采用连续流动微反装置考察了ZrO2-Al2O3复合载体制备方法对Pd基催化荆加氢脱硫性能的影响,并采用XRD,TPR,H2-TPD.NH3-TPD和H2吸附等技术对催化剂进行了表征.结果表明,复合载体的制备方法对Pd基催化剂加氢脱硫性能有较大的影响,与浸渍法相比,溶胶一凝胶法制备的复合载体增强了活性组分与载体的相互作用,有利于Pd分散度的增大和催化剂酸量的增加,从而有利于Pd基催化剂活性的提高.
参考文献
[1] | 顾忠华,罗来涛,李茂康.聚合物稳定的Au-Pd/TiO2-Al2O3催化剂的还原方法及其催化性能的研究[J].稀有金属,2006(06):789-794. |
[2] | Yang Zongxian;Wu Ruqian .First-principles study Of the adsorption Of sulfur on Pt(111):Score.1evel shifts and the nature Of the Pt-S bond[J].Physical Review B,2002,65:155409. |
[3] | Marecot P;Mahoungon J R;Barbier J .Benzene hydrogenation on platinum and iridium catalysts.Variation of the toxicity of sulfurwith the nature Of the support[J].Applied Catalysis A:General,1993,101:143. |
[4] | Melada S.;Signoretto M.;Somma F.;Pinna F.;Cerrato G.;Meligrana G. Morterra C. .Gas- and liquid-phase reactions on sulphated zirconia prepared by precipitation[J].Catalysis Letters,2004(3/4):193-198. |
[5] | Fujikawa T.;Mizuguchi H.;Godo H.;Idei K.;Usui K.;Tsuji K. .EXAFS characterization of bimetallic Pt-Pd/SiO2-Al2O3 catalysts for hydrogenation of aromatics in diesel fuel[J].Catalysis Letters,1999(1/2):27-33. |
[6] | Enrique R C;Josefa M R;Lourdes D;Pedro M T Deborah J J Jacques R Antonio J L .Hydrogenation and ring opening of tetralin on noble metal supported an zirconium doped mesoporous silica catalysts[J].Applied Catalysis A:General,2004,260(01):9. |
[7] | Lin W;Zhu Y X;Wu N Z;Xie Y C,Murwani I,Kemnitz E .Total oxidation of methane at low temperature over Pd/TiO2/A12O3:effects of the support and residual chlorine ions[J].Applied Catalysis B:Environmental,2004,50(01):59. |
[8] | Mazzieri V.;Coloma-Pascual F.;Arcoya A.;L'Argentiere P.;Figoli NS. .XPS, FTIR and TPR characterization of Ru/Al2O3 catalysts[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2003(3/4):222-230. |
[9] | Jeong Gil Seo;Min Hye Youn;In Kyu Song .Hydrogen production by steam reforming of LNG over Ni/Al2O3–ZrO2 catalysts: Effect of Al2O3–ZrO2 supports prepared by a grafting method[J].Journal of molecular catalysis, A. Chemical,2007(1/2):9-14. |
[10] | 魏俊梅,徐柏庆,李晋鲁,程振兴,王亚权,朱起明.CO2重整CH4纳米ZrO2负载Ni催化剂的研究(Ⅰ)--与常规载体上Ni催化剂的比较[J].高等学校化学学报,2002(01):92-97. |
[11] | Fornasiero P.;Rao GR.;Kaspar J.;Meriani S.;Trovarelli A. Graziani M.;Dimonte R. .RH-LOADED CEO2-ZRO2 SOLID SOLUTIONS AS HIGHLY EFFICIENT OXYGEN EXCHANGERS - DEPENDENCE OF THE REDUCTION BEHAVIOR AND THE OXYGEN STORAGE CAPACITY ON THE STRUCTURAL PROPERTIES[J].Journal of Catalysis,1995(1):168-177. |
[12] | Gopinath R;Lingaiah N;Babu NS;Suryanarayana I;Prasad PSS;Obuchi A .A highly active low Pd content catalyst synthesized by deposition-precipitation method for hydrodechlorination of chlorobenzene[J].Journal of molecular catalysis, A. Chemical,2004(1/2):289-293. |
[13] | Chen L F;Wang J A;Valenzuela M A;Bokhimi X Acosta D R Novaro O .Hydrogen spillover and structural defects in a PdO/zirconia nanophase synthesized through a surfactant-templated route Journal of Alloys and Compounds[J].Journal of Alloys and Compounds,2006,417:220. |
[14] | 刘旦初.多相催化原理[M].上海:复旦大学出版社,1997 |
[15] | 陈国清,张凯锋,王国峰,张蕾.纳米Al2O3/ZrO2复合粉体的制备及表征[J].材料科学与工艺,2004(01):20-23,28. |
[16] | 刘征,王文祥,李凡.添加ZrO2对熔铁催化剂还原的影响[J].燃料化学学报,1990(04):370-374. |
[17] | 岳宝华,周仁贤,沙风,郑小明.Pd/CexZr1-xO2/Al2O3催化剂上甲烷燃烧及TPR/TPO性能研究[J].中国稀土学报,2006(01):22-26. |
[18] | Okumura K.;Kobayashi T.;Tanaka H.;Niwa M. .Toluene combustion over palladium supported on various metal oxide supports[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(4):325-331. |
[19] | Wang J A;Bokhimi X;Novaro O;Lopez T,Tzompantzi F,Gomez R,Navarrete J,Llano M E,Lopez-Salina E .Effects of structural defects acid-basic-basic properties On the activity and selectivity of isopropanol decomposition on nanocrystallite sol-gel alumina catalyst[J].Journal of Molecular Catalysis A:Chemical,1999,137:239. |
[20] | Katada N;Igi H;Kim J H;Niwa M .Determination of the acidic properties of zeolite by theoretical analysis of temper ature-progrmmed desprtion of ammonia based On adsorption equilibrium[J].Journal of Physical Chemistry B,1997,101(31):5969. |
[21] | Echard M;Leglise J .Sulphidation of an oxidic CoMo/AL2O3 catalyst under practical conditions:different Kinds of sulphur species[J].Catalsis Letters,2001,72:83. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%