tris(triphenylphosphine)hydridochlororuthenium(Ⅱ); Hydrogen transfer in exchange and isomerisation reactions of olefins[J].Chemistry Communications,1967:305. |
| [8] | Hallman P S;Mcgarvey B R;Wilkinson G.The preparation and reactions of hydridochlorotris(triphenylphosphine) ruthenium(Ⅱ) including homogeneous catalytic hydrogenation of Alk-1-enes[J].Journal of The Chemical Society(A),1968:3143. |
| [9] | Knifton J F;Robert M .Suggitt,Homogenous catalysts useful in the reaction of nitroaromatics to amines[P].US 3832401,1974. |
| [10] | Ohta T;Takaya H;Noyori R;Nagai K .Asymmetric hydrogenation of unsaturated carboxylic acids catalyzed by BINAP-ruthenium(Ⅱ) complexes[J].Journal of Organic Chemistry,1987,52:3174. |
| [11] | Noyori R;Ohta M;Hsiao Y;Kitamura M,Ohta T M,Abramson L .Asymmetric synthesis of isoquinoline alkaloids by homogeneous catalysis[J].Journal of the American Chemical Society,1986,108:7117. |
| [12] | Tschaen DM.;Cai DW.;Desmond R.;Dolling UH.;Frey L. Karady S.;Shi YJ.;Verhoeven TR.;Abramson L. .ASYMMETRIC SYNTHESIS OF MK-0499[J].The Journal of Organic Chemistry,1995(14):4324-4330. |
| [13] | Kitamura M;Ohkuma T;Inoue S .Homogeneous asymmetric hydrogenation of functionalized ketones[J].Journal of the American Chemical Society,1988,110:629. |
| [14] | Burk M J;Harper T G P;Kalberg C S .Highly enantioselective hydrogenation of beta-keto esters under mild conditions[J].Journal of the American Chemical Society,1995,117:4423. |
| [15] | Ohkuma T;Ooka H;Hashiguchi S .Practical enantioselective hydrogenation of aromatic ketones[J].Journal of the American Chemical Society,1995,117:2675. |
| [16] | Ohkuma T;Ooka H;Ikariya T .Preferential hydrogenation of aldehydes and ketones[J].Journal of the American Chemical Society,1995,117:10417. |
| [17] | Hashiguchi S;Fujii A;Takehara J .Asymmetric transfer hydrogenation of aromatic ketones catalyzed by chiral ruthenium(Ⅱ) complexes[J].Journal of the American Chemical Society,1995,117:7562. |
| [18] | Trost B M;Kulawiec R .Chemoselectivity in the ruthenium-catalyzed redox isomerization of allyl alcohols[J].Journal of the American Chemical Society,1993,115:2027. |
| [19] | Murahashi S;Naota T;Ito K .Ruthenium-catalyzed oxidative transformation of alcohols and aldehydes to esters and lactones[J].Journal of Organic Chemistry,1987,52:4319. |
| [20] | Ishii Y;Osakada K;Ikariya T .Ruthenium complex catalyzed regioselective dehydrogenation of unsymmetrical.alpha.,.omega.-diols[J].Journal of Organic Chemistry,1986,51:2034. |
| [21] | Wang G Z;Andreasson U;Backvall J E .Aerobic oxidation of alcohols with ruthenium-cobalt bimetallic catalyst[J].Journal of the Chemical Society Chemical Communication,1994,25:1037. |
| [22] | Carlsen P H J;Katsuki T;Martin V S;Sharpless K B .A greatly improved procedure for ruthenium tetroxide catalyzed oxidations of organic compounds[J].Journal of Organic Chemistry,1981,46:3936. |
| [23] | Murahashi S I;Naota T;Nakajima N .Ruthenium catalyzed oxidation of cyanohydrins to acyl cyanides useful reagents for selective N-benzoylation of aminoalcohols[J].Tetrahedron Letters,1985,26:925. |
| [24] | Tsuji Y;Ohta T;Ido T;Noda S .Ruthenium-catalyzed oxidation of alcohols and catechols using t-butyl hydroperoxide[J].Journal of Organometallic Chemistry,1984,270:333. |
| [25] | Ley S V;Anthony N J;Armstrong A et al.A highly convergent total synthesis of the spiroacetal macrolide (+)-milbemycin β1[J].Tetrahedrom,1989,45:7161. |
| [26] | Matsumoto M;Watanabe N .Oxidation of allylic alcohols to unsaturated carbonyl compounds by ruthenium dioxide and dioxyged ruthenium dixoxide[J].Journal of Organic Chemistry,1984,49:3435. |
| [27] | Murahashi S I;Naota T;Hirai N .Aerobic oxidation of alcohols with ruthenium-cobalt bimetallic catalyst in the presence of aldehydes[J].Journal of Organic Chemistry,1993,58:7318. |
| [28] | Murahashi S I;Naota T;Miyaguchi N et al.Ruthenium-catalyzed oxidation of phenols with alkyl hydroperoxides.a novel,facile route to 2-substituted quinones[J].Journal of the American Chemical Society,1996,118:2509. |
| [29] | Higuchi T;Ohtake H;Hirobe M .Highly efficient oxygen transfer reactions from various heteroaromatic n-oxides to olefins,alcohols,and sulfides catalyzed by ruthenium porphyrin[J].Tetrahedron Letters,1991,32:7435. |
| [30] | Reuter J M;Salomon R G .Ruthenium(Ⅱ) catalyzed rearrangement of diallyl ethers.A synthesis of.gamma.,.delta.-unsaturated aldehydes and ketones[J].Journal of Organic Chemistry,1977,42:3360. |
| [31] | Stille J K;Becker Y .Isomerization of N-allylamides and -imides to aliphatic enamides by iron,rhodium,and ruthenium complexes[J].Journal of Organic Chemistry,1980,45:2139. |
| [32] | 朱杰,张学景,邹永.关环复分解反应（RCM）及其催化剂研究进展[J].有机化学,2004(02):127-139. |
| [33] | 李蕊琼,傅尧,刘磊,郭庆祥.钌催化烯烃复分解反应的研究进展[J].有机化学,2004(09):1004-1017. |
| [34] | 郭盈岑,肖文精.烯烃的交叉复分解反应（CM）及其合成应用[J].有机化学,2005(11):1334-1341. |
| [35] | Murdzek J S;Schrock R R .Well-characterized olefin metathesis catalysts that contain molybdenum[J].Organometallics,1987,6:1373. |
| [36] | Schrock R R;Krouse S A;Knoll K .Controlled ring-opening metathesis polymerization by molybdenum and tungsten alkylidene complexes[J].J Molecular Catal,1988,46:243. |
| [37] | Schrock R R;Murdzek J S;Barzan G C et al.Synthesis of molybdenum imido alkylidene complexes and some reactions involving acyclic olefins[J].Journal of the American Chemical Society,1990,112:3875. |
| [38] | Barzan G C;Oskam J H;Cho H N;Park L Y,Schrcck R R .Living ring-opening metathesis polymerization of 2,3-difunctionalized 7-oxanorbornenes and 7-oxanorbornadienes by Mo(CHCMe2R)(NC6H3-iso-Pr2-2,6)(O-tert-Bu)2 and Mo(CHCMe2R)(NC6H3-iso-Pr2-2,6)(OCMe2CF3)2[J].Journal of the American Chemical Society,1991,113:6899. |
| [39] | Nguyen S T;Johnsson L K;Grubbs R H;Ziller J W .Ring-opening metathesis polymerization (ROMP) of norbornene by a Group Ⅷ carbene complex in protic media[J].Journal of the American Chemical Society,1992,114:3974. |
| [40] | Fu G C;Nguyen S T;Grubbs R H .Catalytic ring-closing metathesis of functionalized dienes by a ruthenium carbene complex[J].Journal of the American Chemical Society,1993,115:9856. |
| [41] | Nguyen S T;Grubbs R H;Ziller J W .Syntheses and activities of new single-component,ruthenium-based olefin metathesis catalysts[J].Journal of the American Chemical Society,1993,115:9858. |
| [42] | Schwab P;Grubbs RH;Ziller JW .SYNTHESIS AND APPLICATIONS OF RUCL2(=CHR')(PR(3))(2) - THE INFLUENCE OF THE ALKYLIDENE MOIETY ON METATHESIS ACTIVITY[J].Journal of the American Chemical Society,1996(1):100-110. |
| [43] | Stragies R;Blechert S .Total synthesis of (-)-halosaline by a ruthenium-catalyzed ring rearrangement[J].Tetrahedrom,1999,55:8179. |
| [44] | Scholl M.;Morgan JP.;Grubbs RH.;Trnka TM. .Increased ring closing metathesis activity of ruthenium-based olefin metathesis catalysts coordinated with imidazolin-2-ylidene ligands[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,1999(12):2247-2250. |
| [45] | Pia Kahnberg;Choon Woo Lee;Robert H Grubbs;Olov S .Alternative routes to pterulone[J].Tetrahedrom,2002,58:5203. |
| [46] | Cossy J;Bargiggia F;BouzBouz S .Tandem cross-metathesis/hydrogenation/cyclization reactions by using compatible catalysts[J].Organic Letters,2003,5:459. |
| [47] | Kingsbury J S;Harrity J P A;Hoverda A H;Bonitatebus J P Jr .A recyclable Ru-based metathesis catalyst[J].Journal of the American Chemical Society,1999,121:791. |
| [48] | Justin P.Gallivan;Jason P.Jordan;Robert H.Grubbs .A neutral,water-soluble olefin metathesis catalyst based on an N-heterocyclic carbene ligand[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,2005(15):2577-2580. |
| [49] | Soon Hyeok Hong;Robert H.Grubbs .Highly Active Water-Soluble Olefin Metathesis Catalyst[J].Journal of the American Chemical Society,2006(11):3508-3509. |
| [50] | Tarun K Maishal;Biplab Mondal;Vedavati G Puranik .Synthesis,structure,electrochemistry and ROMP-activity of new ferrocenyl analog of Grubbs metathesis catalyst[J].Journal of Organometallic Chemistry,2005,690:1018. |
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