锆和铪的化学性质十分相似,所以分离锆和铪一直足世界各国研究的重要课题.溶荆萃取法分离锆和铪是日前研究最多的方法.文章详细评述了溶剂萃取分离锆和铪的研究进展.介绍了用于分离锆和铪的萃取体系及已工业化的萃取体系.
参考文献
[1] | 熊炳昆;温旺光;杨新民;李蕙嫒 罗方承 张伟 郭靖茂.锆铪冶金[M].北京:冶金工业出版社,2002 |
[2] | Lee H Y;Kim S G;Oh J K .Stoichiometric relution for extraction of zirconium and hafnium from acidic chloride solutions with versatic acid 10[J].HYDROMETALLURGY,2004,73:91. |
[3] | Fisher W;Chalyhaeus W .Uber die trennung anorganischer stoffgemische durch verteilung zwisehen zweil losungsmitteln.3.die trennung des hafniums vom zirkonium durch verteilung[J].Zeitschrift Fur Anorganische Und Allgemeine Chemie,1947,255:79. |
[4] | 徐光宪;王文清;吴瑾光;高宏成 施鼎.萃取化学原理[M].上海:上海科学技术出版社,1984 |
[5] | Levitt A E;Freund H .Solvent extraction of zireoninm with tributyl phosphate[J].Journal of the American Chemical Society,1956,78:1545. |
[6] | Cox R P;Poterson H C;Beyer G H .Separation hafnium from zirconium-solvent extraction with tributyl phosphate[J].Industrial and Engineering Chemistry,1958,50:141. |
[7] | Dibrov I A;Chirkst D E;Litvinova T E .Experimental study of zirconium(Ⅳ) extraction from fluoride containing acid solutions[J].Russian Journal of Applied Chemistry,2002,75:195. |
[8] | Taghizadeh M;Ghasemzadeh B;Ashrafizadeh S N .Determination of optimum process conditions for the extraction and separation of zirconium and hafnium by solvent extraction[J].Hydrometallurgy,2008,90:115. |
[9] | 蒋竹筠 .混合酸系统磷酸三丁酯萃取分离锆铪[J].稀有金属与硬质合金,1996,125:55. |
[10] | 林振汉.用TBP萃取分离锆和铪的工艺研究[J].稀有金属快报,2004(11):21-25. |
[11] | Wood D F;Jones J T .The determination of zirconium (and hafnium) in niobium and other metals with catexhol violet[J].Analyst,1965,90:125. |
[12] | Kakade S M;Shinde V M .Extraction separation of group IVB elements:analysis of alloy samples[J].Talanta,1995,42:635. |
[13] | GuptaB;MalikP;MudharN .Extraction and recovery of zirconium from zircon using cyanex 923[J].Solvent Extraction and Ion Exchange,2005,23:345. |
[14] | Da S A;EI-Ammouri E;Distin P A .Hafnium/zirconium ssparation using cyanex 925[J].Canadian Metallurgical Quarterly,2000,39:37. |
[15] | 罗方承;陈忠锡;孙小龙;谌美玲 .MIBK双溶剂萃取法制备原子能级氧化锆和氧化铪的工艺设计[J].有色金属快报,2007,26:89. |
[16] | 林振汉.用甲基异丁基酮萃取分离锆铪的工艺评价[J].稀有金属快报,2007(01):93-96. |
[17] | Kalyanaraman S;Khopkar S M .Solvent extraction separation of hafnium with 4-methyl-3-pentene-2-ene[J].Talanta,1978,25:395. |
[18] | SatoT;WatanabeH .The extraction of zircouium(Ⅳ) from hydrochloric acid solutions by high-molecular-weight amines[J].Anlytica Chimica Acta,1971,54:439. |
[19] | Vibhute C P;Khopkar S M .Liqaid/liquid extraction separation of hafnium with ambedite La-1 from zirconium and dements in citric add solutions[J].Anlytica Chimica Acta,193:387. |
[20] | Yamani I S;Farah M Y;Aleim F A .Co-extraction and separation of zirconium and hafnium by long-chain from sulphate media[J].Talanta,1978,25:523. |
[21] | Moore F L .Long-chain versatile acid extractants[J].Analytical Chemistry,1957,29:1660. |
[22] | Rajmane M M;Sargar B M;Mahamuni S V;Anuse M A .Solvent extraction separation of zirconium (IV) from sulcinate medin with N-(n-octyl) aniline[J].Journal of the Serbian Chemical Society,2006,71:223. |
[23] | 杨利民;王秋泉;李明辉;赵丰刚 .石油亚砜在盐酸-硫氰酸铵混合体系中对锆和铪的萃取研究[J].稀有金属,1996,20:124. |
[24] | Khan MH.;Ali A. .Liquid-liquid extraction of Hf(IV) from nitric acid with dibutylsulfoxide in cyclohexane[J].Radiochimica Acta: International Journal for Chemical Aspects of Nuclear Science and Technology,2002(5):297-301. |
[25] | Huffman E H;Beaufait L J .The fractional separation of zirconium and hafnium by extraction with thenoyhrifluoroacotane[J].Journal of the American Chemical Society,1949,71:3179. |
[26] | Schultz B G;Larsen E M .The fractional separation of zirconium and hafnium by extraction with trifluoroacetylacetene[J].Journal of the American Chemical Society,1950,72:3610. |
[27] | King E L;Reas W H .The activity coefficient of thenoyltrifluoroacetane in benzene solution[J].Journal of the American Chemical Society,1951,73:1804. |
[28] | Moore F L .Separation of zirconium from other elements by liquid-liquid extraction[J].Analytical Chemistry,1956,28:997. |
[29] | Hala J .The solvent extraction of hafnium (Ⅳ) and zirconium (Ⅳ) by N-benzoyi-phenylhydroxylamine and 2-thenoyitrifluoroacetone from strongly acidic solutions[J].Journal of Inorganic and Nuclear Chemistry,1967,29:187. |
[30] | Larsen E M;Terry G;Leddy J .The preparation and properties of zirconium and hafnium chelates of certain β-diketones[J].Journal of the American Chemical Society,1953,75:5107. |
[31] | Larsen E M;Terry G .Extraction of zirconium and hafnium with varionsβ-diketenes[J].J Am Chem Sov,1953,75:1560. |
[32] | Huffmen EH;IddingsGM;OsborneRN;Shalimoff G V .Extraction of zirconium and hafnium with various fluorinated β-diketones[J].Journal of the American Chemical Society,1955,77:881. |
[33] | Johnston J R;Holland W J.3-Thianaphthenoyltrifluoroacetone:A new reagent for the solvent extraction of zirconium and hafnium[J].J Gerard Mikrochlmica Acta,1972:608. |
[34] | Busev A I;Zhlvopistsev V P;Petrov B I;Degtev M I Nenning P .Extraction of zirconium and hafnium from hydrochloric acid solutions with derivatives of diantipyrylmethane[J].Anlytica Chimica Acta,1975,80:311. |
[35] | Fenche K F .Extraction of Hf(Ⅳ) from strongly acidic N-ben-zoyl-N-phenylhydroxylamins[J].Journal of Inorganic and Nuclear Chemistry,1968,30:3057. |
[36] | Fouche K F;Roux H J;Phillips F .Complex formation of Zr (Ⅳ) and Hf(Ⅳ) with hydroxamic acids in acidic solutions[J].J lnorg Nucl Chem,1970,32:1949. |
[37] | Roux H J;Fouche K F .Extraction of zirconium and hafnium with trifluoromethyl-substitued hydroxamic acids[J].J lnorg Nuel Chem,1970,32:3059. |
[38] | Desideri D;Staccioli L;Testa C .Liquid-liquid extraction og zirconium with tri-n-butylacetohydroxamic acid and speetrophntometric determination in the organic phase with xylenol[J].Anlytiea Chimica Acta,1985,176:269. |
[39] | Reddy B R;Kumar J R;Reddy A V .Solvent extraction of zirconium(Ⅳ) from acid chloride solutions using LIX-84-IC[J].Hydrometallurgy,2004,74:173. |
[40] | Reddy B R;Kumar I R .Liquid liquid extraction of tetravalent zirconium and hafnium from acidic chloride solutions using 2-hy-droxy-5-nonylsalysildehydeoxime[J].SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN,2006,13:37. |
[41] | Gorican H M .Solvent extraction of zirconium and hafnium-extrac-tion with di-n-bntylmethylebisphonic[J].Journal of Inorganic and Nuclear Chemistry,1971,33:1919. |
[42] | Biswas R K;Hayat M A .Solvent extraction of zirconium(Ⅳ) from chloride media by D2EHPA in kerosene[J].Hydrometallurgy,2002,63:149. |
[43] | Reddy B R;Kumar J R;Reddy A V;Priya D N .Solvent extraction of zirconium(IV) from acidic chloride solutions using 2-ethyl hexyl phnsphanic acid mono-2-ethyi hexyl ester (PC-88A)[J].Hydrometallurgy,2004,72:303. |
[44] | Kumar, JR;Reddy, BR;Reddy, KJ;Reddy, AV .Liquid-liquid extraction of tetravalent hafnium from acidic chloride solutions using bis(2,4,4-trimethylpentyl) dithiophosphinic acid (Cyanex 301)[J].Separation Science and Technology,2007(4):865-877. |
[45] | Lee H Y;Kim S G;Oh J K .Stoichiometric relation for extraction of zirconium and hafnium from acidic chloride solutions with versatie acid 10[J].HYDROMETALLURGY,2004,73:91. |
[46] | Fouche K F;Lessing J G V .Benzylphenylarsinic acid as extractant for Zr(Ⅳ) and Hf(Ⅳ)[J].J Inorg Nuci Chem,1970,32:2357. |
[47] | Yamani I S;Farah M Y;Aleim F A .Studies on extraction of zirconium by quaternary ammonium halides from hydrochloric acid media and its separation from hafnium[J].Talanta,1978,25:714. |
[48] | ReddyKJ;KumarJ R;Reddy A V;Reddy M L P .Synergistic extraction of zirconium(Ⅳ) and hafnium(Ⅳ) with 4-acylbis(1-phenyl-3-methyl-5-pyrazolones) in the presence of neutral organophesphprus extractants[J].Solvent Extraction and Ion Exchange,2006,24:419. |
[49] | Dedrkar N V;Khopkar S M .Liquid-liquid extraction of zirconium from hafnium and other elements with dicyclohexyl-18-crown-6[J].Anlytiea Chimiea Acta,1991,254:27. |
[50] | Agrawal Y K;Sudhakar S .Extraction,separation and preconcentmtion of zirconium[J].Separation and Purification Technology,2002,27:111. |
[51] | 张力.锆铪分离的湿法工艺比较及分析[J].稀有金属快报,2007(01):115-118. |
[52] | 刘敏娉,丁燕,张泽光,蔡挺.锆与铪分离技术的研究现状及应用前景[J].广东有色金属学报,2001(02):115-119. |
[53] | 田胜军,刘艳,陈刚,高仁喜.锆铪的分离技术及应用[J].铀矿冶,2006(02):103-109. |
[54] | 丁纯梅,王芬华,李芳,苏云,张德海,沙乐.壳聚糖-Zr(Ⅳ)配合物的制备及催化氧化降解的研究[J].稀有金属,2007(02):232-236. |
[55] | 罗方承,吕文广,罗新文.硫酸锆、碳酸锆的性质、应用及生产技术综述[J].稀有金属,2003(01):53-56. |
[56] | 许圣麟.锆铪丝材加工及其在等离子切割电极中的应用[J].稀有金属,2005(01):88-91. |
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